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Vol. 26 No. 21 (2014): Vol 26 Issue 21

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Solvothermal Synthesis, Crystal Structure and Luminescent Property of Metal-Organic Frameworks with New Topology Built from Tetrazole Ligand

https://doi.org/10.14233/ajchem.2014.17859
Chenghua Zeng
School of Resource and Environmental Engineering, Panzhihua University, Panzhihua City 617000, Sichuan Province, P.R. China

Corresponding Author(s) : Chenghua Zeng

zch1963111@163.com

Asian Journal of Chemistry, Vol. 26 No. 21 (2014): Vol 26 Issue 21

Abstract

A novel two-dimensional (2D) Zn(II) metal-organic frameworks [Zn2(H2bdc)(ATZ)2.5(H2O)·2(H2O)] (1; H2bdc = 1,4-benzenedicarboxylate; ATZ = 5-aminotetrazole) has been solvothermally prepared and structurally characterized by single-crystal X-ray diffraction, which shows that compound 1 crystallized in the orthorhombic space group Pbcm with a = 10.2647(3) Å, b = 26.1194(12) Å, c = 27.3699(13) Å, a = b = g = 90°, V = 7338.1(5) Å3 and Z = 4. Compound 1 exhibits a layered structure with 3,4-connected new topology, and further stacking of layers leads to a 3D supramolecular framework. The thermalgravimatric behaviour and luminescent properties of 1 have been also investigated. The compound exhibits an intense photoluminescence emissions at 450 nm (lex = 375 nm).

Keywords

Solvothermal Crystal structure Luminescent Metal-organic frameworks Tetrazole
Zeng, C. (2014). Solvothermal Synthesis, Crystal Structure and Luminescent Property of Metal-Organic Frameworks with New Topology Built from Tetrazole Ligand. Asian Journal of Chemistry, 26(21), 7472–7474. https://doi.org/10.14233/ajchem.2014.17859
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References
  1. B.F. Hoskins and R. Robson, J. Am. Chem. Soc., 111, 5962 (1989); doi:10.1021/ja00197a079.
  2. S. Kitagawa, R. Kitaura and S.I. Noro, Angew. Chem. Int. Ed., 43, 2334 (2004); doi:10.1002/anie.200300610.
  3. K. Barthelet, J. Marrot, D. Riou and G. Ferey, Angew. Chem. Int. Ed., 41, 281 (2002); doi:10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO;2-Y.
  4. X.L. Wang, C. Qin, S.X. Wu, K.Z. Shao, Y.Q. Lan, S. Wang, D.X. Zhu, Z.M. Su and E.B. Wang, Angew. Chem. Int. Ed., 48, 5291 (2009); doi:10.1002/anie.200902274.
  5. K. Ove Kongshaug and H. Fjellvåg, Polyhedron, 26, 5113 (2007); doi:10.1016/j.poly.2007.07.045.
  6. K.O. Kongshaug and H. Fjellvåg, Solid State Sci., 5, 303 (2003); doi:10.1016/S1293-2558(03)00005-0.
  7. H.R. Moon, N. Kobayashi and M.P. Suh, Inorg. Chem., 45, 8672 (2006); doi:10.1021/ic0611948.
  8. Y. Liu, G. Li, X. Li and Y. Cui, Angew. Chem. Int. Ed., 46, 6301 (2007); doi:10.1002/anie.200701056.
  9. P.K. Chen, S.R. Batten, Y. Qi and J.M. Zheng, Cryst. Growth Des., 9, 2756 (2009); doi:10.1021/cg8013893.
  10. G. Ferey, C. Mellot-Draznieks, C. Serre and F. Millange, Acc. Chem. Res., 38, 217 (2005); doi:10.1021/ar040163i.
  11. K. Ove Kongshaug and H. Fjellvåg, Polyhedron, 26, 5113 (2007); doi:10.1016/j.poly.2007.07.045.
  12. A.I. Lesnikovich, O.A. Ivashkevich, S.V. Levchik, A.I. Balabanovich, P.N. Gaponik and A.A. Kulak, Thermochim. Acta, 388, 233 (2002); doi:10.1016/S0040-6031(02)00027-8.
  13. X.W. Wang, J.Z. Chen and J.H. Liu, Cryst. Growth Des., 7, 1227 (2007); doi:10.1021/cg070330w.
  14. Z.Z. Lin, F.L. Jiang, D.Q. Yuan, L. Chen, Y.F. Zhou and M.C. Hong, Eur. J. Inorg. Chem., 2005, 1927 (2005); doi:10.1002/ejic.200400968.
  15. X.M. Lu, P.Z. Li, X.T. Wang, S. Gao, X.J. Wang, S. Wang, Y.H. Deng, Y.J. Zhang and L. Zhou, Polyhedron, 27, 2402 (2008); doi:10.1016/j.poly.2008.04.029.
  16. X.W. Wang, J.Z. Chen and J.H. Liu, Cryst. Growth Des., 7, 1227 (2007); doi:10.1021/cg070330w.
  17. J. Neutz, O. Grosshardt, S. Schäufele, H. Schuppler and W. Schweikert, Pyrotech., 28, 181 (2003); doi:10.1002/prep.200300003.
  18. Z.P. Demko and K.B. Sharpless, Org. Lett., 4, 2525 (2002); doi:10.1021/ol020096x.
  19. A.R. Katritzky, B.V. Rogovoy and K.V. Kovalenko, J. Org. Chem., 68, 4941 (2003); doi:10.1021/jo0266543.
  20. G.M. Sheldrick, SADABS, Program for Area Detector Adsorption Correction; Institute for Inorganic Chemistry, University of Göttingen: Göttingen, Germany (1996).
  21. G.M. Sheldrick, SHELXL-97, Program for Solution of Crystal Structures; University of Göttingen: Göttingen, Germany (1997).
  22. L. Zhao and F. Guo, Z. Anorg. Allg. Chem., 640, 168 (2014); doi:10.1002/zaac.201300298.
  23. J.Y. Wang and H.P. You, Z. Anorg. Allg. Chem., 637, 415 (2011); doi:10.1002/zaac.201000315.
  24. K. Jiang, L.F. Ma, X.Y. Sun and L.Y. Wang, CrystEngComm, 13, 330 (2010); doi:10.1039/c0ce00190b.
  25. G.Z. Liu, L.Y. Xin and L.Y. Wang, CrystEngComm, 13, 3013 (2011); doi:10.1039/c0ce00873g.
  26. W.L. Liu, J.H. Yu, J.X. Jiang, L.M. Yuan, B. Xu, Q. Liu, B.T. Qu, G.Q. Zhang and C.G. Yan, CrystEngComm, 13, 2764 (2011); doi:10.1039/c0ce00950d.
  27. K. Liu, W. Shi and P. Cheng, Dalton Trans., 40, 8475 (2011); doi:10.1039/c0dt01578d.
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