Copyright (c) 2024 Hafiz Omer Ahmed, Attaelmanan Gaffar Attaelmanan, Muath Khairi Mousa
This work is licensed under a Creative Commons Attribution 4.0 International License.
Determination of Metals in Children’s Plastic Toys using Inductively Coupled Plasma Optical Emission Spectrometry
Corresponding Author(s) : Hafiz Omer Ahmed
Asian Journal of Chemistry,
Vol. 36 No. 6 (2024): Vol 36 Issue 6, 2024
Abstract
Children’s health and safety may be compromised if exposed to metals through contaminated toys. Hence, evaluation of the quality of the toys available in markets is essential to protect children. This study undertaken to identify the presence of metals contents in plastic toys and compares the results with the national and international limits. For this purpose, 56 types of popular children’s toys marked were purchased from the UAE markets and the metal contents were estimated in 156 toy samples by inductively coupled plasma-optical emission spectrometry (ICP-OES) technique. The results reveal that Ti, Fe, Zn and Mg were present in all types of toys. At the same time, other metals such as K and Na in 54 types of toys, Cr in 51 types of toys, Al in 50 types of toys, B, Ba and Ca in types of 49 toys, Mn in 41 types of toys, Cd in 40 types of toys, Ag in 39 types of toys, Ni in 25 types of toys, Pd in 23 types of toys, Cu in 18 types of toys, Bi in 4 types of toys and Co in 3 types of toys were also detected. Furthermore, Pd and B concentrations in 3 types of toys, while Zn and Ba concentrations in two types of toys exceeded the permissible limits. Toxic stabilizers and colours added to PVC during manufacturing are responsible for the existence of such elements in plastic toys. However, additional research is required to establish the role of metals in toys, identify potential risks to children’s health and propose regulations.
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T. Murphy, S. Lim, S. Kim, K. Irvine, W. Chaiwat and K. Wilson, J. Health Pollut., 6, 47 (2016); https://doi.org/10.5696/2156-9614-6-11.47
M.M. Hillyer, L.E. Finch, A.S. Cerel, J.D. Dattelbaum and M.C. Leopold, Chemosphere, 108, 205 (2014); https://doi.org/10.1016/j.chemosphere.2014.01.041
J.L. Yost and J.D. Weidenhamer, Sci. Total Environ., 393, 348 (2008); https://doi.org/10.1016/j.scitotenv.2008.01.009
T. Sanders, Y. Liu, V. Buchner and P.B. Tchounwou, Rev. Environ. Health, 24, 15 (2009); https://doi.org/10.1515/reveh.2009.24.1.15
R.A. Bernhoft, J. Environ. Public Health, 2012, 460508 (2012); https://doi.org/10.1155/2012/460508
H.-W. Huang, C.-H. Lee and H.-S. Yu, Int. J. Environ. Res. Public Health., 16, 2746 (2019); https://doi.org/10.3390/ijerph16152746
M. Jaishankar, T. Tseten, N. Anbalagan, B.B. Mathew and K.N. Beeregowda, Interdiscip Toxicol., 7, 60 (2014); https://doi.org/10.2478/intox-2014-0009
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N. Yazdanfar, N. Vakili Saatloo and P. Sadighara, Environ. Sci. Pollut. Res. Int., 29, 68441 (2022); https://doi.org/10.1007/s11356-022-20720-1
M. Negev, T. Berman, S. Reicher, M. Sadeh, R. Ardi and Y. Shammai, Chemosphere, 192, 217 (2018); https://doi.org/10.1016/j.chemosphere.2017.10.132
J.A. Greenway and S. Gerstenberger, Bull. Environ. Contam. Toxicol., 85, 363 (2010); https://doi.org/10.1007/s00128-010-0100-3
M. Guney and G.J. Zagury, Environ. Sci. Technol., 47, 5921 (2013); https://doi.org/10.1021/es304969n
T. Mohammed, D. Dial, D. Maharaj, C. Smith, N. Persad, S. Mohammed and A. Mohammed, J. Environ. Chem. Ecotoxicol., 12, 59 (2020).
A. Turner, Environ. Sci. Technol., 52, 3110 (2018); https://doi.org/10.1021/acs.est.7b04685
T. Vo, T. Tran, T. Nguyen and T. Nguyen, Int. J. Innov. Stud. Sci. Eng. Technol., 3, 11 (2017).
S.G. Kang and J.X. Zhu, Adv. Mater. Res., 878, 112 (2014); https://doi.org/10.4028/www.scientific.net/AMR.878.112
M. Becker, S. Edwards and R.I. Massey, Environ. Sci. Technol., 44, 7986 (2010); https://doi.org/10.1021/es1009407
S.Y. Njati and M.M. Maguta, Environ. Pollut., 249, 1091 (2019); https://doi.org/10.1016/j.envpol.2019.03.062
J.D. Weidenhamer, B.E. Newman and A. Clever, J. Hazard. Mater., 177, 1150 (2010); https://doi.org/10.1016/j.jhazmat.2010.01.016
L.E. Finch, M.M. Hillyer and M.C. Leopold, J. Chem. Educ., 92, 849 (2015); https://doi.org/10.1021/ed500647w
A.A. Dahab, D.E.A. Elhag, A.B. Ahmed and H.A. Al-Obaid, Environ. Sci. Pollut. Res. Int., 23, 3406 (2016); https://doi.org/10.1007/s11356-015-5594-0
European Commission, New Version of Toy Safety Standard EN 71-3:2019 on Migration of Certain Elements (2019).
ASTM ASTM F963-17: Standard Consumer Safety Specification for Toy Safety (2017).
GCC Standardization Organization (GSO), GCC Technical Regulation on Children Toys, Issue No. 2 (2013).
H.O. Ahmed, A.G. Attaelmanan, F.I. Alshaer and E.M. Abdallah, Environ. Sci. Pollut. Res. Int., 28, 43970 (2021); https://doi.org/10.1007/s11356-021-13838-1
J.H. Duffus, Pure Appl. Chem., 74, 793 (2002); https://doi.org/10.1351/pac200274050793
A. Kumar and P. Pastore, Curr. Sci., 93, 818 (2007).
C.A. Erdogdu, S. Atakul, D. Balköse and S. Ülkü, Chem. Eng. Commun., 196, 148 (2008); https://doi.org/10.1080/00986440802293148
S.N.S. Ismail, N.S. Mohamad, K. Karuppiah, E.Z. Abidin, I. Rasdi and S.M. Praveena, APRN J. Eng. Appl. Sci., 12, 1499 (2017).
M. Lim, S. Guak, N.Y. Cheong, Y.C. Song, K.-F. Ho, S. Nakai, S.-C.C. Lung, K. Tantrakarnapa and K. Lee, J. Expo. Sci. Environ. Epidemiol., 32, 103 (2022); https://doi.org/10.1038/s41370-021-00321-9
M. Al-Qutob, A. Asafra, T. Nashashibi and A.A. Qutob, J. Environ. Prot., 5, 1104 (2014); https://doi.org/10.4236/jep.2014.512108
S.I. Korfali, R. Sabra, M. Jurdi and R.I. Taleb, Arch. Environ. Contam. Toxicol., 65, 368 (2013); https://doi.org/10.1007/s00244-013-9925-1
J.A. Omolaomolaoye, A. Uzairu and C.E. Gimba, J. Environ. Chem. Ecotoxicol., 2, 126 (2010).
M. Corazza, F. Baldo, A. Pagnoni, R. Miscioscia and A. Virgili, Acta Derm. Venereol., 89, 130 (2009); https://doi.org/10.2340/00015555-0595