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Spectroscopic Characterization of Some Oxovanadium(IV, V) Complexes
Corresponding Author(s) : Shivadhar Sharma
Asian Journal of Chemistry,
Vol. 26 No. 16 (2014): Vol 26 Issue 16
Abstract
Six new oxovanadium(IV, V) complexes of N-bis(caproyl)hydroxamic acid, N-caproyl acetohydroxamic acids and N-caproyl benzohydroxamic acids have been synthesized. The synthesized hydroxamic acids and their oxovanadium(IV, V) complexes were characterized by melting point, running TLC for single spot, elemental analysis, IR, 1H NMR and electronic spectral studies. The spectral studies suggest distorted octahedral geometry for both V(IV) and V(V) metal complexes.
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- A. Isha, N.A. Yusof, M. Ahmad, D. Suhendra, W.M.Z.W. Yunus and Z. Zainal, Spectrochim. Acta, 67, 1398 (2007); doi:10.1016/j.saa.2006.10.031.
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- M. Koncic, Z. Rajic, N. Petric and B. Zorc, Acta Pharm., 59, 235 (2009); doi:10.2478/v10007-009-0017-8.
- Y.K. Agrawal, G. Shah and S.B. Vora, J. Radioanal. Nucl. Chem., 270, 453 (2006); doi:10.1007/s10967-006-0371-7.
- Y. K. Agarwal and C. R. Sharma, Indian J. Chem., 46A, 1772 (2007).
- S.I. Gorlovskii and Obroz Tsky Tovorang, Zauki, 38, 16 (1981).
- V.K. Agarwal and A.J. Midair, J. Indian Chem. Soc., 34, 757 (1977).
- H.R. Das and S.C. Shome, Anal. Chim. Acta, 35, 256 (1966); doi:10.1016/S0003-2670(01)81660-3.
- D.S. Antal, C.A. Dehelean, C.M. Canciu and M. Anke, J. Anaiele Univ. din Oradea Fascicula Biol., 2, 5 (2009).
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- M.A. Atkinson and N.K. Maclaren, Sci. Am., 260, 42 (1990).
- K.H. Thompson, J.H. McNeill and C. Orvig, Chem. Rev., 99, 2561 (1999); doi:10.1021/cr980427c.
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- S. Sharma, M. Kumar and T. Sharma, J. Indian Chem. Soc., 52, 761 (1985).
- R. Ranjan, R. Rani, V. Kumar, A.K. Singh Jr. and S. Sharma, J. Indian Chem. Soc., 85, 317 (2008).
- J. Fugita, K. Nakamoto and M. Kobayashi, J. Am. Chem. Soc., 78, 3963 (1956); doi:10.1021/ja01597a026.
- E. Wafa, M. Abu and E.I.M. Deekin, Indian J. Chem., 29A, 285 (1990).
- F. Mathis, Bull. Soc. Chem., D-9, 22 (1953).
- F.J. Fasha, M.S. Thesis, Wichita State University, Wichita Kansas (1957).
- E.M. Vsova and E.M. Voroshin, Dok-1 Akasd Nauk SSSR., 113, 1306 (1957).
- L.J. Bellamy, The Infra-red Spectra of Complex Molecules, John Wiley & Sons. Inc., New York (1958).
- A. Palm and H. Werbin, Can. J. Chem., 31, 1004 (1953); doi:10.1139/v53-132.
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- S. Pinchas and I. Lavtichat, Infra-red Spectra of Labelled Compounds, Academic Press, New York (1971).
- P.A. Giguère and I.D. Liu, Can. J. Chem., 30, 948 (1952); doi:10.1139/v52-115.
- A.K. Banerjee and P. Dharmprakash, J. Indian Chem. Soc., 55, 755 (1978).
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- B. Singh, B.P. Yadav and R.C. Agarwal, J. Indian Chem., 23A, 332 (1984).
- M. Kumar, A. Choudhary and S. Sharma, Indian J. Chem., 25A, 281 (1986).
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References
A. Isha, N.A. Yusof, M. Ahmad, D. Suhendra, W.M.Z.W. Yunus and Z. Zainal, Spectrochim. Acta, 67, 1398 (2007); doi:10.1016/j.saa.2006.10.031.
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L.P. Tardibono and M.J. Miller, Org. Lett., 7, 1575 (2009); doi:10.1021/ol900210h.
M. Koncic, Z. Rajic, N. Petric and B. Zorc, Acta Pharm., 59, 235 (2009); doi:10.2478/v10007-009-0017-8.
Y.K. Agrawal, G. Shah and S.B. Vora, J. Radioanal. Nucl. Chem., 270, 453 (2006); doi:10.1007/s10967-006-0371-7.
Y. K. Agarwal and C. R. Sharma, Indian J. Chem., 46A, 1772 (2007).
S.I. Gorlovskii and Obroz Tsky Tovorang, Zauki, 38, 16 (1981).
V.K. Agarwal and A.J. Midair, J. Indian Chem. Soc., 34, 757 (1977).
H.R. Das and S.C. Shome, Anal. Chim. Acta, 35, 256 (1966); doi:10.1016/S0003-2670(01)81660-3.
D.S. Antal, C.A. Dehelean, C.M. Canciu and M. Anke, J. Anaiele Univ. din Oradea Fascicula Biol., 2, 5 (2009).
T. Kiss, T. Jakusch, D. Hollender, Á. Dörnyei, É.A. Enyedy, J.C. Pessoa, H. Sakurai and A. Sanz-Medel, Coord. Chem. Rev., 252, 1153 (2008); doi:10.1016/j.ccr.2007.09.011.
M.A. Atkinson and N.K. Maclaren, Sci. Am., 260, 42 (1990).
K.H. Thompson, J.H. McNeill and C. Orvig, Chem. Rev., 99, 2561 (1999); doi:10.1021/cr980427c.
K.H. Thompson, J. Chiles, V.G. Yuen, J. Tse, J.H. McNeill and C. Orvig, J. Inorg. Biochem., 98, 683 (2004); doi:10.1016/j.jinorgbio.2004.01.006.
H. Sakurai, Y. Kojima, Y. Yoshikawa, K. Kawabe and H. Yasui, Coord. Chem. Rev., 226, 187 (2002); doi:10.1016/S0010-8545(01)00447-7.
K.H. Thompson and C. Orvig, J. Inorg. Biochem., 100, 1925 (2006); doi:10.1016/j.jinorgbio.2006.08.016.
S. Sharma, M. Kumar and T. Sharma, J. Indian Chem. Soc., 52, 761 (1985).
R. Ranjan, R. Rani, V. Kumar, A.K. Singh Jr. and S. Sharma, J. Indian Chem. Soc., 85, 317 (2008).
J. Fugita, K. Nakamoto and M. Kobayashi, J. Am. Chem. Soc., 78, 3963 (1956); doi:10.1021/ja01597a026.
E. Wafa, M. Abu and E.I.M. Deekin, Indian J. Chem., 29A, 285 (1990).
F. Mathis, Bull. Soc. Chem., D-9, 22 (1953).
F.J. Fasha, M.S. Thesis, Wichita State University, Wichita Kansas (1957).
E.M. Vsova and E.M. Voroshin, Dok-1 Akasd Nauk SSSR., 113, 1306 (1957).
L.J. Bellamy, The Infra-red Spectra of Complex Molecules, John Wiley & Sons. Inc., New York (1958).
A. Palm and H. Werbin, Can. J. Chem., 31, 1004 (1953); doi:10.1139/v53-132.
G. Allen, P.S. Ellington and G.D. Meakins, J. Chem. Soc., 1909 (1960); doi:10.1039/JR9600001909.
S. Pinchas and I. Lavtichat, Infra-red Spectra of Labelled Compounds, Academic Press, New York (1971).
P.A. Giguère and I.D. Liu, Can. J. Chem., 30, 948 (1952); doi:10.1139/v52-115.
A.K. Banerjee and P. Dharmprakash, J. Indian Chem. Soc., 55, 755 (1978).
J.F. Brown, J. Am. Chem. Soc., 77, 6341 (1955); doi:10.1021/ja01628a078.
B. Singh, B.P. Yadav and R.C. Agarwal, J. Indian Chem., 23A, 332 (1984).
M. Kumar, A. Choudhary and S. Sharma, Indian J. Chem., 25A, 281 (1986).
T. Ghosh, J. Indian Chem. Soc., 81, 957 (2004).
M.M. Patel, M.R. Patel and B.N. Mankad, J. Indian Chem. Soc., 54, 1188 (1977).
F.F. Bentley, L.D. Somothsen and A.L. Rojek, Infra-red Spectra and Characteristic Frequencies 700-300 cm-1, Interscience Publisher, London (1968).
W.J. Geary, Coord. Chem. Rev., 7, 81 (1971); doi:10.1016/S0010-8545(00)80009-0.