Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Copyright (c) 2014 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Design, Synthesis and Crystal Structure Analysis of Co(II) and Cd(II) Coordination Compounds with Benzimidazole Derivative Ligands

https://doi.org/10.14233/ajchem.2014.16808
Dan Sun
Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, P.R. China
Ke-Qi Pan
College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P.R. China
Hai-Jun Xu
Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, P.R. China

Corresponding Author(s) : Hai-Jun Xu

xuhaijun@njfu.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 21 (2014): Vol 26 Issue 21

Abstract

Two benzimidazole complexes of Cd(II) and Co(II) (1 and 2) were synthesized and characterized by single-crystal X-ray diffraction. The structure analysis indicates that the Cd(II) complex belongs to tetragonal P41212 space group with a = 0.85006 (17) nm, b = 0.85006 (17) nm, c = 2.9594 (6) nm, V = 2.1385 (7) nm3, Z = 4. Each Cd(II) atom coordinates with two benzimidazole derivative ligands and two nitrate anions in the shape of coordination polyhedron existing between the dodecahedron and tetragonal antiprism. In the crystal structure, the adjacent coordination units were connected together through strong intermolecular N-H···O H-bonding interactions, which result in the formation of a two-dimension supramolecular structure. For the Co(II) complex with chiral ligand, the same handedness structure was formed and crystallized in the orthorhombic P212121 space group with a = 0.80052 (6) nm, b = 1.39487 (8) nm, c = 1.529340 (10) nm, V = 1.70769 (16) nm3, Z = 4. Each Co(II) atom coordinates with one benzimidazole derivative ligand and two chlorides in distorted tetrahedron geometry.

Keywords

Crystal structure Benzimidazole Chiral coordination Cd(II) Co(II)
Sun, D., Pan, K.-Q., & Xu, H.-J. (2014). Design, Synthesis and Crystal Structure Analysis of Co(II) and Cd(II) Coordination Compounds with Benzimidazole Derivative Ligands. Asian Journal of Chemistry, 26(21), 7355–7358. https://doi.org/10.14233/ajchem.2014.16808
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. B.L. Chen, N.W. Ockwig, A.R. Millward, D.S. Contreras and O.M. Yaghi, Angew. Chem. Int. Ed., 44, 4745 (2005); doi:10.1002/anie.200462787.
  2. M. Eddaoudi, D.B. Moler, H.L. Li, B.L. Chen, T.M. Reineke, M. O‘Keeffe and O.M. Yaghi, Acc. Chem. Res., 34, 319 (2001); doi:10.1021/ar000034b.
  3. M. Xue, S.Q. Ma, Z. Jin, R.M. Schaffino, G.S. Zhu, E.B. Lobkovsky, S.L. Qiu and B.L. Chen, Inorg. Chem., 47, 6825 (2008); doi:10.1021/ic800854y.
  4. Z. Jin, H.Y. Zhao, X.J. Zhao, Q.R. Fang, J.R. Long and G.S. Zhu, Chem. Commun., 46, 8612 (2010); doi:10.1039/c0cc01031f.
  5. L. Pan, T. Frydel, M.B. Sander, X. Huang and J. Li, Inorg. Chem., 40, 1271 (2001); doi:10.1021/ic001012o.
  6. M.T. Caudle, J.W. Kampf, M.L. Kirk, P.G. Rasmussen and V.L. Pecoraro, J. Am. Chem. Soc., 119, 9297 (1997); doi:10.1021/ja9715197.
  7. F.Y. Yi, W. Yang and Z.M. Sun, J. Mater. Chem., 22, 23201 (2012); doi:10.1039/c2jm35273g.
  8. D.W. Fu, M.M. Zhao and J.Z. Ge, J. Mol. Struct., 1006, 227 (2011); doi:10.1016/j.molstruc.2011.09.013.
  9. L. Zhao, X.T. Dong, Q. Cheng and J.X. Zhao, Asian J. Chem., 25, 4646 (2013); doi:10.14233/ajchem.2013.14408.
  10. H.J. Xu, L. Xu and Y.K. Zhang, Inorg. Chem. Commun., 28, 94 (2013); doi:10.1016/j.inoche.2012.11.023.
  11. Y.Q. Tian, C.X. Cai, Y. Ji, X.Z. You, S.M. Peng and G.H. Lee, Angew. Chem. Int. Ed., 41, 1384 (2002); doi:10.1002/1521-3773(20020415)41:8<1384::AID-ANIE1384>3.0.CO;2-6.
  12. G.R. Desiraju, J. Am. Chem. Soc., 135, 9952 (2013); doi:10.1021/ja403264c.
  13. D.W. Fu, W. Zhang and R.G. Xiong, Cryst. Growth Des., 8, 3461 (2008); doi:10.1021/cg800507k.
  14. Y.Q. Tian, C.X. Cai, X.M. Ren, C.Y. Duan, Y. Xu, S. Gao and X.Z. You, Chem. Eur. J., 9, 5673 (2003); doi:10.1002/chem.200304957.
  15. J.K. Hu, X.Y. Yu, Y.H. Luo, X.-F. Wang, F.-X. Yue and H. Zhang, Inorg. Chem. Commun., 32, 37 (2013); doi:10.1016/j.inoche.2013.03.030.
  16. Y.L. Yao, Y.X. Che and J.M. Zheng, Inorg. Chem. Commun., 11, 883 (2008); doi:10.1016/j.inoche.2008.04.024.
  17. P.C. Song, W.C. Song, Y. Tao, T.L. Hu and Y.F. Zeng, Solid State Sci., 12, 1357 (2010); doi:10.1016/j.solidstatesciences.2010.05.008.
  18. H.J. Xu, Y.X. Liu, Z. Shen, Y.Q. Tian and X.Z. You, Z. Anorg. Allg. Chem., 631, 1349 (2005); doi:10.1002/zaac.200400507.
  19. Y.Q. Tian, H.J. Xu, L.H. Weng, Z.X. Chen, D.Y. Zhao and X.Z. You, Eur. J. Inorg. Chem., 2004, 1813 (2004); doi:10.1002/ejic.200300920.
  20. B. Barszcz, A. Jabłońska-Wawrzycka, K. Stadnicka and J. Jezierska, Polyhedron, 27, 3500 (2008); doi:10.1016/j.poly.2008.07.038.
  21. L. Han and M. Hong, Inorg. Chem. Commun., 8, 406 (2005); doi:10.1016/j.inoche.2005.01.028.
  22. R. Xia and H.J. Xu, Acta Crystallogr., E64, o1223 (2008); doi:10.1107/S1600536808013871.
  23. G.M. Sheldrick, SHELXTL Version 5.10 (Bruker AXS Inc., Madsion), (1997.
  24. J.M. Grevy, F. Tellez, S. Bernés, H. Nöth, R. Contreras and N. Barba-Behrens, Inorg. Chim. Acta, 339, 532 (2002); doi:10.1016/S0020-1693(02)01132-5.
  25. W.-H. Sun, C. Shao, Y. Chen, H. Hu, R.A. Sheldon, H. Wang, X. Leng and X. Jin, Organometallics, 21, 4350 (2002); doi:10.1021/om020370r.
  26. N.H. Tarte, S.I. Woo, L. Cui, Y.-D. Gong and Y.H. Hwang, J. Organomet. Chem., 693, 729 (2008); doi:10.1016/j.jorganchem.2007.12.001.
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 1 Download : 0