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Vol. 31 No. 8 (2019): Vol 31 Issue 8

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Synthesis, Characterization and Antifungal Studies of Adducts of p-Ethylphenyldithiocarbonates of Copper(II)

https://doi.org/10.14233/ajchem.2019.22089
Shivangi Sharma
Department of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu-180006, India
Renu Sachar
Department of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu-180006, India
G.D. Bajju
Department of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu-180006, India
Vikas Sharma
Division of Biochemistry, Faculty of Basic Sciences, Sher-e-Kashmir University of Agricultural Sciences and Technology of Jammu, Main Campus Chatha, Jammu-180009, India

Corresponding Author(s) : Shivangi Sharma

sharmashivangi8618@gmail.com

Asian Journal of Chemistry, Vol. 31 No. 8 (2019): Vol 31 Issue 8

Abstract

A series of adducts of p-ethylphenyldithiocarbonates of copper(II) [(p-C2H5C6H4OCS2)2Cu] with ethyl pyridines and chloro pyridines have been synthesized in 1:2 molar ratio. They were characterized by elemental analysis, magnetic susceptibility and molar conductance measurements, infrared, electronic, electron spin resonance and mass spectroscopy, NMR and thermogravimetric analysis. In addition, antifungal studies of these adducts were also performed. The results revealed that the adducts have 1:2 stoichiometry, non-electrolytic and paramagnetic at room temperature. On the basis of spectral studies, a distorted octahedral geometry is proposed around copper(II) ion. ESR studies depicted elongated axial symmetry of Cu(II)adducts with nitrogen donors. Moreover, the adducts also showed potential antifungal activity against Fusarium oxysporium.

Keywords

Dithiocarbonates Pyridines Octahedral Antifungal
Sharma, S., Sachar, R., Bajju, G., & Sharma, V. (2019). Synthesis, Characterization and Antifungal Studies of Adducts of p-Ethylphenyldithiocarbonates of Copper(II). Asian Journal of Chemistry, 31(8), 1819–1824. https://doi.org/10.14233/ajchem.2019.22089
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