Issue

Vol. 26 No. 22 (2014): Vol 26 Issue 22

Copyright (c) 2014 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Anodic Stripping Voltammetric Determination of Trace Cadmium Using Carbon Paste Electrode Modified by 1-Butyl-3-methylimidazolium Tetraflouroborate Ionic Liquid

https://doi.org/10.14233/ajchem.2014.16827
L.Q. Hung
Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
N.H. Anh
Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
V.T.T. Ha
Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam
P.H. Phong
Institute of Chemistry, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam

Corresponding Author(s) : L.Q. Hung

hunglq@ich.vast.ac.vn

Asian Journal of Chemistry, Vol. 26 No. 22 (2014): Vol 26 Issue 22

Abstract

Carbon paste electrodes modified with ionic liquid and carbon nanotubes were used for the determination of trace cadmium by anodic stripping voltammetry. The electroanalytical performance for the determination of Cd2+ on the ionic liquid-carbon paste electrode and ionic liquid-carbon nanotube carbon paste electrode (IL-CPE and IL-CNT-CPE) were better than that on the pure carbon paste electrode. Compared with two others, the best electrode obtained in this study was IL-CNT-CPE. The measuring conditions were also optimized. The measurement of trace cadmium on the IL-CNT-CPE had the best response under the conditions of 0.10 M phosphate buffer solution (PBS) (pH 4), deposition potential of -1 V and a deposition time of 240 s. The IL-CPE and IL-CNT-CPE revealed highly linear behaviour in the concentration range of 20-100 ppb and 5-220 ppb with detection limits of 5 ppb and 1.48 ppb respectively. The developed sensor has been applied to the determination of Cd2+ in real water samples with satisfactory results.

Keywords

Modified carbon paste electrode Ionic liquid Cadmium ion Anodic stripping voltammetry
Hung, L., Anh, N., Ha, V., & Phong, P. (2014). Anodic Stripping Voltammetric Determination of Trace Cadmium Using Carbon Paste Electrode Modified by 1-Butyl-3-methylimidazolium Tetraflouroborate Ionic Liquid. Asian Journal of Chemistry, 26(22), 7557–7563. https://doi.org/10.14233/ajchem.2014.16827
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. T. Noyhouzer and D. Mandler, Anal. Chim. Acta, 684, 1 (2011).
  2. J.F. van Staden and M.C. Matoetoe, Anal. Chim. Acta, 411, 201 (2000).
  3. Y. Bonfil and E. Kirowa-Eisner, Anal. Chim. Acta, 457, 285 (2002).
  4. J. Wang, Ü. Anik Kirgöz, J.-W. Mo, J. Lu, A. Nasser Kawde and A. Muck, Electrochem. Commun., 3, 203 (2001).
  5. M. Chirea, V. García-Morales, J.A. Manzanares, C. Pereira, R. Gulaboski and F. Silva, J. Phys. Chem. B, 109, 21808 (2005).
  6. R.M. Iost and F.N. Crespilho, Biosens. Bioelectron., 31, 1 (2012).
  7. Y. Liu, X. Zou and S. Dong, Electrochem. Commun., 8, 1429 (2006).
  8. L. Cao, Q. Li, J. Ji, P. Yan and T. Wang, Int. J. Electrochem. Soc., 8, 3074 (2013).
  9. N. Muskal and D. Mandler, Electrochim. Acta, 45, 537 (1999).
  10. S. Ben-Ali, D.A. Cook, P.N. Bartlett and A. Kuhn, J. Electroanal. Chem., 579, 181 (2005).
  11. S.Y. Li, W.H. Ma, Y. Zhou, X.H. Chen, M.Y. Ma, Y.H. Xu, Z. Ding and X.H. Wu, Int. J. Electrochem. Sci., 8, 1802 (2013).
  12. F. Ivanauskas, I. Kaunietis, V. Laurinavicius, J. Razumiene and R. Šimkus, J. Math. Chem., 43, 1516 (2008).
  13. L. Chu and X. Zhang, J. Nanosci. Nanotechnol., 12, 300 (2012).
  14. Y.-C. Tsai, J.-M. Chen, S.-C. Li and F. Marken, Electrochem. Commun.,6, 917 (2004).
  15. W. Sun, Z. Zhai, D. Wang, S. Liu and K. Jiao, Bioelectrochemistry, 74,295 (2009).
  16. R.G. Freitas, R.T.S. Oliveira, M.C. Santos, L.O.S. Bulhões and E.C.Pereira, Mater. Lett., 60, 1906 (2006).
  17. D. Farina, K. Yoshida, T. Stieglitz and K.P. Koch, J. Appl. Physiol.,104, 821 (2008).
  18. S. Schubert, M. Hermenau, J. Meiss, L. Müller-Meskamp and K. Leo, Adv. Funct. Mater., 22, 4993 (2012).
  19. M. Bonne, K. Edler, J.G. Buchanan, D. Wolverson, E. Psillakis, M. Helton, W. Thielemans and F. Marken, J. Phys. Chem. C, 112, 2660 (2008).
  20. S. Harrer, S. Ahmed, A. Afzali-Ardakani, B. Luan, P.S. Waggoner, X. Shao, H. Peng, D.L. Goldfarb, G.J. Martyna, S.M. Rossnagel, L. Deligianni and G.A. Stolovitzky, Langmuir, 26, 19191 (2010).
  21. M. Musameh and J. Wang, Anal. Chim. Acta, 606, 45 (2008).
  22. D.V. Chernyshov, N.V. Shvedene, E.R. Antipova and I.V. Pletnev, Anal. Chim. Acta, 621, 178 (2008).
  23. D. Wei and A. Ivaska, Anal. Chim. Acta, 607, 126 (2008).
  24. T. Torimoto, T. Tsuda, K. Okazaki and S. Kuwabata, Adv. Mater., 22, 1196 (2010).
  25. M.J.A. Shiddiky and A.A.J. Torriero, Biosens. Bioelectron., 26, 1775 (2011).
  26. M. Opallo and A. Lesniewski, J. Electroanal. Chem., 656, 2 (2011).
  27. H. Liu, Y. Liu and J. Li, Phys. Chem. Chem. Phys., 12, 1685 (2010).
  28. M.G. Freire, C.M. Neves, I.M. Marrucho, J.A. Coutinho and A.M. Fernandes, J. Phys. Chem. A, 114, 3744 (2010).
  29. Y. Wang, J. Wu, T. Zhan, W. Sun and K. Jiao, Sensor Lett., 7, 1106 (2009).
  30. Y. She, Y. Tang, H. Liu and P. He, Chem. Cent. J., 4, 17 (2010).
  31. Y. Feng, Z.X. Liu, L.Y. Wang, H. Chen, Y.M. He and Q.H. Fan, Chin. Sci. Bull., 57, 4289 (2012).
  32. A. Safavi, N. Maleki, S. Momeni and F. Tajabadi, Anal. Chim. Acta, 625, 8 (2008).
  33. P. Zhang, S. Dong, G. Gu and T. Huang, Bull. Korean Chem. Soc., 31, 2949 (2010).
  34. J. Ping, J. Wu, Y. Ying, M. Wang, G. Liu and M. Zhang, J. Agric. Food Chem., 59, 4418 (2011).
  35. B.L. Li, Z.L. Wu, C.H. Xiong, H.Q. Luo and N.B. Li, Talanta, 88, 707 (2012).
  36. S.B. Hocevar, I. Švancara, K. Vytras and B. Ogorevc, Electrochim. Acta, 51, 706 (2005).
  37. T. Fukushima, A. Kosaka, Y. Yamamoto, T. Aimiya, S. Notazawa, T. Takigawa, T. Inabe and T. Aida, Small, 2, 554 (2006).
  38. T. Fukushima, A. Kosaka, Y. Ishimura, T. Yamamoto, T. Takigawa, N. Ishii and T. Aida, Science, 300, 2072 (2003).
  39. F. Zhao, X. Wu, M. Wang, Y. Liu, L. Gao and S. Dong, Anal. Chem., 76, 4960 (2004).
  40. W. Tao, D. Pan, Q. Liu, S. Yao, Z. Nie and B. Han, Electroanalysis, 18, 1681 (2006).
  41. F. Xiao, L. Liu, J. Li, J. Zeng and B. Zeng, Electroanalysis, 20, 2047 (2008).
  42. F. Xiao, F. Zhao, J. Zeng and B. Zeng, Electrochem. Commun., 11, 1550 (2009).
  43. B.G. Choi, H. Park, T.J. Park, D.H. Kim, S.Y. Lee and W.H. Hong, Electrochem. Commun., 11, 672 (2009).
  44. X. Liu, Z. Ding, Y. He, Z. Xue, X. Zhao and X. Lu, Colloids Surf. B Biointerfaces, 79, 27 (2010).
  45. J. Dong, Y. Hu, S. Zhu, J. Xu and Y. Xu, Anal. Bioanal. Chem., 396, 1755 (2010).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0