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Vol. 31 No. 10 (2019): Vol 31 Issue 10

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Partial Molar Volumes and Spectral Studies on Binary Mixtures of p-Chloroacetophenone with Aniline and N-Alkyl Anilines

https://doi.org/10.14233/ajchem.2019.22094
M. Radha Sirija
Physico-Chemical Laboratory, Department of Chemistry, Acharya Nagarjuna University, Nagarjuna Nagar-522510, India
D. Bala
Physico-Chemical Laboratory, Department of Chemistry, Acharya Nagarjuna University, Nagarjuna Nagar-522510, India
D. Ramachandran
Physico-Chemical Laboratory, Department of Chemistry, Acharya Nagarjuna University, Nagarjuna Nagar-522510, India

Corresponding Author(s) : D. Ramachandran

dittakavirc@gmail.com

Asian Journal of Chemistry, Vol. 31 No. 10 (2019): Vol 31 Issue 10

Abstract

Ultrasonic velocities (u), viscosities (η) and densities (ρ) were measured for the binary mixtures of p-chloroacetophenone with aniline, N-methylaniline and N,N-dimethylaniline over the whole range of composition at different temperatures (303.15 K to 318.15 K) and at atmospheric pressure 0.1 MPa. Excess molar volume (VE), deviation in viscosity (Δη) and deviation in isentropic compressibility (Δks) have been calculated and fitted to Redlich-Kister polynomial equation to obtain their coefficients and standard deviations. The analyzed viscosity data of binary liquid mixtures were used to test the Grunberg-Nissan, Katti-Chaudari and Hind semi-empirical equations. The FTIR spectral study supports the experimental data to explain the molecular interactions between unlike molecules. Partial molar volumes of binary mixtures were evaluated for better understanding of intermolecular interactions of the above binary mixtures.

Keywords

Excess molar volume Partial molar volume Redlich-Kister polynomial equation Ultrasonic velocities
Sirija, M. R., Bala, D., & Ramachandran, D. (2019). Partial Molar Volumes and Spectral Studies on Binary Mixtures of p-Chloroacetophenone with Aniline and N-Alkyl Anilines. Asian Journal of Chemistry, 31(10), 2173–2180. https://doi.org/10.14233/ajchem.2019.22094
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