Copyright (c) 2026 Mohanambal Joyal, Andal Perumal, Anbarasu Mariyappillai

This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis and Characterisation of Micronutrient Based Copper Alginate and Ferric Alginate Beads for Agricultural Applications
Corresponding Author(s) : Andal Perumal
Asian Journal of Chemistry,
Vol. 38 No. 3 (2026): Vol 38 Issue 3, 2026
Abstract
The excessive use of chemical fertilizers has caused major environmental issues, emphasizing the need for sustainable nutrient delivery systems. In this work, copper and ferric alginate beads were synthesised using the ionotropic gelation method and analysed through UV-DRS, FTIR, FE-SEM, TGA, DSC and AAS techniques. The results showed that Cu2+ and Fe3+ ions had been successfully added. The copper beads had porous surfaces and the ferric beads had solid structures. Thermal studies showed that the material was more stable and AAS measured the metal contents at 18.2% Cu and 14.6% Fe. Pot experiments on black gram (Vigna mungo L.) showed that ferric alginate beads significant improved plant height (26.5 cm), pod number (32) and seed yield (6.82 g) compared to copper beads. Ferric beads also helped the roots grow better (8.8 cm, 0.75 g dry weight). Based on studies, ferric alginate beads demonstrate strong potential as eco-friendly slow-release fertilizers, while copper alginate beads provide comparatively moderate performance in supporting nutrient release.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- I. Yruela, Funct. Plant Biol., 32, 409 (2009); https://doi.org/10.1071/FP08288
- G. Aguirre and M. Pilon, Front. Plant Sci., 6, 1250 (2016); https://doi.org/10.3389/fpls.2015.01250
- N. Ahmed, B. Zhang, Z. Chachar, J. Li, G. Xiao, Q. Wang, F. Hayat, L. Deng, M.-N. Narejo, B. Bozdar and P. Tu, Sci. Hortic., 323, 112512 (2024); https://doi.org/10.1016/j.scienta.2023.112512
- J. Niu, C. Liu, M. Huang, K. Liu and D. Yan, J. Soil Sci. Plant Nutr., 21, 104 (2021); https://doi.org/10.1007/s42729-020-00346-3
- P.S. Bindraban, C. Dimkpa, L. Nagarajan, A. Roy and R. Rabbinge, Biol. Fertility Soils, 51, 897 (2015); https://doi.org/10.1007/s00374-015-1039-7
- M. Fagnano, D. Agrelli, A. Pascale, P. Adamo, N. Fiorentino, C. Rocco, O. Pepe and V. Ventorino, Sci. Total Environ., 734, 139434 (2020); https://doi.org/10.1016/j.scitotenv.2020.139434
- G. Poggere, A. Gasparin, J.Z. Barbosa, G.W. Melo, R.S. Corrêa and A.C.V. Motta, J. Trace Elem. Minerals, 4, 100059 (2023); https://doi.org/10.1016/j.jtemin.2023.100059
- Q. Chen, M. Gao, Z. Li, Y. Xiao, X. Bai, K.O. Boakye-Yiadom, X. Xu and X.-Q. Zhang, J. Controlled Rel., 323, 179 (2020); https://doi.org/10.1016/j.jconrel.2020.03.044
- C.S. Reshma, S. Remya and J. Bindu, Fishery Technol., 62, 16 (2025); https://doi.org/10.56093/ft.v62i1.153493
- A. Sharma and A.K. Singh, Colloids Interfaces, 9, 32 (2025); https://doi.org/10.3390/colloids9030032
- R.S. Alfinaikh, K.A. Alamry and M.A. Hussein, RSC Adv., 15, 4708 (2025); https://doi.org/10.1039/D4RA07277D
- Y. Wang, Z. Shen, H. Wang, Z. Song, D. Yu, G. Li, X. Liu and W. Liu, Gels, 11, 16 (2025); https://doi.org/10.3390/gels11010016
- Z. Zou, B. Zhang, X. Nie, Y. Cheng, Z. Hu, M. Liao and S. Li, RSC Adv., 10, 39722 (2020); https://doi.org/10.1039/d0ra04316h
- Y. Li, Y. Ma, F. Chang, H. Zhu, C. Tian, F. Jia, Y. Ke and J. Dai, Processes, 12, 842 (2024); https://doi.org/10.3390/pr12040842
- K. Yetilmezsoy, E. Kıyan and F. Ilhan, Int. J. Biol. Macromol., 279, 135382 (2024); https://doi.org/10.1016/j.ijbiomac.2024.135382
- M. Vinceković, S. Jurić, K. Vlahoviček-Kahlina, A. Novak, D. Ivić, L. Hazler, T. Jurkin, A. Bafti and N. Šijaković Vujičić, Sustainability, 16, 5637 (2024); https://doi.org/10.3390/su16135637
- H. Munigala, S. Singh, S.B. Vineetha and B.B. Christina, J. Exp. Agric. Int., 46, 22 (2024); https://doi.org/10.9734/jeai/2024/v46i72553
- W.I.S.T. Astuti, D.H. Wardhani, Ratnawati, E.A.P.P. Sagala and B.E.I. Siregar, Food Res., 8, 48 (2024); https://doi.org/10.26656/fr.2017.8(S1).7
- K.Z. Elwakeel, M.M. Ahmed, A. Akhdhar, M.G.M. Sulaiman and Z.A. Khan, Desalin. Water Treatment, 272, 50 (2022); https://doi.org/10.5004/dwt.2022.28834
- Z.A. Sutirman, M.M. Sanagi and W.I.W. Aini, Int. J. Biol. Macromol., 174, 216 (2021); https://doi.org/10.1016/j.ijbiomac.2021.01.150
- A. Raucci, M. Metitiero, C. Cuzzi, P.M. Kalligosfyri, M. Messina, M. Spinelli, A. Amoresano, S.L. Woo, I. Cacciotti and S. Cinti, Analyst, 149, 3302 (2024); https://doi.org/10.1039/D4AN00494A
- E. Kalantari, L. Lucia and N. Lavoine, Green Synth. Catal., 3, 179 (2022); https://doi.org/10.1016/j.gresc.2022.04.005
- D.T.B. Ngoc, D. Bui Duy, L.N.A. Tuan, B.D. Thach, T.P. Tho and D. Van Phu, Adv. Nat. Sci.: Nanosci. Nanotechnol., 12, 013001 (2021); https://doi.org/10.1088/2043-6262/abebd6
- R.D. Horniblow, M. Dowle, T.H. Iqbal, G.O. Latunde-Dada, R.E. Palmer, Z. Pikramenou and C. Tselepis, PLoS One, 10, e0138240 (2015); https://doi.org/10.1371/journal.pone.0138240
- S.K. Papageorgiou, E.P. Kouvelos, E.P. Favvas, A.A. Sapalidis, G.E. Romanos and F.K. Katsaros, Carbohydr. Res., 345, 469 (2010); https://doi.org/10.1016/j.carres.2009.12.010
- P. Tordi, F. Ridi, P. Samorì and M. Bonini, Adv. Funct. Mater., 35, 2416390 (2025); https://doi.org/10.1002/adfm.202416390
- Y. Wang, Z. Shen, H. Wang, Z. Song, D. Yu, G. Li, X. Liu and W. Liu, Gels, 11, 16 (2024); https://doi.org/10.3390/gels11010016
- L. Bahsis, E. Ablouh, H. Anane, M. Taourirte, M. Julve and S.-E. Stiriba, RSC Adv., 10, 32821 (2020); https://doi.org/10.1039/D0RA06410F
- T. Sapkota, S. Shrestha, B.P. Regmi and N. Bhattarai, RSC Adv., 15, 12876 (2025); https://doi.org/10.1039/D5RA01397F
- M. Elhoudi, R. Oukhrib, C. A. Celaya, D. G. Araiza, Y. Abdellaoui, I. Barra, Y. Brahmi, H. Bourzi, M. Reina, A. Albourine and H. Abou Oualid,, J. Mol. Model., 28, 37 (2022); https://doi.org/10.1007/s00894-022-05028-8
- Y. Kabalan, X. Montane, B. Tylkowski, S. De la Flor and M. Giamberini, Int. J. Biol. Macromol., 233, 123530 (2023); https://doi.org/10.1016/j.ijbiomac.2023.123530
- Y. Moglie, E. Buxaderas, A.G. Cabrera and D.D. Díaz, Front Chem., 13, 1644592 (2025); https://doi.org/10.3389/fchem.2025.1644592
- O. Churio, F. Pizarro and C. Valenzuela, Food Hydrocoll., 74, 1 (2018); https://doi.org/10.1016/j.foodhyd.2017.07.020
- T. Tavallali and M.D. Darvishzadeh, BMC Plant Biol., 25, 905 (2025); https://doi.org/10.1186/s12870‑025‑06930‑y
- G. Chen, J. Li, H. Han, R. Du and X. Wang, Int. J. Mol. Sci., 23, 12950 (2022); https://doi.org/10.3390/ijms232112950
- A. Sepehri and S. Norimanesh, Isfahan Univ. Technol.-J. Crop Prod. Process., 14, 47 (2024); https://doi.org/10.47176/jcpp.14.1.32192
- I.F. Carvalho, P.B. Alves, T.C. Ferreira, B.S. Santos, B.B. Cozin, R.P. Souza and L.S. Camargos, Rev. Caatinga, 38, e12686 (2024); https://doi.org/10.1590/1983-21252025v3812686rc
- G.R. Rout and S. Sahoo, Rev. Agric. Sci., 3, 1 (2015); https://doi.org/10.7831/ras.3.1
- M. Parveen and M. Muthukumaran, Int. J. Ecol. Environ. Sci., 49, 363 (2023); https://doi.org/10.55863/ijees.2023.2663
- H. Waheed, M.M. Javaid, A. Shahid, H.H. Ali, J. Nargis and A. Mehmood, J. Plant Nutr., 42, 1133 (2019); https://doi.org/10.1080/01904167.2019.1607380
- A. Javaid, Afr. J. Biotechnol., 8, 5189 (2009); https://doi.org/10.5897/AJB09.793
- A.M. Ashraf, H.A. Archana, R. Mahendran, J. Vanitha, S.N. Begam and V. Prakash, Indian J. Agric. Res., 59, (2025); https://doi.org/10.18805/IJARe.A-6155
- S. Alagarswamy, K.M. Karuppasami, P.B.R. Venugopal, S. Natarajan, M. Djanaguiraman, S. Rathinavelu, V. Dhashnamurthi, R. Veerasamy and B. Parasuraman, Plants, 13, 1549 (2024); https://doi.org/10.3390/plants13111549
- S. Chandwani, A. Gajera, M. Riddhi, H.A. Gamit and N. Amaresan, J. Appl. Microbiol., 134, lxad189 (2023); https://doi.org/10.1093/jambio/lxad189
- S. Sinha, S. Mondal, S. Maji, P. Dutta and P. Bandopadhyay, Legume Res., 1, 6 (2022); https://doi.org/10.18805/LR-4953
References
I. Yruela, Funct. Plant Biol., 32, 409 (2009); https://doi.org/10.1071/FP08288
G. Aguirre and M. Pilon, Front. Plant Sci., 6, 1250 (2016); https://doi.org/10.3389/fpls.2015.01250
N. Ahmed, B. Zhang, Z. Chachar, J. Li, G. Xiao, Q. Wang, F. Hayat, L. Deng, M.-N. Narejo, B. Bozdar and P. Tu, Sci. Hortic., 323, 112512 (2024); https://doi.org/10.1016/j.scienta.2023.112512
J. Niu, C. Liu, M. Huang, K. Liu and D. Yan, J. Soil Sci. Plant Nutr., 21, 104 (2021); https://doi.org/10.1007/s42729-020-00346-3
P.S. Bindraban, C. Dimkpa, L. Nagarajan, A. Roy and R. Rabbinge, Biol. Fertility Soils, 51, 897 (2015); https://doi.org/10.1007/s00374-015-1039-7
M. Fagnano, D. Agrelli, A. Pascale, P. Adamo, N. Fiorentino, C. Rocco, O. Pepe and V. Ventorino, Sci. Total Environ., 734, 139434 (2020); https://doi.org/10.1016/j.scitotenv.2020.139434
G. Poggere, A. Gasparin, J.Z. Barbosa, G.W. Melo, R.S. Corrêa and A.C.V. Motta, J. Trace Elem. Minerals, 4, 100059 (2023); https://doi.org/10.1016/j.jtemin.2023.100059
Q. Chen, M. Gao, Z. Li, Y. Xiao, X. Bai, K.O. Boakye-Yiadom, X. Xu and X.-Q. Zhang, J. Controlled Rel., 323, 179 (2020); https://doi.org/10.1016/j.jconrel.2020.03.044
C.S. Reshma, S. Remya and J. Bindu, Fishery Technol., 62, 16 (2025); https://doi.org/10.56093/ft.v62i1.153493
A. Sharma and A.K. Singh, Colloids Interfaces, 9, 32 (2025); https://doi.org/10.3390/colloids9030032
R.S. Alfinaikh, K.A. Alamry and M.A. Hussein, RSC Adv., 15, 4708 (2025); https://doi.org/10.1039/D4RA07277D
Y. Wang, Z. Shen, H. Wang, Z. Song, D. Yu, G. Li, X. Liu and W. Liu, Gels, 11, 16 (2025); https://doi.org/10.3390/gels11010016
Z. Zou, B. Zhang, X. Nie, Y. Cheng, Z. Hu, M. Liao and S. Li, RSC Adv., 10, 39722 (2020); https://doi.org/10.1039/d0ra04316h
Y. Li, Y. Ma, F. Chang, H. Zhu, C. Tian, F. Jia, Y. Ke and J. Dai, Processes, 12, 842 (2024); https://doi.org/10.3390/pr12040842
K. Yetilmezsoy, E. Kıyan and F. Ilhan, Int. J. Biol. Macromol., 279, 135382 (2024); https://doi.org/10.1016/j.ijbiomac.2024.135382
M. Vinceković, S. Jurić, K. Vlahoviček-Kahlina, A. Novak, D. Ivić, L. Hazler, T. Jurkin, A. Bafti and N. Šijaković Vujičić, Sustainability, 16, 5637 (2024); https://doi.org/10.3390/su16135637
H. Munigala, S. Singh, S.B. Vineetha and B.B. Christina, J. Exp. Agric. Int., 46, 22 (2024); https://doi.org/10.9734/jeai/2024/v46i72553
W.I.S.T. Astuti, D.H. Wardhani, Ratnawati, E.A.P.P. Sagala and B.E.I. Siregar, Food Res., 8, 48 (2024); https://doi.org/10.26656/fr.2017.8(S1).7
K.Z. Elwakeel, M.M. Ahmed, A. Akhdhar, M.G.M. Sulaiman and Z.A. Khan, Desalin. Water Treatment, 272, 50 (2022); https://doi.org/10.5004/dwt.2022.28834
Z.A. Sutirman, M.M. Sanagi and W.I.W. Aini, Int. J. Biol. Macromol., 174, 216 (2021); https://doi.org/10.1016/j.ijbiomac.2021.01.150
A. Raucci, M. Metitiero, C. Cuzzi, P.M. Kalligosfyri, M. Messina, M. Spinelli, A. Amoresano, S.L. Woo, I. Cacciotti and S. Cinti, Analyst, 149, 3302 (2024); https://doi.org/10.1039/D4AN00494A
E. Kalantari, L. Lucia and N. Lavoine, Green Synth. Catal., 3, 179 (2022); https://doi.org/10.1016/j.gresc.2022.04.005
D.T.B. Ngoc, D. Bui Duy, L.N.A. Tuan, B.D. Thach, T.P. Tho and D. Van Phu, Adv. Nat. Sci.: Nanosci. Nanotechnol., 12, 013001 (2021); https://doi.org/10.1088/2043-6262/abebd6
R.D. Horniblow, M. Dowle, T.H. Iqbal, G.O. Latunde-Dada, R.E. Palmer, Z. Pikramenou and C. Tselepis, PLoS One, 10, e0138240 (2015); https://doi.org/10.1371/journal.pone.0138240
S.K. Papageorgiou, E.P. Kouvelos, E.P. Favvas, A.A. Sapalidis, G.E. Romanos and F.K. Katsaros, Carbohydr. Res., 345, 469 (2010); https://doi.org/10.1016/j.carres.2009.12.010
P. Tordi, F. Ridi, P. Samorì and M. Bonini, Adv. Funct. Mater., 35, 2416390 (2025); https://doi.org/10.1002/adfm.202416390
Y. Wang, Z. Shen, H. Wang, Z. Song, D. Yu, G. Li, X. Liu and W. Liu, Gels, 11, 16 (2024); https://doi.org/10.3390/gels11010016
L. Bahsis, E. Ablouh, H. Anane, M. Taourirte, M. Julve and S.-E. Stiriba, RSC Adv., 10, 32821 (2020); https://doi.org/10.1039/D0RA06410F
T. Sapkota, S. Shrestha, B.P. Regmi and N. Bhattarai, RSC Adv., 15, 12876 (2025); https://doi.org/10.1039/D5RA01397F
M. Elhoudi, R. Oukhrib, C. A. Celaya, D. G. Araiza, Y. Abdellaoui, I. Barra, Y. Brahmi, H. Bourzi, M. Reina, A. Albourine and H. Abou Oualid,, J. Mol. Model., 28, 37 (2022); https://doi.org/10.1007/s00894-022-05028-8
Y. Kabalan, X. Montane, B. Tylkowski, S. De la Flor and M. Giamberini, Int. J. Biol. Macromol., 233, 123530 (2023); https://doi.org/10.1016/j.ijbiomac.2023.123530
Y. Moglie, E. Buxaderas, A.G. Cabrera and D.D. Díaz, Front Chem., 13, 1644592 (2025); https://doi.org/10.3389/fchem.2025.1644592
O. Churio, F. Pizarro and C. Valenzuela, Food Hydrocoll., 74, 1 (2018); https://doi.org/10.1016/j.foodhyd.2017.07.020
T. Tavallali and M.D. Darvishzadeh, BMC Plant Biol., 25, 905 (2025); https://doi.org/10.1186/s12870‑025‑06930‑y
G. Chen, J. Li, H. Han, R. Du and X. Wang, Int. J. Mol. Sci., 23, 12950 (2022); https://doi.org/10.3390/ijms232112950
A. Sepehri and S. Norimanesh, Isfahan Univ. Technol.-J. Crop Prod. Process., 14, 47 (2024); https://doi.org/10.47176/jcpp.14.1.32192
I.F. Carvalho, P.B. Alves, T.C. Ferreira, B.S. Santos, B.B. Cozin, R.P. Souza and L.S. Camargos, Rev. Caatinga, 38, e12686 (2024); https://doi.org/10.1590/1983-21252025v3812686rc
G.R. Rout and S. Sahoo, Rev. Agric. Sci., 3, 1 (2015); https://doi.org/10.7831/ras.3.1
M. Parveen and M. Muthukumaran, Int. J. Ecol. Environ. Sci., 49, 363 (2023); https://doi.org/10.55863/ijees.2023.2663
H. Waheed, M.M. Javaid, A. Shahid, H.H. Ali, J. Nargis and A. Mehmood, J. Plant Nutr., 42, 1133 (2019); https://doi.org/10.1080/01904167.2019.1607380
A. Javaid, Afr. J. Biotechnol., 8, 5189 (2009); https://doi.org/10.5897/AJB09.793
A.M. Ashraf, H.A. Archana, R. Mahendran, J. Vanitha, S.N. Begam and V. Prakash, Indian J. Agric. Res., 59, (2025); https://doi.org/10.18805/IJARe.A-6155
S. Alagarswamy, K.M. Karuppasami, P.B.R. Venugopal, S. Natarajan, M. Djanaguiraman, S. Rathinavelu, V. Dhashnamurthi, R. Veerasamy and B. Parasuraman, Plants, 13, 1549 (2024); https://doi.org/10.3390/plants13111549
S. Chandwani, A. Gajera, M. Riddhi, H.A. Gamit and N. Amaresan, J. Appl. Microbiol., 134, lxad189 (2023); https://doi.org/10.1093/jambio/lxad189
S. Sinha, S. Mondal, S. Maji, P. Dutta and P. Bandopadhyay, Legume Res., 1, 6 (2022); https://doi.org/10.18805/LR-4953