Copyright (c) 2024 Dr. Supriya Dutta, Dr. Animesh Sahana
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthetic Fluorometric and Colorimetric Sensors for Identification of Fluoride Anion: A Short Review
Corresponding Author(s) : Animesh Sahana
Asian Journal of Chemistry,
Vol. 36 No. 7 (2024): Vol 36 Issue 7, 2024
Abstract
Over two decades of research in fluoride ion detection has been an intriguing field and many papers have been published enriching the possibilities of fluoride ion detection in even nano molar concentration levels. However, few reviews have been published, critically analyzing the design strategies, especially to detect fluoride ions in aqueous and real samples. About 21 colorimetric sensors and fluorescent probes, published during 1999 to 2014 have been covered to analyze their design strategies, speed of detection, limit of detection and their applicability in real samples and in aqueous medium. The fundamental principles can be broadly classified into 5 categories namely Si-O bond cleavage, B-F monomer formation, deprotonation of amide hydrogen, Si-F bond formation and Sb-F bond formations which enable fluoride ion detection. Variations in the organic substituents attached to the Si-O bond, B-F monomer and amide groups is the key to the efficacy of the sensor. Optimization of applicability of the sensors in aqueous solvents vis-a-vis maintaining the sensitivity, range of detection, speed of detection, both quantitatively and qualitatively are a challenge. This review aims to present a comprehensive and critically analyzed discussion of the published probes, which will encourage further research in this field.
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