Synthesis, Crystal Structure and Spectra Properties of Cd(II) Complex with 1,5-Diamino-3-oxapentane

Congfen Li; Yuchen Bai; Furong Shi; Zaihui Yang; Cuiping Wang; Huilu Wu

doi:10.14233/ajchem.2014.16565

Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Issue Published : September 30, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Crystal Structure and Spectra Properties of Cd(II) Complex with 1,5-Diamino-3-oxapentane

https://doi.org/10.14233/ajchem.2014.16565

Congfen Li

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, Gansu Province, P.R. China

Yuchen Bai

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, Gansu Province, P.R. China

Furong Shi

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, Gansu Province, P.R. China

Zaihui Yang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, Gansu Province, P.R. China

Cuiping Wang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, Gansu Province, P.R. China

Huilu Wu

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, Gansu Province, P.R. China

Corresponding Author(s) : Huilu Wu

wuhuilu@163.com

Asian Journal of Chemistry, Vol. 26 No. 21 (2014): Vol 26 Issue 21
Article Published : September 30, 2014

Abstract

A new complex of the cadmium(II) nitrate with 1,5-diamino-3-oxapentane (L), with the composition is [Cd(L)(NO₃)₂], was synthesized and characterized by elemental analyses and IR spectra. The crystal structure of the complex has been determined by the single-crystal X-ray diffraction. The molecular structure consists of a ligand L, two nitrate radical and a Cd (II) atom. In the complex, the Cd(II) atom is N, O, N'-chelated by a ligand L and is further coordinated by two nitrate anions in a distorted monocapped octahedral geometry. The crystal structure is mainly stabilized by the intermolecular hydrogen bond.

Keywords

Crystal structure Cadmium complex Spectra property

Li, C., Bai, Y., Shi, F., Yang, Z., Wang, C., & Wu, H. (2014). Synthesis, Crystal Structure and Spectra Properties of Cd(II) Complex with 1,5-Diamino-3-oxapentane. Asian Journal of Chemistry, 26(21), 7201–7203. https://doi.org/10.14233/ajchem.2014.16565

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References

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T.W.G. Solomons and C.B. Fryhle, Organic Chemistry, John Wiley & Sons, Inc., New York, edn. 10, Ch. 20, p. 1024 (2010).

L.H. Zhang, X.Q. Li, Y.S. Zhou and X. Wang, J. Mol. Struct., 928, 59 (2009); doi:10.1016/j.molstruc.2009.03.015.

A. De Robertis, C. Foti, O. Giuffrè and S. Sammartano, J. Chem. Eng. Data, 46, 1425 (2001); doi:10.1021/je010143g.

N.G. Tsierkezos, D. Schröder and H. Schwarz, Int. J. Mass Spectrom., 235, 33 (2004); doi:10.1016/j.ijms.2004.03.005.

S. Deng, R.B. Bai and J.P. Chen, Langmuir, 19, 5058 (2003); doi:10.1021/la034061x.

N. Li and R.B. Bai, Ind. Eng. Chem. Res., 44, 6692 (2005); doi:10.1021/ie050145k.

C.K. Liu, R.B. Bai and L. Hong, J. Colloid Interf. Sci., 303, 99 (2006); doi:10.1016/j.jcis.2006.07.057.

C. Lodeiro and F. Pina, Coord. Chem. Rev., 253, 1353 (2009); doi:10.1016/j.ccr.2008.09.008.

M.T. Oms, R. Forteza, V. Cerda and F. Borrull, Thermochim. Acta, 138, 1 (1989); doi:10.1016/0040-6031(89)87235-1.

J.N. Jolley, A.I. Yanovsky, L.R. Kelland and K.B. Nolan, J. Inorg. Biochem., 83, 91 (2001); doi:10.1016/S0162-0134(00)00190-2.

M.W. Ndinguri, F.R. Fronczek, P.A. Marzilli, W.E. Crowe, R.P. Hammer and L.G. Marzilli, Inorg. Chim. Acta, 363, 1796 (2010); doi:10.1016/j.ica.2010.02.027.

W. Shen, S.Y. Chen, S.K. Shi, X. Li, X. Zhang, W.L. Hu and H.P. Wang, Carbohydr. Polym., 75, 110 (2009); doi:10.1016/j.carbpol.2008.07.006.

S.I. Ali and K. Majid, Thermochim. Acta, 317, 141 (1998); doi:10.1016/S0040-6031(98)00373-6.

R.L. Fanshawe, A. Mobinikhaledi, C.R. Clark and A.G. Blackman, Inorg. Chim. Acta, 307, 26 (2000); doi:10.1016/S0020-1693(00)00184-5.

P.C. Junk and J.W. Steed, Inorg. Chim. Acta, 360, 1661 (2007); doi:10.1016/j.ica.2006.09.001.

S.M. Nelson and C.V. Knox, J. Chem. Dalton Transac., 2525 (1983); doi:10.1039/dt9830002525.

Bruker, SAINT and SMART, Bruker AXS Inc., Madison, Wisconsin, USA (2001).

G.M. Sheldrick, SADABS. University of Göttingen, Germany (2001).

G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.

K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons, New York, edn 4, p. 284 (1986).

W.K. Dong, Y.X. Sun, C.Y. Zhao, X.Y. Dong and L. Xu, Polyhedron, 29, 2087 (2010); doi:10.1016/j.poly.2010.04.006.

W.-K. Dong, J.-G. Duan, Y.-H. Guan, J.-Y. Shi and C.-Y. Zhao, Inorg. Chim. Acta, 362, 1129 (2009); doi:10.1016/j.ica.2008.05.028.

D.H. Kang, J.B. Seo, S.Y. Lee, J.Y. Lee, K.S. Choi and S.S. Lee, Inorg. Chem. Commun., 10, 1425 (2007); doi:10.1016/j.inoche.2007.09.003.

Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Synthesis, Crystal Structure and Spectra Properties of Cd(II) Complex with 1,5-Diamino-3-oxapentane

Corresponding Author(s) : Huilu Wu

Abstract

Keywords

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