Copyright (c) 2024 Renu Yadav, Anoop Kumar Sharma, ANIL YADAV
This work is licensed under a Creative Commons Attribution 4.0 International License.
Adsorption of Brilliant Green Dye Using Raw and Activated Adsorbent Prepared from Sesbania Leaves
Corresponding Author(s) : Anil Yadav
Asian Journal of Chemistry,
Vol. 36 No. 6 (2024): Vol 36 Issue 6, 2024
Abstract
In present study, the adsorption of brilliant green (BG) dye from an aqueous solution using raw sesbania leaves (RSL) and activated adsorbent of sesbania leaves (ACSL), batch adsorption studies were carried out to evaluate the effects of various parameters such as contact time, initial concentration, adsorbent dosage, pH and temperature on the removal of BG dye from aqueous solution. The maximum percentage removal of BG dye using RSL and ACSL was 73.2 and 93.8, respectively. The best-fitted isotherm for equilibrium data was Freundlich’s and Langmuir’s for ACSL and RSL adsorbents, respectively. The maximum adsorption capacities obtained were 158.74 mg/g and 98.41 mg/g for adsorption of BG dye on ACSL and RSL, respectively. The pseudo-second-order model best fit for the adsorption kinetic studies, which showed that the adsorption of BG dye on both adsorbents (RSL and ACSL) was limited by the chemisorption process. Thermodynamics parameters such as (ΔGº), (ΔHº) and (ΔSº) were also calculated. At 293 K to 333 K, the values of ΔGº lie in the range of 0.9346 to 1.1971 and 6.1199 to 9.0231 for RSL and ACSL, respectively, indicating that the adsorption process is spontaneous and endothermic.
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- K. Singh, M. Gautam, B. Chandra and A. Kumar, Desalination Water Treat., 57, 24487 (2016); https://doi.org/10.1080/19443994.2016.1141328
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- Y. Kismir and A.Z. Aroguz, Chem. Eng. J., 172, 199 (2011); https://doi.org/10.1016/j.cej.2011.05.090
- M. Ghaedi, H. Hossainian, M. Montazerozohori, A. Shokrollahi, F. Shojaipour, M. Soylak and M.K. Purkait, Desalination, 281, 226 (2011); https://doi.org/10.1016/j.desal.2011.07.068
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J.R. Sunkara and S.M. Botsa, Chem. Africa, 2, 635 (2019); https://doi.org/10.1007/s42250-019-00086-7
H. Elhleli, F. Mannai, M.B. Mosbah, R. Khiari and Y. Moussaoui, Processes, 8, 1242 (2020); https://doi.org/10.3390/pr8101242
V. Kumar, M. Sharma, S. Sondhi, K. Kaur, D. Sharma, S. Sharm and D. Utreja, Sustainability, 15, 16376 (2023); https://doi.org/10.3390/su152316376
I. M’barek, M. Gun, Y. Moussaoui, H. Arslan and N. Dizge, Int. J. Environ. Sci. Technol., 20, 4839 (2022); https://doi.org/10.1007/s13762-022-04435-x
F. Taleb, M. Ammar, M. Mosbah, R. Salem and Y. Moussaoui, Sci. Rep., 10, 11048 (2020); https://doi.org/10.1038/s41598-020-68047-6
M. Ben Mosbah, A.K.D. Alsukaibi, L. Mechi, F. Alimi and Y. Moussaoui, Water, 14, 1509 (2022); https://doi.org/10.3390/w14091509
M. Naushad, T. Ahamad, Z.A. AlOthman and A.H. Al-Muhtaseb, J. Mol. Liq., 279, 1 (2019); https://doi.org/10.1016/j.molliq.2019.01.090
Y. Zhou, J. Lu, Y. Zhou and Y. Liu, Environ. Pollut., 252, 352 (2019); https://doi.org/10.1016/j.envpol.2019.05.072
V. Yadav, D.P. Tiwari and M. Bhagat, Asian J. Chem., 30, 2765 (2018); https://doi.org/10.14233/ajchem.2018.21611
N. Sivarajasekar, R. Baskar, T. Ragu, K. Sarika, N. Preethi and T. Radhika, Appl. Water Sci., 7, 1987 (2017); https://doi.org/10.1007/s13201-016-0379-2
J. García-Montaño, X. Domènech, J.A. García-Hortal, F. Torrades and J. Peral, J. Hazard. Mater., 154, 484 (2008); https://doi.org/10.1016/j.jhazmat.2007.10.050
E. Hosseini Koupaie, M.R. Alavi Moghaddam and S.H. Hashemi, J. Hazard. Mater., 195, 147 (2011); https://doi.org/10.1016/j.jhazmat.2011.08.017
E. Alventosa-deLara, S. Barredo-Damas, M.I. Alcaina-Miranda and M.I. Iborra-Clar, J. Hazard. Mater., 209–210, 492 (2012); https://doi.org/10.1016/j.jhazmat.2012.01.065
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B.K. Körbahti, K. Artut, C. Geçgel and A. Özer, Chem. Eng. J., 173, 677 (2011); https://doi.org/10.1016/j.cej.2011.02.018
M. Sharma, R.K. Vyas and K. Singh, Adsorption, 19, 161 (2013); https://doi.org/10.1007/s10450-012-9436-9
Y. Shi, S. Zhong, X. Wang and C. Feng, Desalination Water Treat., 286, 238 (2023); https://doi.org/10.5004/dwt.2023.29340
A.N.M.A. Haque, N. Sultana, A.S.M. Sayem and S.A. Smriti, Sustainability, 14, 11098 (2022); https://doi.org/10.3390/su141711098
R. Fiaz, M. Hafeez and R. Mahmood, J. Water Reuse Desalin., 10, 70 (2020); https://doi.org/10.2166/wrd.2020.054
K. Sukla Baidya and U. Kumar, S. Afr. J. Chem. Eng., 35, 33 (2021); https://doi.org/10.1016/j.sajce.2020.11.001
R.A.E.G. Mansour, M.G. Simeda and A.A. Zaatout, RSC Adv., 11, 7851 (2021); https://doi.org/10.1039/D0RA08488C
A. Sharma and R. Anthal, Appl. Water Sci., 12, 1 (2022); https://doi.org/10.1007/s13201-021-01536-9
M. Abbas, Adsorpt. Sci. Technol., 38, 464 (2020); https://doi.org/10.1177/0263617420957829
Z. Heidarinejad, M.H. Dehghani, M. Heidari, G. Javedan, I. Ali and M. Sillanpää, Environ. Chem. Lett., 18, 393–415 (2020); https://doi.org/10.1007/s10311-019-00955-0
M.S. Bretanha, G.L. Dotto, J.C.P. Vaghetti, S.L.P. Dias, E.C. Lima and F.A. Pavan, Desalination Water Treat., 57, 28474 (2016); https://doi.org/10.1080/19443994.2016.1179223
A.F. Ali, A.S. Kovo and S.A. Adetunji, J. Encapsulation Adsorpt. Sci., 7, 95 (2017); https://doi.org/10.4236/jeas.2017.72007
A. Ragab, I. Ahmed and D. Bader, Molecules, 24, 847 (2019); https://doi.org/10.3390/molecules24050847
V. Yadav, D.P. Tiwari and M. Bhagat, Int. J. Res. Anal. Rev., 6, 958 (2019).
C. Bläker, J. Muthmann, C. Pasel and D. Bathen, ChemBioEng, 6, 119 (2019); https://doi.org/10.1002/cben.201900008
J.O. Ighalo and A.G. Adeniyi, SN Appl. Sci., 2, 509 (2020); https://doi.org/10.1007/s42452-020-2335-x
V. Yadav, D.P. Tiwari and M. Bhagat, Desalination Water Treat., 184, 214 (2020); https://doi.org/10.5004/dwt.2020.25369
K. Singh, M. Gautam, B. Chandra and A. Kumar, Desalination Water Treat., 57, 24487 (2016); https://doi.org/10.1080/19443994.2016.1141328
A. Yadav, M. Bhagat and V. Yadav, Int. J. Eng. Tech. Sci. Resch., 4, 149 (2017).
V. Yadav, D.P. Tiwari and M. Bhagat, Int. J. Basic Appl. Res., 9, 1282 (2019).
M. Bhagat, A. Yadav and V. Yadav, Int. J. Res. Advent Technol., 6, 688 (2018).
R.A. Mansour, A. El Shahawy, A. Attia and M.S. Beheary, Int. J. Chem. Eng., 2020, 1 (2020); https://doi.org/10.1155/2020/8053828
V. Yadav, D.P. Tiwari and M. Bhagat, Indian Chem. Eng., 63, 1 (2019); https://doi.org/10.1080/00194506.2019.1684212
R.M.M. Santos, R.G.L. Gonçalves, V.R.L. Constantino, C.V. Santilli, P.D. Borges, J. Tronto and F.G. Pinto, Appl. Clay Sci., 140, 132 (2017); https://doi.org/10.1016/j.clay.2017.02.005
M. Fazlzadeh, R. Khosravi and A. Zarei, Ecol. Eng., 103, 180 (2017); https://doi.org/10.1016/j.ecoleng.2017.02.052
J. Fu, Z. Chen, M. Wang, S. Liu, J. Zhang, J. Zhang, R. Han and Q. Xu, Chem. Eng. J., 259, 53 (2015); https://doi.org/10.1016/j.cej.2014.07.101
R.L. Liu, Y. Liu, X.Y. Zhou, Z.Q. Zhang, J. Zhang and F.Q. Dang, Bioresour. Technol., 154, 138 (2014); https://doi.org/10.1016/j.biortech.2013.12.034
Y. Kismir and A.Z. Aroguz, Chem. Eng. J., 172, 199 (2011); https://doi.org/10.1016/j.cej.2011.05.090
M. Ghaedi, H. Hossainian, M. Montazerozohori, A. Shokrollahi, F. Shojaipour, M. Soylak and M.K. Purkait, Desalination, 281, 226 (2011); https://doi.org/10.1016/j.desal.2011.07.068
V.S. Mane and P.V.V. Babu, Desalination, 273, 321 (2011); https://doi.org/10.1016/j.desal.2011.01.049
B.K. Nandi, A. Goswami and M.K. Purkait, J. Hazard. Mater., 161, 387 (2009); https://doi.org/10.1016/j.jhazmat.2008.03.110
L.T. Popoola, T.A. Aderibigbe, A.S. Yusuff and M.M. Munir, Environ. Qual. Manage., 28, 63 (2018); https://doi.org/10.1002/tqem.21597