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Vol. 26 No. 16 (2014): Vol 26 Issue 16

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Determination of Eucomic Acid in Chinese Hawthorn Fruit and Products by Gas Chromatography-Mass Spectrometry

https://doi.org/10.14233/ajchem.2014.16312
Zhe Gao
College of Food Science and Technology, Agricultural University of Hebei, Baoding 071001, Hebei Province, P.R. China
Rong-Fang Wang
College of Food Science and Technology, Agricultural University of Hebei, Baoding 071001, Hebei Province, P.R. China
Xiao-Hu Kang
College of Food Science and Technology, Agricultural University of Hebei, Baoding 071001, Hebei Province, P.R. China
Ai-Xia Qin
College of Food Science and Technology, Agricultural University of Hebei, Baoding 071001, Hebei Province, P.R. China
Ya-Nan Jia
College of Food Science and Technology, Agricultural University of Hebei, Baoding 071001, Hebei Province, P.R. China
Tong-Sen He
College of Food Science and Technology, Agricultural University of Hebei, Baoding 071001, Hebei Province, P.R. China
Yu-Lei Pan
College of Food Science and Technology, Agricultural University of Hebei, Baoding 071001, Hebei Province, P.R. China
Tong Cui
College of Food Science and Technology, Agricultural University of Hebei, Baoding 071001, Hebei Province, P.R. China

Corresponding Author(s) : Tong Cui

cuitong98@aliyun.com

Asian Journal of Chemistry, Vol. 26 No. 16 (2014): Vol 26 Issue 16

Abstract

An analytical method for determination of eucomic acid in Chinese hawthorn fruit and its products by gas chromatography-mass spectrometry (GC-MS) was developed. The sample was extracted by ethanol, esterificated with sulphuric acid-methanol solution and then extracted with dichloromethane. The final analysis was performed by GC-MS using the fragment ions m/z 107 under selected ion monitoring (SIM) for the content of eucomic acid. External standard method was used for quantification. Under optimum conditions, there was a good linearity within the range of 2-500 μg/g. The limit of detection was 0.35 μg/g, the recoveries were in the range 87-102 %, the relative standard deviation (RSD) was 3.1-5.6 %. This method was applied to determine the eucomic acid in hawthorn fruit and its products. The content is between 5.1-255 μg/g.

Keywords

Eucomic acid GC-MS Crataegus pinnatifida Flavor component Eucomic acid 1,4-dimethyl ester
Gao, Z., Wang, R.-F., Kang, X.-H., Qin, A.-X., Jia, Y.-N., He, T.-S., … Cui, T. (2014). Determination of Eucomic Acid in Chinese Hawthorn Fruit and Products by Gas Chromatography-Mass Spectrometry. Asian Journal of Chemistry, 26(16), 5053–5057. https://doi.org/10.14233/ajchem.2014.16312
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References
  1. H.H.S. Fong and J.L.J. Bauman, Cardiovasc. Nurs., 16, 1 (2002); doi:10.1097/00005082-200207000-00002.
  2. J.M. Rigelsky and B.V.H. Sweet, Am. J. Health Syst. Pharm., 59, 417 (2002).
  3. D.S. Ding and B.X. Li, Flavour Fragrance Cosmet., 57, 4 (1999).
  4. W. Heller and C. Tamm, Helv. Chim. Acta, 57, 1766 (1974); doi:10.1002/hlca.19740570628.
  5. T. Koizumi, Y. Isogai, S. Nomoto, K. Shudo and T. Okamoto, Phytochemistry, 15, 342 (1976); doi:10.1016/S0031-9422(00)89030-5.
  6. M. Ishii, S. Uemoto, K. Fujieda, M. Nonaka, Y. Shoyama, Y. Miyahara and I. Nishioka, Phytochemistry, 18, 1211 (1979); doi:10.1016/0031-9422(79)80137-5.
  7. J.Q. Jiang, W.C. Ye, Z. Chen, F.C. Lou and Z.D. Min, J. Chin. Pharm. Sci., 11, 1 (2002).
  8. A. Mun’Im, O. Negishi and T. Ozawa, Biosci. Biotechnol. Biochem., 67, 410 (2003); doi:10.1271/bbb.67.410.
  9. F.C. Stintzing and R. Carle, Mol. Nutr. Food Res., 49, 175 (2005); doi:10.1002/mnfr.200400071.
  10. J.Q. Jiang, Y.F. Li, Z. Chen, Z.D. Min and F.C. Lou, Steroids, 71, 1073 (2006); doi:10.1016/j.steroids.2006.09.005.
  11. C.E. Tovar-Gijón, B. Hernández-Carlos, E. Burgueño-Tapia, E. Cedillo-Portugal and P.J. Joseph-Nathan, Mol. Struct., 783, 96 (2006); doi:10.1016/j.molstruc.2005.08.024.
  12. G. Ginestra, M.L. Parker, R.N. Bennett, J. Robertson, G. Mandalari, A. Narbad, R.B. Lo Curto, G. Bisignano, C.B. Faulds and K.W.J. Waldron, Agric. Food Chem., 57, 10323 (2009); doi:10.1021/jf9022096.
  13. J.Y. Sun, X.R. Liu, H.Y. Wu and K. Liu, Food Drugs, 13, 441 (2011).
  14. M. Okada, S. Park, T. Koshizawa and M. Ueda, Tetrahedron, 65, 2136 (2009); doi:10.1016/j.tet.2008.11.097.
  15. C. Simmler, C. Antheaume, P. André, F. Bonté and A. Lobstein, J. Nat. Prod., 74, 949 (2011); doi:10.1021/np1006636.
  16. G.Y. Gao, Y.X. Feng and X.Q. Qin, Acta Pharmacol. Sin., 30, 138 (1995).
  17. X.Y. Shi and Y.H. Ma, Food Sci., 29, 297 (2008).
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