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Vol. 26 No. 19 (2014): Vol 26 Issue 19

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Synthesis and Structural Characterization of Diiron Ethanedithiolate Complex [(μ-SCH2)2Fe2(CO)4](PPh3)2 Related to the Active Site of [Fe-Fe]-Hydrogenases

https://doi.org/10.14233/ajchem.2014.16763
Wei Gao
School of Pharmacy, Henan University of Traditional Chinese Medicine, Zhengzhou 450046, P.R. China
Ting-Ting Zhang
School of Pharmacy, Henan University of Traditional Chinese Medicine, Zhengzhou 450046, P.R. China
Yan-Jun Sun
School of Pharmacy, Henan University of Traditional Chinese Medicine, Zhengzhou 450046, P.R. China

Corresponding Author(s) : Yan-Jun Sun

weigao415@aliyun.com

Asian Journal of Chemistry, Vol. 26 No. 19 (2014): Vol 26 Issue 19

Abstract

A diiron ethanedithiolate complex [(μ-SCH2)2Fe2(CO)4](PPh3)2 (1), as the active site of [Fe-Fe]-hydrogenases, has been prepared and characterized. The title complex was prepared by reaction of [(μ-SCH2)2]Fe2(CO)6 (A) with PPh3 at reflux in xylene in 50 % yield. The new complex was characterized by IR, 1H NMR, 31P NMR and 13C NMR spectroscopy.

Keywords

Diiron ethanedithiolate Triphenylphosphine Synthesis Characterization
Gao, W., Zhang, T.-T., & Sun, Y.-J. (2014). Synthesis and Structural Characterization of Diiron Ethanedithiolate Complex [(μ-SCH2)2Fe2(CO)4](PPh3)2 Related to the Active Site of [Fe-Fe]-Hydrogenases. Asian Journal of Chemistry, 26(19), 6687–6688. https://doi.org/10.14233/ajchem.2014.16763
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