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Preparation of Sodium Sulfonates Using by Copper as Catalyst
Corresponding Author(s) : Xilong Yan
Asian Journal of Chemistry,
Vol. 26 No. 21 (2014): Vol 26 Issue 21
Abstract
The sodium alkyl sulfonates were prepared by Strecker reaction. The synthesis of sodium chloroethyl sulfonate from dichloroethane and sodium sulfite with different catalysts, it was found that copper was an efficient catalyst with a yield (81 %). The reaction conditions were also optimized to make the route more competitive and suitable for large-scale industrial production. Besides, some more sulfonates were also obtained with copper as catalyst via Strecker reaction.
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- K. Kosswing, Surfactants, in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH: Weinheim, edn 6 (2005).
- R. Loos and R. Niessner, J. Chromatogr. A, 882, 291 (1998); doi:10.1016/S0021-9673(98)00620-7.
- M.A. Castles, B.L. Moore and S.R. Ward, Anal. Chem., 61, 2534 (1989); doi:10.1021/ac00197a016.
- A. Marcomini, A. Di Corcia, R. Samperi and S. Capri, J. Chromatogr. A, 644, 59 (1993); doi:10.1016/0021-9673(93)80120-W.
- S.A. Shamsi and N.D. Danielson, Anal. Chem., 67, 4210 (1995); doi:10.1021/ac00118a027.
- B. Altenbach and W. Giger, Anal. Chem., 67, 2325 (1995); doi:10.1021/ac00110a002.
- P. Jandera, J. Fischer, V. Stanek, M. Kucerova and P. Zvonicek, J. Chromatogr. A, 738, 201 (1996); doi:10.1016/0021-9673(96)00082-9.
- J. Fischer, P. Jandera and V. Stanek, J. Chromatogr. A, 772, 385 (1997); doi:10.1016/S0021-9673(97)00076-9.
- T. Reemtsma, J. Chromatogr. A, 733, 473 (1996); doi:10.1016/0021-9673(95)00738-5.
- J.P. Guthrie, Can. J. Chem., 56, 2342 (1978); doi:10.1139/v78-385.
- V.R. Dhanuka, V.C. Malshe and S.B. Chandalia, Chem. Eng. Sci., 32, 551 (1977); doi:10.1016/0009-2509(77)87013-9.
- R.D. Badley and W.T. Ford, J. Org. Chem., 54, 5437 (1989); doi:10.1021/jo00284a014.
- Q. Zhou, Fine Chemicals, 03, 59 (1995).
- L. Cohen and Y.M. Han, China Cleaning Industry, 02, 54, 63 (2011).
- H. Zhou, J. Chen, X. Zhang, G. Tang and Q. Yang, China Leather, 31, 29 (2002).
- Z. Huang, S. Chen, T. Zhang, H. Lu and H. Quan, Special. Petrochem., 28, 50 (2011).
- J. Hu, Chem. Prod. Technol., 16, 23 (2009).
- P. Tang, Fine Organic Synthetic Chemistry and Technology, Tianjin University Press: HuanYang, edn 2, p. 136 (2007).
- N.E. Good, G.D. Winget, W. Winter, T.N. Connolly, S. Izawa and R.M.M. Singh, Biochemistry, 5, 467 (1966); doi:10.1021/bi00866a011.
- J.W. Schick and E.F. Degering, Ind. Eng. Chem., 39, 906 (1947); doi:10.1021/ie50451a024.
- F.M. Beringer and R.A. Falk, J. Am. Chem. Soc., 81, 2997 (1959); doi:10.1021/ja01521a020.
- C. Benod, G. Subra, V. Nahoum, A. Mallavialle, J.-F. Guichou, J. Milhau, S. Roblés, W. Bourguet, J.-M. Pascussi and P. Balaguer, Bioorg. Med. Chem., 16, 3537 (2008); doi:10.1016/j.bmc.2008.02.020.
- K. Fujimori, Bull. Chem. Soc. Jpn., 32, 850 (1959); doi:10.1246/bcsj.32.850.
- R. Reed and H.V. Tartar, J. Am. Chem. Soc., 57, 570 (1935); doi:10.1021/ja01306a055.
References
K. Kosswing, Surfactants, in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH: Weinheim, edn 6 (2005).
R. Loos and R. Niessner, J. Chromatogr. A, 882, 291 (1998); doi:10.1016/S0021-9673(98)00620-7.
M.A. Castles, B.L. Moore and S.R. Ward, Anal. Chem., 61, 2534 (1989); doi:10.1021/ac00197a016.
A. Marcomini, A. Di Corcia, R. Samperi and S. Capri, J. Chromatogr. A, 644, 59 (1993); doi:10.1016/0021-9673(93)80120-W.
S.A. Shamsi and N.D. Danielson, Anal. Chem., 67, 4210 (1995); doi:10.1021/ac00118a027.
B. Altenbach and W. Giger, Anal. Chem., 67, 2325 (1995); doi:10.1021/ac00110a002.
P. Jandera, J. Fischer, V. Stanek, M. Kucerova and P. Zvonicek, J. Chromatogr. A, 738, 201 (1996); doi:10.1016/0021-9673(96)00082-9.
J. Fischer, P. Jandera and V. Stanek, J. Chromatogr. A, 772, 385 (1997); doi:10.1016/S0021-9673(97)00076-9.
T. Reemtsma, J. Chromatogr. A, 733, 473 (1996); doi:10.1016/0021-9673(95)00738-5.
J.P. Guthrie, Can. J. Chem., 56, 2342 (1978); doi:10.1139/v78-385.
V.R. Dhanuka, V.C. Malshe and S.B. Chandalia, Chem. Eng. Sci., 32, 551 (1977); doi:10.1016/0009-2509(77)87013-9.
R.D. Badley and W.T. Ford, J. Org. Chem., 54, 5437 (1989); doi:10.1021/jo00284a014.
Q. Zhou, Fine Chemicals, 03, 59 (1995).
L. Cohen and Y.M. Han, China Cleaning Industry, 02, 54, 63 (2011).
H. Zhou, J. Chen, X. Zhang, G. Tang and Q. Yang, China Leather, 31, 29 (2002).
Z. Huang, S. Chen, T. Zhang, H. Lu and H. Quan, Special. Petrochem., 28, 50 (2011).
J. Hu, Chem. Prod. Technol., 16, 23 (2009).
P. Tang, Fine Organic Synthetic Chemistry and Technology, Tianjin University Press: HuanYang, edn 2, p. 136 (2007).
N.E. Good, G.D. Winget, W. Winter, T.N. Connolly, S. Izawa and R.M.M. Singh, Biochemistry, 5, 467 (1966); doi:10.1021/bi00866a011.
J.W. Schick and E.F. Degering, Ind. Eng. Chem., 39, 906 (1947); doi:10.1021/ie50451a024.
F.M. Beringer and R.A. Falk, J. Am. Chem. Soc., 81, 2997 (1959); doi:10.1021/ja01521a020.
C. Benod, G. Subra, V. Nahoum, A. Mallavialle, J.-F. Guichou, J. Milhau, S. Roblés, W. Bourguet, J.-M. Pascussi and P. Balaguer, Bioorg. Med. Chem., 16, 3537 (2008); doi:10.1016/j.bmc.2008.02.020.
K. Fujimori, Bull. Chem. Soc. Jpn., 32, 850 (1959); doi:10.1246/bcsj.32.850.
R. Reed and H.V. Tartar, J. Am. Chem. Soc., 57, 570 (1935); doi:10.1021/ja01306a055.