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Vol. 26 No. 16 (2014): Vol 26 Issue 16

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Experimental and Theoretical Studies of Ultrasonic Velocity in Ternary Liquid Mixtures of Methyl Benzoate, Cyclohexane and Alcohols at Different Temperatures

https://doi.org/10.14233/ajchem.2014.16557
Umadevi Muthukrishnan
Department of Physics, SVS College of Engineering, Coimbatore-642 109, India
Kesavasamy Ramasamy
Department of Physics, Sri Ramakrishna Engineering College, Coimbatore-641 022, India
Palani Rathinasamy
Department of Physics, Sri Ramakrishna Engineering College, Coimbatore-641 022, India
Priya Nachimuthu Senniappan
Department of Physics, DDE, Annamalai University, Chidambaram-608 002, India

Corresponding Author(s) : Umadevi Muthukrishnan

devuma55@gmail.com

Asian Journal of Chemistry, Vol. 26 No. 16 (2014): Vol 26 Issue 16

Abstract

Ultrasonic velocities of ternary liquid mixtures of methyl benzoate and cyclohexane with 1-propanol, 1-butanol, 1-pentanol and 1-hexanol are measured using ultrasonic interferometer at 303, 308 and 313 K over the entire range of composition. Theoretical values of ultrasonic velocity have been evaluated at the three temperatures using Nomoto's relation, ideal mixture relation, impedance relation, Junjie's method, Rao's specific velocity relation and free length theory. Theoretical values are compared with the experimental values and Uexp2/Uimx2 is evaluated for non-ideality in the mixtures. A good agreement has been found between experimental and theoretical values of ultrasonic velocity. The relative applicability of these theories to the present systems has been checked and discussed. The results are explained in terms of molecular interactions occurring in these ternary liquid mixtures.

Keywords

Ultrasonic velocity Methyl benzoate Cyclohexane Molecular interactions Theoretical models
Muthukrishnan, U., Ramasamy, K., Rathinasamy, P., & Nachimuthu Senniappan, P. (2014). Experimental and Theoretical Studies of Ultrasonic Velocity in Ternary Liquid Mixtures of Methyl Benzoate, Cyclohexane and Alcohols at Different Temperatures. Asian Journal of Chemistry, 26(16), 5142–5148. https://doi.org/10.14233/ajchem.2014.16557
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References
  1. J. Thennarasu and G. Meenakshi, Int. Interdiscipl. Res. J., 1, 43 (2011).
  2. N. Santhi, P. L. Sabarathinam, J. Madhumitha, G. Alamelumangai and M. Emayavaramban, Int. Lett. Chem. Phy. Astron., 2, 18 (2013).
  3. A. Ali, Abida, A.K. Nain and S. Hyder, J. Pure Appl. Ultrason., 23, 73 (2001).
  4. P.S. Naidu and K. Ravindra Prasad, J. Pure Appl. Ultrason, 24, 1824 (2002).
  5. C.H. Srinivasu, K. Narendra and C.H. Kalpana, E-J. Chem., 8, 977 (2011); doi:10.1155/2011/701547.
  6. A. Pal and H. Kumar, Indian J. Phys., 78, 1319 (2004).
  7. G.V.R. Rao, A.V. Sarma, J.S.R. Krishna and C. Rambabu, J. Indian Pure Appl. Phys., 43, 345 (2005).
  8. D. Saravana Kumar and D. Krishna Rao J. Indian Pure Appl. Phys., 45, 210 (2007).
  9. R. Uvarani and S. Punitha, E-J. Chem., 6(s1), 235 (2009); doi:10.1155/2009/836129.
  10. S. Parveen, D. Shukla, S. Singh, K.P. Singh, M. Gupta and J.P. Shukla, Appl. Acoust., 70, 507 (2009); doi:10.1016/j.apacoust.2008.05.008.
  11. O. Nomoto, J. Phys. Soc. Jpn., 13, 1528 (1958); doi:10.1143/JPSJ.13.1528.
  12. W. Van Dael and E. Vangeel, Proc Int Conf on Calorimetry and Thermodynamics, Warasa, p. 555 (1955).
  13. S. Baluja and P.H. Parsania, Asian J. Chem., 7, 417 (1995).
  14. V.D. Gokhale and N.N. Bhagavan, Indian J. Pure Appl. Ultrason., 11, 21 (1989).
  15. Z. Junjie, J. China Univ. Sci. Technol., 14, 298 (1984).
  16. G.V. Rama Rao, P.B. Sandhya Sri, A. Viswanatha Sarma, C. Rambabu and J. Indian, Pure Appl. Phys., 45, 135 (2007).
  17. K. Saravanaku, R. Baskaran and T.R. Kubendran, J. Appl. Sci., 10, 1616 (2010); doi:10.3923/jas.2010.1616.1621.
  18. S. Anuradha, S. Prema and K. Rajagopal, J. Pure Appl. Ultrason., 27, 49 (2005).
  19. N. Santhi, P.L. Sabarathinam, M.E. C. Gopi and C. Manivannan, E-J. Chem., 7, 648 (2010); doi:10.1155/2010/487874.
  20. M. Rastogi, A. Awasthi, M. Gupta and J.P. Shukla, J. Indian Pure Appl. Phys., 40, 256 (2002).
  21. P. Vasantharani, S. Muthu Shailaja, A.N. Kannappan and R. Ezhil Pavai, J. Appl. Sci., 8, 2329 (2008); doi:10.3923/jas.2008.2329.2332.
  22. S. Babu, S.V.K. Sastry, H.S. Tiong and S.S. Sastry, E-J. Chem., 9, 2309 (2012); doi:10.1155/2012/147940.
  23. G.R. Bedare, V.D. Bhandakkar and B.M. Suryavanshi, J. Chem. Pharm. Res., 4, 1028 (2012).
  24. A. Ali and A.K. Nain, J. Pure Appl. Ultrason., 22, 10 (2000).
  25. A. Ali, Abida, S. Hyder and A.K. Nain, Collect. Czech. Chem. Commun., 67, 1125 (2002); doi:10.1135/cccc20021125.
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