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Vol. 26 No. 15 (2014): Vol 26 Issue 15

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Synthesis, Structure, Properties and Time-Dependent Density Functional Theory Calculations of Cadmium Complex

https://doi.org/10.14233/ajchem.2014.16263
Wen-Tong Chen
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian Province, P.R. China
Rong-Hua Hu
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Xiu-Guang Yi
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Yin-Feng Wang
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Zhi-Gang Luo
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Hong-Ru Fu
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian Province, P.R. China
Juan Liu
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian Province, P.R. China
Hua-Long Chen
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China

Corresponding Author(s) : Wen-Tong Chen

wtchen_2000@aliyun.com

Asian Journal of Chemistry, Vol. 26 No. 15 (2014): Vol 26 Issue 15

Abstract

A cadmium complex CdCl2(2,2'-bipy)2 (1) (bipy = bipyridine) was obtained by a hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Photoluminescent study shows that complex 1 exhibits a greenish yellow emission. Theoretical investigations reveal that the emission is ascribed to the ligand-to-ligand charge transfer (LLCT). The spectral data of FT-IR were also reported.

Keywords

Bipyridine Crystal Ligand-to-ligand charge transfer Photoluminescence Time-dependent density functional theory
Chen, W.-T., Hu, R.-H., Yi, X.-G., Wang, Y.-F., Luo, Z.-G., Fu, H.-R., … Chen, H.-L. (2014). Synthesis, Structure, Properties and Time-Dependent Density Functional Theory Calculations of Cadmium Complex. Asian Journal of Chemistry, 26(15), 4865–4867. https://doi.org/10.14233/ajchem.2014.16263
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