Thermal and Morphological Studies on Bismaleimide Modified ZnO Nanoparticles

M. Vadivel; M. Suresh Chandra kumar; V. Selvam; Sutha Shobana; S. Arvind Narayan

doi:10.14233/ajchem.2014.16537

Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Issue Published : September 30, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Thermal and Morphological Studies on Bismaleimide Modified ZnO Nanoparticles

https://doi.org/10.14233/ajchem.2014.16537

M. Vadivel

Polymer Nanocomposite Centre, Department of Chemistry & Research Centre, Scott Christian College, Nagercoil-629 003, India

M. Suresh Chandra kumar

Polymer Nanocomposite Centre, Department of Chemistry & Research Centre, Scott Christian College, Nagercoil-629 003, India

V. Selvam

Polymer Nanocomposite Centre, Department of Chemistry & Research Centre, Scott Christian College, Nagercoil-629 003, India

Sutha Shobana

Department of Chemistry, Rajas Institute of Technology for Women, Ozhuginaseri, Nagercoil-629 001, India

S. Arvind Narayan

Faculty of Science and Humanities K.N.S.K. College of Engineering, Therekalputhoor, Nagercoil-629 901, India

Corresponding Author(s) : M. Suresh Chandra kumar

vadivelche@rediffmail.com

Asian Journal of Chemistry, Vol. 26 No. 21 (2014): Vol 26 Issue 21
Article Published : September 30, 2014

Abstract

The bismaleimide (N,N'-bismaleimide-4,4'-diphenylmethane) (BMI) modified siliconized zinc oxide nanoparticles were prepared in chloroform. The FT-IR spectroscopy analysis of BMI/ZnO reveals that -NH₂ groups of siliconized ZnO reacts with the maleimide double bond of bismaleimide molecules through a nucleophilic (Michael) addition reaction. The thermal (TG) and morphological properties of bismaleimide modified zinc oxide nanoparticles (BMI/ZnO), were investigated. The particle size and morphology of zinc oxide nanoparticles and siliconized zinc oxide nanoparticles were determined by XRD. The SEM images indicate that the diameter of the zinc oxide nanoparticles is in the range of 25-40 nm with a strong aggregation process. It is observed that aggregates of bismaleimide modified siliconized zinc oxide nanocomposites of different size and shape are heterogeneously distributed in the elastomeric surface due to the low shear stress and processing time, which do not make an exfoliated material.

Keywords

Bismaleimide modified zinc oxide nanoparticles FT-IR XRD TG SEM

Vadivel, M., Suresh Chandra kumar, M., Selvam, V., Shobana, S., & Arvind Narayan, S. (2014). Thermal and Morphological Studies on Bismaleimide Modified ZnO Nanoparticles. Asian Journal of Chemistry, 26(21), 7160–7164. https://doi.org/10.14233/ajchem.2014.16537

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P. Liu, Eng. Aspects, 291, 155 (2006); doi:10.1016/j.colsurfa.2006.05.007.

F.F. Zhang, X.L. Wang, S.Y. Ai, Z.D. Sun, Q. Wan, Z.Q. Zhu, Y.Z. Xian, L.T. Jin and K. Yamamoto, Anal. Chim. Acta, 519, 155 (2004); doi:10.1016/j.aca.2004.05.070.

X.L. Zhu, I. Yuri, X. Gan, I. Suzuki and G.X. Li, Biosens. Bioelectron., 22, 1600 (2007); doi:10.1016/j.bios.2006.07.007.

A.P.A. Oliveria, J.F. Hochepied, F. Grillion and M.H. Berger, Chem. Mater., 15, 3202 (2003); doi:10.1021/cm0213725.

M. Yin, Y. Gu, I.L. Kuskovsky, T. Andelman, Y. Zhu, G.F. Neumark and S. O’Brien, J. Am. Chem. Soc., 126, 6206 (2004); doi:10.1021/ja031696+.

T. Pauporte, T. Yoshida, A. Goux and D. Lincot, Electroanal. J. Chem., 534, 55 (2002); doi:10.1016/S0022-0728(02)01105-1.

J. Zheng, R. Ozisik and R.W. Siegel, Polymer, 46, 10873 (2005); doi:10.1016/j.polymer.2005.08.082.

A.E. Suliman and Y. Tang, J. Appl. Sci., 7, 314 (2007); doi:10.3923/jas.2007.314.316.

M.S.A.S. Shah, M. Nag, T. Kalagara, S. Singh and S.V. Manorama, Chem. Mater., 20, 2455 (2008); doi:10.1021/cm7033867.

S.G. Hussain, D. Liu, X. Huang, K.M. Sulieman and S.T. Rasool, Int. J. Nanopart., 2, 443 (2009); doi:10.1504/IJNP.2009.028779.

F. Grasset, N. Saito, D. Li, D. Park, I. Sakaguchi, N. Ohashi, H. Haneda, T. Roisnel, S. Mornet and E. Duguet, J. Alloys Comp., 360, 298 (2003); doi:10.1016/S0925-8388(03)00371-2.

J.A. Parker, D.A. Kowrides, Foblen and G.M. High, Temperature Polymer Matrix Composites. NASA Conf Pub No 2385:5 (1983).

K. Albert, B. Pfleiderer, E. Bayer and R. Schnabel, J. Colloid Interf. Sci., 142, 35 (1991); doi:10.1016/0021-9797(91)90031-3.

J. Meng and X. Hu, Polymer, 45, 9011 (2004); doi:10.1016/j.polymer.2004.09.058.

H.M. Kao, Y.Y. Tsai and S.W. Chao, Solid State Ion., 176, 1261 (2005); doi:10.1016/j.ssi.2005.02.011.

K. Krishnan, T.M. Vijayan and K.N. Ninan, J. Mater. Sci., 34, 5907 (1999); doi:10.1023/A:1004743210352.

A.A. Kumar, M. Alagar and R.M.V.G.K. Rao, J. Appl. Polym. Sci., 81, 2330 (2001); doi:10.1002/app.1674.

G. Shen, A. Horgan and R. Levicky, Colloids Surf. B, 35, 59 (2004); doi:10.1016/j.colsurfb.2004.02.010.

M.T. Weller, Inorganic Materials Chemistry, Oxford Chemistry Primer, 5 (1996).

P. Musto, E. Mariuscelli, G. Ragosta, P. Russo and G. Scarinzi, J. Appl. Polym. Sci., 69, 1029 (1998); doi:10.1002/(SICI)1097-4628(19980801)69:5<1029::AID-APP23>3.0.CO;2-V.

Y.W. Lao, S.T. Kuo and W.H. Tuan, Ceram. Int., 35, 1317 (2009); doi:10.1016/j.ceramint.2008.06.015.

Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Thermal and Morphological Studies on Bismaleimide Modified ZnO Nanoparticles

Corresponding Author(s) : M. Suresh Chandra kumar

Abstract

Keywords

Full Article

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