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Vol. 27 No. 2 (2015): Vol 27 Issue 2

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Syntheses and Structure of New Mononuclear Nickel(III) Complex [Ni(L)]·H2O, where H3L = [(3-Ethoxy-2-hydroxy-benzylidene)]-[N-(3-ethoxy- 2-hydroxy-benzylidene)]-1-amino-N-amino-Formimidic Acid

F.Y. Chen
Department of Chemistry, Shangrao Normal University, Shangrao 334001, Jiangxi Province, P.R. China
G. Li
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, P.R. China
L. Yang
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, P.R. China
S.H. Zhang
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, P.R. China
H.Y. Zhang
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, P.R. China
H.P. Li
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, P.R. China

Corresponding Author(s) : F.Y. Chen

srcfy1972@163.com

Asian Journal of Chemistry, Vol. 27 No. 2 (2015): Vol 27 Issue 2

Abstract

A new complex [Ni(L)]·H2O (1) ([H3L = [(3-ethoxy-2-hydroxy-benzylidene)]-[N'-(3-ethoxy-2-hydroxybenzylidene)]-1-amino-N-amino-Formimidic acid) was synthesized through solvothermal method and it's structure (C19H21N3O6Ni, Mr = 446.10) was determined by IR spectra, elemental analysis, single-crystal X-ray diffraction analysis. The crystal belongs to monoclinic system, space group P21/n with a = 11.4763(4), b = 7.1321(2), c = 24.2433(7) Å, β = 96.578(3)º, V = 1971.26(11), Z = 4, R1 = 0.0484. The Ni(III) ion is coordinated by two O atoms and two N atoms from a tetradentate L3- in a slightly distorted planar environment. In the crystal structure, the main structure [Ni(L)] seized a solvent water molecule through intramolecular O-H···O hydrogen bond. Ni(III) ion and L3- were attained through in situ reaction.

Keywords

Schiff base Ni(III) Complex Crystal Structure
(1)
Chen, F.; Li, G.; Yang, L.; Zhang, S.; Zhang, H.; Li, H. Syntheses and Structure of New Mononuclear Nickel(III) Complex [Ni(L)]·H2O, Where H3L = [(3-Ethoxy-2-Hydroxy-benzylidene)]-[N-(3-Ethoxy- 2-Hydroxy-benzylidene)]-1-Amino-N-Amino-Formimidic Acid. ajc 2015, 27, 565-568.
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