Preparation and Properties of Branched Poly(phosphoric ester) Oligomer and its Influences on Poly(L-lactide)

Yuqing Bai; Yingbin Liu; Mingtao Run

doi:10.14233/ajchem.2014.16189

Issue

Vol. 26 No. 15 (2014): Vol 26 Issue 15

Issue Published : July 16, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Preparation and Properties of Branched Poly(phosphoric ester) Oligomer and its Influences on Poly(L-lactide)

https://doi.org/10.14233/ajchem.2014.16189

Yuqing Bai

College of Chemistry & Environmental Science, Hebei University, Baoding, P.R. China

Yingbin Liu

College of Chemistry & Environmental Science, Hebei University, Baoding, P.R. China

Mingtao Run

College of Chemistry & Environmental Science, Hebei University, Baoding, P.R. China

Corresponding Author(s) : Mingtao Run

lhbx@hbu.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 15 (2014): Vol 26 Issue 15
Article Published : July 16, 2014

Abstract

Branched poly(phosphoric ester) (BPPE) oligomer containing intumescent flame retardant were synthesized from spirocyclic pentaerythritol diphosphonate dichloride (SPDPC) and triethanolamine (TEA) and it was blended with poly(L-lactide) (PLLA) to investigate its influences on the thermal and rheological properties of poly(L-Lactide). The results suggest that branched poly(phosphoric ester) oligomer is an intumescent flame retardant whose residual char reaches 47 % at 600 °C and it can partially crystallize into monoclinic crystals. When it was blended with poly(L-lactide), it functions as an intumescent flame retardant, not only widening the degradation temperature range at high temperature but also increasing the residual carbon ratio of poly(L-lactide). Branched poly(phosphoric ester) also serves as a plasticizer for poly(L-lactide) by decreasing the melt viscosity.

Keywords

Branched oligomer Intumescent flame retardant Thermal stability Melting Rheology

Bai, Y., Liu, Y., & Run, M. (2014). Preparation and Properties of Branched Poly(phosphoric ester) Oligomer and its Influences on Poly(L-lactide). Asian Journal of Chemistry, 26(15), 4735–4740. https://doi.org/10.14233/ajchem.2014.16189

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References

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M. Gao and S.S. Yang, J. Appl. Polym. Sci., 115, 2346 (2010); doi:10.1002/app.29483.

A.K. Sen, B. Mukherjee, A.S. Bhattacharya, L.K. Sanghi, P.P. De and A.K. Bhowmick, J. Appl. Polym. Sci., 43, 1673 (1991); doi:10.1002/app.1991.070430910.

Z.L. Ma, M. Zhao, H.F. Hu, H.T. Ding and J. Zhang, J. Appl. Polym. Sci., 83, 3128 (2002); doi:10.1002/app.10099.

Y. Chen, Y. Liu, Q. Wang, H. Yin, N. Aelmans and R. Kierkels, Polym. Degrad. Stabil., 81, 215 (2003); doi:10.1016/S0141-3910(03)00091-0.

Y. Halpern, D.M. Mott and R.H. Niswander, Ind. Eng. Chem. Prod. Res. Dev., 23, 233 (1984); doi:10.1021/i300014a011.

H.Y. Ma, L.F. Tong, Z.B. Xu, Z.P. Fang, Y.M. Jin and F.Z. Lu, Polym. Degrad. Stabil., 92, 720 (2007); doi:10.1016/j.polymdegradstab.2006.12.009.

X. Wang, Y. Hu, L. Song, W.Y. Xing, H.D. Lu, P. Lv and G.X. Jie, Polymer (Guildf.), 51, 2435 (2010); doi:10.1016/j.polymer.2010.03.053.

D.Q. Chen, Y.Z. Wang, X.P. Hu, D.Y. Wang, M.H. Qu and B. Yang, Polym. Degrad. Stabil., 88, 349 (2005); doi:10.1016/j.polymdegradstab.2004.11.010.

M. Jikei and M.A. Kakimoto, Prog. Polym. Sci., 26, 1233 (2001); doi:10.1016/S0079-6700(01)00018-1.

Y.H. Kim, J. Polym. Sci. A Polym. Chem., 36, 1685 (1998); doi:10.1002/(SICI)1099-0518(199808)36:11<1685::AID-POLA1>3.0.CO;2-R.

C. Gao and D. Yan, Prog. Polym. Sci., 29, 183 (2004); doi:10.1016/j.progpolymsci.2003.12.002.

C.R. Yates and W. Hayes, Eur. Polym. J., 40, 1257 (2004); doi:10.1016/j.eurpolymj.2004.02.007.

Y. Lin, K.Y. Zhang, Z.M. Dong, L.S. Dong and Y.S. Li, Macromolecules, 40, 6257 (2007); doi:10.1021/ma070989a.

Y. Hong, S.J. Coombs, J.J. Cooper-White, M.E. Mackay, C.J. Hawker, E. Malmström and N. Rehnberg, Polymer, 41, 7705 (2000); doi:10.1016/S0032-3861(00)00130-0.

R. Mezzenga, C.J.G. Plummer, L. Boogh and J.-A.E. Manson, Polymer, 42, 305 (2001); doi:10.1016/S0032-3861(00)00307-4.

R. Bhardwaj and A.K. Mohanty, Biomacromolecules, 8, 2476 (2007); doi:10.1021/bm070367x.

Y. Kikkawa, H. Abe, T. Iwata, Y. Inoue and Y. Doi, Biomacromolecules, 3, 350 (2002); doi:10.1021/bm015623z.

N. Ljungberg and B. Wesslen, Biomacromolecules, 6, 1789 (2005); doi:10.1021/bm050098f.

Y. Lin, K.Y. Zhang, Z.M. Dong, L.S. Dong and Y.S. Li, Macromolecules, 40, 6257 (2007); doi:10.1021/ma070989a.

R. Ratz and O.J. Sweeting, J. Org. Chem., 28, 1608 (1963); doi:10.1021/jo01041a043.

L.C. Wang, J.Q. Jiang, P.K. Jiang and J.H. Yu, J. Polym. Res., 17, 891 (2010); doi:10.1007/s10965-009-9381-9.

M.J. Sinclair and J.E. Watts, Fire Retardant Intumescent Coating, US Patent 7,217,753 (2003).

Issue

Vol. 26 No. 15 (2014): Vol 26 Issue 15

Preparation and Properties of Branched Poly(phosphoric ester) Oligomer and its Influences on Poly(L-lactide)

Corresponding Author(s) : Mingtao Run

Abstract

Keywords

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