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Vol. 36 No. 9 (2024): Vol 36 Issue 9, 2024

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Metal Incorporated Zeolites as Heterogeneous Catalysts in the Selective Partial Oxidation of Methane to Methanol: A Review

https://doi.org/10.14233/ajchem.2024.32083
Buddhadeb Dutta
Department of Chemistry, Ramakrishna Mission Vivekananda Centenary College, Rahara, Kolkata-700118, India
https://orcid.org/0000-0002-7425-4412

Corresponding Author(s) : Buddhadeb Dutta

buddhadutta@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 9 (2024): Vol 36 Issue 9, 2024

Abstract

Methane, being a potential greenhouse gas, is a very serious environmental concern nowadays. The valorization of methane to valuable chemicals like methanol has long been considered as an effective remedy to this problem. But, in spite of several attempts, the production of methanol directly from methane remains largely challenging, both in laboratory scale and in industrial level, because of low reactivity of methane and challenges in product recovery. In present review, the developments in the application of different heterogeneous catalysts in oxidation of methane to produce methanol directly, the ‘holy grail’ reaction in chemistry is discussed, with the main focus on the metal exchanged porous zeolite matrices as heterogeneous catalysts. The different reaction parameters like the nature of oxidants, reaction conditions, zeolite pore sizes, the metal loading ratio are also critically reviewed.

Keywords

Methane Methanol Zeolite Heterogeneous catalyst Selective oxidation
Dutta, B. (2024). Metal Incorporated Zeolites as Heterogeneous Catalysts in the Selective Partial Oxidation of Methane to Methanol: A Review. Asian Journal of Chemistry, 36(9), 1977–1987. https://doi.org/10.14233/ajchem.2024.32083
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