Catalytic Synthesis of 2-(1-Cyclohexenyl)cyclohexanone by Mixed Heteropoly Acids Catalyst (PW12 + PMo12/SBA-15)

Ying-Ying Wang; Bo Wu; Chun-Li Liu; Fu-Xiang Li; Zhi-Ping Lv; Jian-Wei Xue

doi:10.14233/ajchem.2014.16770

Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Issue Published : September 30, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Catalytic Synthesis of 2-(1-Cyclohexenyl)cyclohexanone by Mixed Heteropoly Acids Catalyst (PW12 + PMo12/SBA-15)

https://doi.org/10.14233/ajchem.2014.16770

Ying-Ying Wang

Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, Shanxi Province, P.R. China

Bo Wu

Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, Shanxi Province, P.R. China

Chun-Li Liu

Shandong Hualu Hengsheng Chemical Industrial Stock Co., Ltd., Dezhou, Shandong Province, P.R. China

Fu-Xiang Li

Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, Shanxi Province, P.R. China

Zhi-Ping Lv

Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, Shanxi Province, P.R. China

Jian-Wei Xue

Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, Shanxi Province, P.R. China

Corresponding Author(s) : Jian-Wei Xue

xuejianwei@yeah.net

Asian Journal of Chemistry, Vol. 26 No. 21 (2014): Vol 26 Issue 21
Article Published : October 1, 2014

Abstract

Mixed heteropoly acids (phosphotungstic acid and phosphomolybdic acid) supported on SBA-15 (PW₁₂ + PMo₁₂/SBA-15) by impregnation method was used as catalysts of self-condensation reaction of cyclohexanone to synthesize the 2-(1-cyclohexenyl)cyclohexanone. The experimental results indicated that the mixed heteropoly acids supported on SBA-15 had effective catalytic performance, which catalytic synthesis of 2-(1-cyclohexenyl)cyclohexanone. The effects of various parameters on the conversion ratio such as the amount of catalyst, loading amount, reaction time and reaction temperature were investigated. The optimum reaction conditions were as follows: The loading of the PW₁₂ + PMo₁₂/SBA-15 was 29 %, the percentage of catalyst in reactants was 3 %, the reaction time was 2.5 h and the reaction temperature was 150 °C. The conversion rate could reach 86.5 %.

Keywords

Catalytic 2-(1-Cyclohexenyl)cyclohexanone Impregnation method Mixed heteropoly acids SBA-15

Wang, Y.-Y., Wu, B., Liu, C.-L., Li, F.-X., Lv, Z.-P., & Xue, J.-W. (2014). Catalytic Synthesis of 2-(1-Cyclohexenyl)cyclohexanone by Mixed Heteropoly Acids Catalyst (PW12 + PMo12/SBA-15). Asian Journal of Chemistry, 26(21), 7343–7347. https://doi.org/10.14233/ajchem.2014.16770

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L. Shi, Chemical Intermediates (Chinese), 16, 12 (2003).

M. Yang, S.f. Yuan, H.L. Yin, Z. Xia and Z.R. Chen, Chemical Reaction Engineering and Technol. (Chinese), 24, 277 (2008).

L.L. Yue, W.W. Jiang and L.J. Mu ect., Chinese J. Synthetic Chem., 11, 147 (2003).

D. Lorenzo, A. Santos, E. Simon and A. Romero, Ind. Eng. Chem. Res., 52, 2257 (2013).

B.C. Gagea, Y. Lorgouilloux, Y. Altintas, P.A. Jacobs and J.A. Martens, J. Catal., 265, 99 (2009).

T. Baba and Y. Ono, Appl. Catal., 22, 321 (1986).

D.F. Ma, Y. Li and S.L. Gu, Petrochem. Technol., 25, 80 (1996).

A.P. Liao and Z.F. Tong, Chemical Reaction Engin. Technol., 11, 406 (1995).

E. Caliman, J.A. Dias, S.C. Dias and A.G.S. Prado, Catal. Today, 107-108, 816 (2005).

R.N. Hua, J. Gong, D.R. Wang, Northeast Normal University (Nat.Sci. Edition) (Chinese), 4, 42 (1997).

M. Yoon, J.A. Chang, Y. Kim, J.R. Choi, K. Kim and S.J. Lee, J. Phys.Chem. B, 105, 2539 (2001).

X.P. Wang, X.K. Ye and Y. Wu, Chin. J. Catal., 15, 314 (1994).

S. Wang, Microporous Mesoporous Mater., 117, 1 (2009).

M. Moritz and M. Laniecki, Appl. Surf. Sci., 258, 7523 (2012).

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J.M. Aragon, J.M.R. Vegas and L.G. Jodra, Ind. Eng. Chem. Res., 32, 2555 (1993).

Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Catalytic Synthesis of 2-(1-Cyclohexenyl)cyclohexanone by Mixed Heteropoly Acids Catalyst (PW12 + PMo12/SBA-15)

Corresponding Author(s) : Jian-Wei Xue

Abstract

Keywords

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