Synthesis and Characterization of Chitosan/Urea-Formaldehyde Hollow Resin for Metal Ion Removal

Magdy Y. Abdelaal; Saleh O.S. Bahaffi; Nadia H. El-Sayed

doi:10.14233/ajchem.2014.16578

Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Issue Published : September 30, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of Chitosan/Urea-Formaldehyde Hollow Resin for Metal Ion Removal

https://doi.org/10.14233/ajchem.2014.16578

Magdy Y. Abdelaal

Chemistry Department, Faculty of Science, King Abdulaziz University, PO Box 80203, Jeddah 21589, Saudi Arabia; Permanent address: Chemistry Department, Faculty of Science, Mansoura University, ET-35516 Mansoura, Egypt

Saleh O.S. Bahaffi

Chemistry Department, Faculty of Science, King Abdulaziz University, PO Box 80203, Jeddah 21589, Saudi Arabia

Nadia H. El-Sayed

Chemistry Department, Faculty of Science, Tabuk University, Tabuk, Saudi Arabia ; Department of Polymers and Pigments, National Research Center, Dokki, Cairo 12311, Egypt

Corresponding Author(s) : Magdy Y. Abdelaal

myabdelaal@gmail.com; magdyabdelaal@yahoo.com

Asian Journal of Chemistry, Vol. 26 No. 21 (2014): Vol 26 Issue 21
Article Published : September 30, 2014

Abstract

In the current study, a series of hollow resins has been synthesized by using chitosan succinate and urea-formaldehyde resin as a cage resin to prepare new polychelates for different metal ions. Resins were characterized by FT-IR spectroscopy, thermal analysis and scanning electron microscopy. Resins have also been investigated for the removal of metal ions from their aqueous solutions through the formation of polychelates of the metal ions and their sorption capacity of such metal ions was determined. The hollow resin exhibited higher surface area than its separate components which facilitates higher ion uptake of metal ions from aqueous solutions.

Keywords

Urea-formaldehyde Chitosan Modification SEM Hollow resin

Y. Abdelaal, M., O.S. Bahaffi, S., & H. El-Sayed, N. (2014). Synthesis and Characterization of Chitosan/Urea-Formaldehyde Hollow Resin for Metal Ion Removal. Asian Journal of Chemistry, 26(21), 7239–7244. https://doi.org/10.14233/ajchem.2014.16578

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References

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M.A. Salam, M.S.I. Makki and M.Y.A. Abdelaal, J. Alloy. Comp., 509, 2582 (2011); doi:10.1016/j.jallcom.2010.11.094.
M.S.I. Makki, T.R. Sobahi and M.Y. Abdelaal, Int. J. Polym. Mater., 58, 647 (2009); doi:10.1080/00914030903146712.
T.R. Sobahi, M.S.I. Makki and M.Y. Abdelaal, J. Saudi Chem. Soc., 17, 245 (2013); doi:10.1016/j.jscs.2011.03.015.
T.R. Sobahi, M.Y. Abdelaal and M.S.I. Makki, Arab. J. Chem., doi:10.1016/j.arabjc.2010.12.011.
M.Y. Abdelaal and R.M. Mohamed, J. Alloys Comp., 576, 201 (2013); doi:10.1016/j.jallcom.2013.04.112.
T.H. Boyer and P.C. Singer, Water Res., 40, 2865 (2007); doi:10.1016/j.watres.2006.05.022.
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V.D. Mane, N.J. Wahane and W.B. Gurnule, J. Appl. Polym. Sci., 111, 3039 (2009); doi:10.1002/app.29369.
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H.A. Essawy, A.B. Moustafa and N.H. El-Sayed, J. Appl. Polym. Sci., 114, 1348 (2009); doi:10.1002/app.30696.
Y.G. Ko, U.S. Choi and B.H. Sung, J. Appl. Polym. Sci., 93, 1559 (2004); doi:10.1002/app.20632.
K. Kurita, Mar. Biotechnol., 8, 203 (2006); doi:10.1007/s10126-005-0097-5.
U.S. Choi, Colloids Surf. A, 157, 193 (1999); doi:10.1016/S0927-7757(99)00051-5.
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R. Qu, Y. Sun, C. Wang, S. Lu, H. Yu and G. Cheng, J. Appl. Polym. Sci., 84, 310 (2002); doi:10.1002/app.10331.

References

M.Y. Abdelaal, E.A. Abdel-Razik, E.M. Abdel-Bary and I.M. El-Sherbiny, J. Appl. Polym. Sci., 103, 2864 (2007); doi:10.1002/app.25154.

M.Y. Abdelaal, T.R. Sobahi and H.F. Al-Shareef, Int. J. Biol. Macromol., 55, 231 (2013); doi:10.1016/j.ijbiomac.2013.01.013.

Q. Wang, X. Hu, Y. Du and J.F. Kennedy, Carbohydr. Polym., 82, 842 (2010); doi:10.1016/j.carbpol.2010.06.004.

A. Sand, M. Yadav, D.K. Mishra and K. Behari, Carb. Polym., 80, 1147 (2010); doi:10.1016/j.carbpol.2010.01.036.

M. Prabaharan and R. Jayakumar, Int. J. Biol. Macromol., 44, 320 (2009); doi:10.1016/j.ijbiomac.2009.01.005.

M.A. Salam, M.S.I. Makki and M.Y.A. Abdelaal, J. Alloy. Comp., 509, 2582 (2011); doi:10.1016/j.jallcom.2010.11.094.

M.S.I. Makki, T.R. Sobahi and M.Y. Abdelaal, Int. J. Polym. Mater., 58, 647 (2009); doi:10.1080/00914030903146712.

T.R. Sobahi, M.S.I. Makki and M.Y. Abdelaal, J. Saudi Chem. Soc., 17, 245 (2013); doi:10.1016/j.jscs.2011.03.015.

T.R. Sobahi, M.Y. Abdelaal and M.S.I. Makki, Arab. J. Chem., doi:10.1016/j.arabjc.2010.12.011.

M.Y. Abdelaal and R.M. Mohamed, J. Alloys Comp., 576, 201 (2013); doi:10.1016/j.jallcom.2013.04.112.

T.H. Boyer and P.C. Singer, Water Res., 40, 2865 (2007); doi:10.1016/j.watres.2006.05.022.

B. Shah, A. Shah and N. Patel, Iran. Polym. J., 17, 17 (2008).

W.B. Gurnule, P.K. Rahangdale, L.J. Paliwal and R.B. Kharat, React. Funct. Polym., 55, 255 (2003); doi:10.1016/S1381-5148(03)00016-6.

V.D. Mane, N.J. Wahane and W.B. Gurnule, J. Appl. Polym. Sci., 111, 3039 (2009); doi:10.1002/app.29369.

L.L. Williams, in eds.: J.I. Kroschwitz and M. Howe-Grant, Kirk-Othmer Encyclopedia of Chemical Technology, John-Wiley & Sons: New York, NY, edn 2, Vol. 2, pp 604 -37 (1991).

I.H. Updegraff, in ed.: I. Skeist, Handbook of Adhesives, Van Nostrans Reinhold; New York, edn 3, 341-346 (1990).

H.A. Essawy, A.B. Moustafa and N.H. El-Sayed, J. Appl. Polym. Sci., 114, 1348 (2009); doi:10.1002/app.30696.

Y.G. Ko, U.S. Choi and B.H. Sung, J. Appl. Polym. Sci., 93, 1559 (2004); doi:10.1002/app.20632.

K. Kurita, Mar. Biotechnol., 8, 203 (2006); doi:10.1007/s10126-005-0097-5.

U.S. Choi, Colloids Surf. A, 157, 193 (1999); doi:10.1016/S0927-7757(99)00051-5.

Y.G. Ko and U.S. Choi, J. Appl. Polym. Sci., 102, 4937 (2006); doi:10.1002/app.24917.

J.H. Sung, W.H. Jang, H.J. Choi and M.S. Jhon, Polymer, 46, 12359 (2005); doi:10.1016/j.polymer.2005.10.133.

U.S. Choi, Y.S. Park and S.S. Lee, Colloids Surf. A, 211, 85 (2002); doi:10.1016/S0927-7757(02)00234-0.

R. Qu, Y. Sun, C. Wang, S. Lu, H. Yu and G. Cheng, J. Appl. Polym. Sci., 84, 310 (2002); doi:10.1002/app.10331.

Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Synthesis and Characterization of Chitosan/Urea-Formaldehyde Hollow Resin for Metal Ion Removal

Corresponding Author(s) : Magdy Y. Abdelaal

Abstract

Keywords

Full Article

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