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Vol. 26 No. 22 (2014): Vol 26 Issue 22

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Synthesis, Crystal Structure and Antioxidation Study of Cadmium(II) Complex with bis(N-Methylbenzimidazol-2-ylmethyl)aniline

https://doi.org/10.14233/ajchem.2014.16654
Yanhui Zhang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Furong Shi
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Yuchen Bai
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Xiaoli Wang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Chengyong Chen
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Jiawen Zhang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Huilu Wu
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : Huilu Wu

wuhuilu@163.com

Asian Journal of Chemistry, Vol. 26 No. 22 (2014): Vol 26 Issue 22

Abstract

A complex of cadmium(II) picrate (pic) with bis(N-methylbenzimidazol-2-ylmethyl)aniline (Mebba), with composition [Cd(Mebba)2](pic)2, was synthesized and characterized by elemental analysis, electrical conductivity, IR and UV/visible spectral measurements. The crystal structure of the cadmium(II) complex has been determined by single-crystal X-ray diffraction. The Cd(II) cation is bonded to two Mebba ligands through four benzimidazole nitrogen atoms and two aniline nitrogen atoms, resulting in a distorted octahedral geometry. The ligand Mebba and Cd(II) complexes have scavenging effects for hydroxyl radicals and complex shows stronger scavenging effects for hydroxyl radicals.

Keywords

Bis(N-methylbenzimidazol-2-ylmethyl)aniline Cadmium(II) complex Crystal structure
Zhang, Y., Shi, F., Bai, Y., Wang, X., Chen, C., Zhang, J., & Wu, H. (2014). Synthesis, Crystal Structure and Antioxidation Study of Cadmium(II) Complex with bis(N-Methylbenzimidazol-2-ylmethyl)aniline. Asian Journal of Chemistry, 26(22), 7523–7526. https://doi.org/10.14233/ajchem.2014.16654
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