Copyright (c) 2024 E. Kala, M. Yogapriya, P. Vasanthi, S. Chitrarasu
This work is licensed under a Creative Commons Attribution 4.0 International License.
Fabrication of Multifunctional (Co2+x Fe2+1-x)(Al3+yFe3+2-y)O4 Ferrite @Graphene Oxide@Titania and Its Biological Activities
Corresponding Author(s) : M. Yogapriya
Asian Journal of Chemistry,
Vol. 36 No. 6 (2024): Vol 36 Issue 6, 2024
Abstract
Recently, a variety of metal oxide-based nanomaterial has been integrated in several applications and achieved excellent performances on cyclic capacitor, antibacterial, antifungal and antioxidant activities. Titania doped cobalt aluminium ferrite fabricated graphene oxide based nanocomposites have received much attention. In this work, cobalt aluminium ferrite (Co2+xFe2+1-x)(Al3+yFe3+2-y)O4@ graphene oxide@titania nanocomposite was prepared at different ratios exhibiting the enhanced properties. Initally, the ferrite nanoparticles (Co2+xFe2+1-x)(Al3+yFe3+2-y)O4 spinal (0 ≤ x and y ≥ 2) (x = 0, 0.2, 0.4, 0.6, 0.8, 1.0 and y = 1.0, 0.8, 0.6, 0.4, 0.2, 0) powder were synthesized by substitution of A- and B-sites via sol-gel method using citrate as precursor. The obtained powder was calcined at 800 ºC for 4 h. The coating of graphene oxide was done through solvothermal hydrolysis and powder obtained was calcined at 600 ºC for 2 h followed by the second coating of titania was also performed similarly. The obtained multifuntional ferrite also showed potential antibacterial activity against Gram-negative bacteria (Escherichia coli) as well as Gram-positive bacteria (Staphylococcus aureus). The synthesized multifaceted spinal ferrites also showed moderate antioxidant activity of 59%.
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M. Faraldos and A. Bahamondem, Catal. Today, 285, 13 (2017); https://doi.org/10.1016/j.cattod.2017.01.029
A. Aguilera-Mandujano and J. Serrato-Rodriguez, Rev. Mex. Fis., 66, 610 (2020); https://doi.org/10.31349/revmexfis.66.610
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A.H. Mamaghani, F. Haghighat and C.-S. Lee, Chemosphere, 219, 804 (2019); https://doi.org/10.1016/j.chemosphere.2018.12.029
L. Ndlwana, N. Raleie, K.M. Dimpe, H.F. Ogutu, E.O. Oseghe, M.M. Motsa, T.A.M. Msagati and B.B. Mamba, Materials, 14, 5094 (2021); https://doi.org/10.3390/ma14175094
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F.S. Alruwashid, M.A. Dar, N.H. Alharthi and H.S. Abdo, Nanomaterials, 11, 2523 (2021); https://doi.org/10.3390/nano11102523
A. Lassoued, M.S. Lassoued, B. Dkhil, S. Ammar and A. Gadri, J. Mag. Magnet Mater., 476, 124 (2019); https://doi.org/10.1016/j.jmmm.2018.12.062
B. Ingale, D. Nadargi, J. Nadargi, R. Suryawanshi, H. Shaikh, M.A. Alam, M.S. Tamboli and S.S. Suryavanshi, ACS Omega, 8, 30508 (2023); https://doi.org/10.1021/acsomega.3c03757
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B.A. Patil and R.D. Kokate, Proc. Manufact., 20, 147 (2018); https://doi.org/10.1016/j.promfg.2018.02.021
V. Vaithyanathan, K. Ugendar, J.A. Chelvane, K.K. Bharathi and S.S.R. Inbanathan, J. Magnet. Magn. Mater., 382, 88 (2015); https://doi.org/10.1016/j.jmmm.2015.01.052
A. Hao and X. Ning, Front. Mater., 8, 718869 (2021); https://doi.org/10.3389/fmats.2021.718869
M. Colombo, S. Carregal-Romero, M.F. Casula, L. Gutierez, M.P. Morales, I.B. Bohm, J.T. Heverhagen, D. Prosperi and W.J. Parak, Chem. Soc. Rev., 41, 4306 (2012); https://doi.org/10.1039/c2cs15337h
A. Sandhu, H. Handa and M. Abe, Nanotechnology, 21, 442001 (2010); https://doi.org/10.1088/0957-4484/21/44/442001
M.D. Butterworth, S.A. Bell, S.P. Armes and A.W. Simpson, J. Colloid Interface Sci., 183, 91 (1996); https://doi.org/10.1006/jcis.1996.0521
Z.-J. Fan, W. Kai, J. Yan, T. Wei, L.-J. Zhi, J. Feng, Y. Ren, L.-P. Song and F. Wei, ACS Nano, 5, 191 (2011); https://doi.org/10.1021/nn102339t
C. Nethravathi and M. Rajamathi, Carbon, 46, 1994 (2008); https://doi.org/10.1016/j.carbon.2008.08.013
T. Szabo, O. Berkesi, P. Forgó, K. Josepovits, Y. Sanakis, D. Petridis and I. Dékány, Chem. Mater., 18, 2740 (2006); https://doi.org/10.1021/cm060258+
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K. Venkat Savunthari and S. Shanmugam, J. Taiwan Inst. Chem. Eng., 101, 105 (2019); https://doi.org/10.1016/j.jtice.2019.04.042
C. Ramesh, K. Maniysundar and S. Selvanandan, Mater. Today: Proc., 3, 1569 (2016); https://doi.org/10.1016/j.matpr.2016.04.044
T. Saemian, M. Gharagozlou, M.H. Sadr and S. Naghibi, J. Inorg. Organomet. Polym., 30, 2347 (2020); https://doi.org/10.1007/s10904-019-01406-7
C.M. Magdalane, G.M.A. Priyadharsini, K. Kaviyarasu, A.I. Jothi and G.G. Simiyon, Surf. Interfaces, 25, 101296 (2021); https://doi.org/10.1016/j.surfin.2021.101296
K. Khalid, A. Zahra, U. Amara, M. Khalid, M. Hanif, K. Mahmood, M. Aziz, M. Ajmal, M. Asif, K. Saeed, M.F. Qayyum and W. Abbas, Chemosphere, 338, 139531 (2023); https://doi.org/10.1016/j.chemosphere.2023.139531
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