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Vol. 26 No. 15 (2014): Vol 26 Issue 15

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Molecular Interactions in Binary Liquid Mixtures of Cyclohexanone with Morpholine, Bromobenzene and Anisole at 308.15 K and 318.15 K

https://doi.org/10.14233/ajchem.2014.16182
A. Rose Venis
Department of Chemistry, St. Joseph's College (Autonomous), Tiruchirappalli-620 002, India
X. Rosario Rajkumar
Oxford Engineering College, Tiruchirappalli-620 009, India

Corresponding Author(s) : A. Rose Venis

rosevenis@gmail.com

Asian Journal of Chemistry, Vol. 26 No. 15 (2014): Vol 26 Issue 15

Abstract

Densities, viscosities and ultrasonic velocities have been measured for the binary mixtures of cyclohexanone with morpholine, bromobenzene and anisole at 308.15 K and 318.15 K over the entire range of mole fraction. Thermodynamic parameters like excess volume, adiabatic compressibility, free volume, linear free energy, acoustic impedance and viscosity are calculated. From these values the excess properties are also calculated. The deviations of the liquid mixture from ideality have been explained based on the nature molecular interactions between unlike molecules.

Keywords

Density Viscosity Ultrasonic velocity Adiabatic compressibility Acoustic impedance
Rose Venis, A., & Rosario Rajkumar, X. (2014). Molecular Interactions in Binary Liquid Mixtures of Cyclohexanone with Morpholine, Bromobenzene and Anisole at 308.15 K and 318.15 K. Asian Journal of Chemistry, 26(15), 4711–4715. https://doi.org/10.14233/ajchem.2014.16182
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