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Vol. 36 No. 8 (2024): Vol 36 Issue 8, 2024

Copyright (c) 2024 Soumini chandralayam, Sugunan Sankaran

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Nanogold Supported Titania Loaded SBA-15: An Efficient Catalyst for Reduction of 4-Nitrophenol

https://doi.org/10.14233/ajchem.2024.31767
Soumini Chandralayam
Department of Chemistry, M.E.S. Keveeyam College, Valanchery, Malappuram-676552, India
https://orcid.org/0009-0007-1113-5719
Sugunan Sankaran
Department of Applied Chemistry, Cochin University of Science and Technology, Cochin-682022, India
https://orcid.org/0000-0001-5261-3472

Corresponding Author(s) : Soumini Chandralayam

souminic@meskeveeyamcollege.ac.in

Asian Journal of Chemistry, Vol. 36 No. 8 (2024): Vol 36 Issue 8, 2024

Abstract

Gold nanoparticles with an average particle size below 5 nm were effectively dispersed over titania loaded SBA-15. The nanogold supported systems were found to be highly effective in the liquid phase reduction of 4-nitrophenol to 4-aminophenol at room temperature (304 K) obeying pseudo-first-order kinetics. The highly effective catalyst with 3 wt.% Au incorporation to 20 wt.% Ti loaded SBA-15 (3Au/20Ti/SBA) showed a TON of 5.8 × 1021 molecules/g and a TOF of 6.5 × 1018 molecules/g/s in the reaction.

Keywords

SBA-15 Gold nanoparticles Reduction of 4-nitrophenol
Chandralayam, S., & Sankaran, S. (2024). Nanogold Supported Titania Loaded SBA-15: An Efficient Catalyst for Reduction of 4-Nitrophenol. Asian Journal of Chemistry, 36(8), 1821–1828. https://doi.org/10.14233/ajchem.2024.31767
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References
  1. Y.C. Chang and D.H. Chen, J. Hazard. Mater., 165, 664 (2009); https://doi.org/10.1016/j.jhazmat.2008.10.034
  2. A.A. Ismail, A. Hakki and D.W. Bahnemann, J. Mol. Catal. Chem., 358, 145 (2012); https://doi.org/10.1016/j.molcata.2012.03.009
  3. A.S. Hashimi, M.A.N.M. Nohan, S.X. Chin, S. Zakaria and C.H. Chia, Nanomaterials, 9, 936 (2019); https://doi.org/10.3390/nano9070936
  4. C. Kästner and A.F. Thünemann, Langmuir, 32, 7383 ( 2016); https://doi.org/10.1021/acs.langmuir.6b01477
  5. A.I. Ayad, D. Luart, A.O. Dris and E. Guénin, Nanomaterials, 10, 1169 (2020); https://doi.org/10.3390/nano10061169
  6. S. Varshney, D. Meyerstein, R. Bar-Ziv and T. Zidki, Molecules, 28, 6530 (2023); https://doi.org/10.3390/molecules28186530
  7. F. Rizzi, R. Castaldo, T. Latronico, P. Lasala, G. Gentile, M. Lavorgna, M. Striccoli, A. Agostiano, R. Comparelli, N. Depalo, M.L. Curri and E. Fanizza, Molecules, 26, 4247 (2021); https://doi.org/10.3390/molecules26144247
  8. S. Singh, A. Kumar, L. Nebhani and C.K. Hazra, JACS Au, 3, 3400 (2023); https://doi.org/10.1021/jacsau.3c00563
  9. H. Zhu, B. Lee, S. Dai and S.H. Overbury, Langmuir, 19, 3974 (2003); https://doi.org/10.1021/la027029w
  10. R. Zanella, A. Sandoval, P. Santiago, V.A. Basiuk and J.M. Saniger, J. Phys. Chem. B, 110, 8559 (2006); https://doi.org/10.1021/jp060601y
  11. A. Ghosh, C. Ranjan Patra, P. Mukherjee, M. Sastry and R. Kumar, Micropor. Mesopor. Mater., 58, 201 (2003); https://doi.org/10.1016/S1387-1811(02)00626-1
  12. N. Petkov, N. Stock and T. Bein, J. Phys. Chem. B, 109, 10737 (2005); https://doi.org/10.1021/jp050429i
  13. L.-F. Gutierrez, S. Hamoudi and K. Belkacemi, Appl. Catal. A Gen., 425–426, 213 (2012); https://doi.org/10.1016/j.apcata.2012.03.025
  14. S. Parambadath and A.P. Singh, Catal. Today, 141, 161 (2009); https://doi.org/10.1016/j.cattod.2008.04.003
  15. Z. Wang, Y. Xie and C.J. Liu, J. Phys. Chem. C, 112, 19818 (2008); https://doi.org/10.1021/jp805538j
  16. D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka and G.D. Stucky, Science, 279, 548 (1998); https://doi.org/10.1126/science.279.5350.548
  17. S. Mondal, M.E. De Anda Reyes and U. Pal, RSC Adv., 7, 8633 (2017); https://doi.org/10.1039/C6RA28640B
  18. X. Li, S. Huang, Q. Xu and Y. Yang, Transition Met. Chem., 34, 943 (2009); https://doi.org/10.1007/s11243-009-9285-x
  19. P. Babelon, A.S. Dequiedt, H. Mostefa-Sba, S. Bourgeois, P. Sibillot and M. Sacilotti, Thin Solid Films, 322, 63 (1998); https://doi.org/10.1016/S0040-6090(97)00958-9
  20. S. Bourgeois, P. le Seigneur and M. Perdereau, Surf. Sci., 328, 105 (1995); https://doi.org/10.1016/0039-6028(95)00022-4
  21. B.M. Mogudi, P. Ncube, N. Bingwa, N. Mawila, S. Mathebula and R. Meijboom, Appl. Catal. B, 218, 240 (2017); https://doi.org/10.1016/j.apcatb.2017.06.045
  22. K. Kuroda, T. Ishida and M. Haruta, J. Mol. Catal. Chem., 298, 7 (2009); https://doi.org/10.1016/j.molcata.2008.09.009
  23. Y. Khalavka, J. Becker and C. Sonnichsen, J. Am. Chem. Soc., 131, 1871 (2009); https://doi.org/10.1021/ja806766w
  24. Y. Peng, W. Leng, B. Dong, R. Ge, H. Duan and Y. Gao, Chin. J. Catal., 36, 1117 (2015); https://doi.org/10.1016/S1872-2067(14)60310-7
  25. X. Le, Z. Dong, W. Zhang, X. Li and J. Ma, J. Mol. Catal. Chem., 395, 58 (2014); https://doi.org/10.1016/j.molcata.2014.08.002
  26. H. Yang, S. Li, X. Zhang, X. Wang and J. Ma, J. Mater. Chem. A Mater. Energy Sustain., 2, 12060 (2014); https://doi.org/10.1039/C4TA01513D
  27. J. Chen, Z. Xue, S. Feng, B. Tu and D. Zhao, J. Colloid Interface Sci., 429, 62 (2014); https://doi.org/10.1016/j.jcis.2014.05.005
  28. W. Wang, Z. Meng, Q. Zhang, X. Jia and K. Xi, J. Colloid Interface Sci., 418, 1 (2014); https://doi.org/10.1016/j.jcis.2013.11.043
  29. H. Liu, C. Lin, Z. Ma, H. Yu and S. Zhou, Molecules, 18, 14258 (2013); https://doi.org/10.3390/molecules181114258
  30. S.P. Viswanathan, B.N. Narayanan, Z. Yaakob, S. Padikkaparambil and M. Mohammad, React. Kinet. Mech. Catal., 111, 335 (2014); https://doi.org/10.1007/s11144-013-0645-3
  31. Z. Zhang, C. Shao, P. Zou, P. Zhang, M. Zhang, J. Mu, Z. Guo, X. Li, C. Wang and Y. Liu, Chem. Commun., 47, 3906 (2011); https://doi.org/10.1039/c0cc05693f
  32. Z. Dong, G. Yu and X. Le, New J. Chem., 39, 8623 (2013); https://doi.org/10.1039/C5NJ00713E
  33. S. Noel, H. Bricout, A. Addad, C. Sonnendecker, W. Zimmermann, E. Monflier and B. Leger, New J. Chem., 44, 21007 (2020); https://doi.org/10.1039/D0NJ03687K
  34. T. Gia-Thien Ho, B.L. Do, B.V. Pham, T.T.V. Nguyen, H.P. Phan, H.B. Nguyen, P.P.T. Vo and N. Tri, RSC Adv., 12, 25753 (2022); https://doi.org/10.1039/D2RA04557E
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