Copyright (c) 2014 AJC
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Layer-by-Layer Assembly of Graphene and Au@Pt Nanostructures and Its Application in Catalytic Oxidation of Methanol
Corresponding Author(s) : Jianfeng Fan
Asian Journal of Chemistry,
Vol. 26 No. 16 (2014): Vol 26 Issue 16
Abstract
Layer-by-layer films comprised of alternating graphene and Au@Pt nanostructures layers are readily produced by the three-step procedure involving the preparation of Au colloid, Au nanoparticles entering the layers of graphite, followed by Au@Pt nanostructures' formation by electrochemical methods on the graphene nanosheet. X-ray diffraction and Raman scattering showed the Au@Pt nanostructures/graphene was fabricated. Electrocatalytic properties of the resulting Au@Pt nanostructures/graphene electrode for methanol oxidation reaction were investigated. Compared with Au@Pt nanostructures/graphite, an appreciably improved electronic conductivity was observed for the Au@Pt nanostructures/graphene electrode.
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- J.L. Xiang and L.T. Drzal, Appl. Mater. Interfaces, 3, 1325 (2011); doi:10.1021/am200126x.
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References
J.L. Xiang and L.T. Drzal, Appl. Mater. Interfaces, 3, 1325 (2011); doi:10.1021/am200126x.
M.J. Allen, V.C. Tung and R.B. Kaner, Chem. Rev., 110, 132 (2010); doi:10.1021/cr900070d.
C. Xu, X. Wang and J.W. Zhu, J. Phys. Chem. C, 112, 19841 (2008); doi:10.1021/jp807989b.
E. Yoo, T. Okata, T. Akita, M. Kohyama, J. Nakamura and I. Honma, Nano Lett., 9, 2255 (2009); doi:10.1021/nl900397t.
Y.M. Li, L.H. Tang and J.H. Li, Electrochem. Commun., 11, 846 (2009); doi:10.1016/j.elecom.2009.02.009.
B. Seger and P.V. Kamat, J. Phys. Chem. C, 113, 7990 (2009); doi:10.1021/jp900360k.
C.Z. Zhu, S.J. Guo, Y.M. Zhai and S.J. Dong, Langmuir, 26, 7614 (2010); doi:10.1021/la904201j.
J. Lu, I. Do, L.T. Drzal, R.M. Worden and I. Lee, ACS Nano, 2, 1825 (2008); doi:10.1021/nn800244k.
S.J. Guo, D. Wen, Y.M. Zhai, S.J. Dong and E. Wang, ACS Nano, 4, 3959 (2010); doi:10.1021/nn100852h.
Y.C. Si and E.T. Samulski, Chem. Mater., 20, 6792 (2008); doi:10.1021/cm801356a.
Y.M. Li, X.J. Lv, J. Lu and J.H. Li, J. Phys. Chem. C, 114, 21770 (2010); doi:10.1021/jp1050047.
S.Y. Wang, X. Wang and S.P. Jiang, Phys. Chem. Chem. Phys., 13, 6883 (2011); doi:10.1039/c0cp02495c.
C.B. Liu, K. Wang, S.L. Luo, Y.H. Tang and L.Y. Chen, Small, 7, 1203 (2011); doi:10.1002/smll.201002340.
X.B. Yan, J.T. Chen, J. Yang, Q.J. Xue and P. Miele, Appl. Mater. Interfaces, 2, 2521 (2010); doi:10.1021/am100293r.
J. Lee, K.S. Novoselov and H.S. Shin, ACS Nano, 5, 608 (2011); doi:10.1021/nn103004c.
W.J. Zhao, P.H. Tan, J. Liu and A.C. Ferrari, J. Am. Chem. Soc., 133, 5941 (2011); doi:10.1021/ja110939a.
Y. Zhao, Y. E, L. Fan, Y. Qiu and S. Yang, Electrochim. Acta, 52, 5873 (2007); doi:10.1016/j.electacta.2007.03.020.