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Vol. 36 No. 8 (2024): Vol 36 Issue 8, 2024

Copyright (c) 2024 Saikat Sarkar

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Synthesis, X-Ray Crystal Structure, Solid State Electrical and Optical Properties of New Copper(II) Complex with 1,10-Phenanthroline Ligand

https://doi.org/10.14233/ajchem.2024.31953
Saikat Sarkar
Department of Chemistry, Chakdaha College, Chakdaha-741222, India
https://orcid.org/0000-0002-9732-2107
Avijit Sarkar
Department of Chemistry, Bhairab Ganguly College, Kolkata-700056, India
https://orcid.org/0000-0002-4939-603X
Yildirim Aydogdu
Department of Physics, Gazi University, Ankara, Turkey
https://orcid.org/0000-0002-1115-0691
Fethi Dagdelen
Department of Physics, Firat University, Elazig, Turkey
https://orcid.org/0000-0001-9849-590X
Sougata Sarkar
Department of Chemistry, Ramakrishna Mission Vivekananda Centenary College, Rahara-700118, India
https://orcid.org/0000-0001-8648-0209
Krishna Chattopadhyay
School of Chemical Sciences, Indian Association for the Cultivation of Science, Kolkata-700032, India
https://orcid.org/0000-0001-8657-7158

Corresponding Author(s) : Saikat Sarkar

saikat_s@rediffmail.com

Asian Journal of Chemistry, Vol. 36 No. 8 (2024): Vol 36 Issue 8, 2024

Abstract

A new ionic copper(II) complex of 1,10-phenanthroline was synthesized and structurally characterized by elemental and spectroscopic analyses, molar conductance and magnetic moment measurements. The crystal structure of complex was also investigated through single crystal X-ray diffraction analysis and suggestted a distorted octahedral geometry around copper(II), where one N atom from 1,10-phenanthroline and three O atoms from three H2O molecules occupying the basal plane while another Nphen and one Cl atom remain at the apical positions. Thus, the presence of three coordinated waters and chloride group along with the counter chloride ion and water of crystallization is responsible for extensive hydrogen bonding present in the molecule. Thus, the complex forms a 3D gigantic H-bonded network. The two types of intermolecular O–H···Cl and O–H···O hydrogen bonding play the pivotal role in crystal packing and plausible conductivity mechanism through the π-π interacting supports. The electrical conductivity and optical properties were also measured and the results focus on the semiconducting nature of the complex with optical band gap (Egd) value 1.23 eV.

Keywords

Complex Crystal structure Spectroscopy Electrical properties Semiconductor
Sarkar, S., Sarkar, A., Aydogdu, Y., Dagdelen, F., Sarkar, S., & Chattopadhyay, K. (2024). Synthesis, X-Ray Crystal Structure, Solid State Electrical and Optical Properties of New Copper(II) Complex with 1,10-Phenanthroline Ligand. Asian Journal of Chemistry, 36(8), 1865–1871. https://doi.org/10.14233/ajchem.2024.31953
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