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Vol. 36 No. 5 (2024): Vol 36 Issue 5, 2024

Copyright (c) 2024 Chandan Maurya, Sangeeta Bajpai, Pramod Kumar Kushwaha, Umesh Chand, Sunita Singh

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Synthesis, Characterization and in vitro Antimicrobial Activity of Organotellurium Decorated 10-Membered Tetraazamacrocyclic Complexes of Cobalt(II)

https://doi.org/10.14233/ajchem.2024.31358
Chandan Maurya
Department of Chemistry, Amity School of Applied Sciences, Amity University Lucknow Campus, Lucknow-226010, India Department of Chemistry, Navyug Kanya Mahavidyalaya (Affliated to Lucknow, University), Lucknow-226004, India
https://orcid.org/0000-0002-6223-9100
Sangeeta Bajpai
Department of Chemistry, Amity School of Applied Sciences, Amity University Lucknow Campus, Lucknow-226010, India
https://orcid.org/0000-0003-1576-9325
Pramod Kumar Kushwaha
Department of Microbiology, School of Basic Sciences, Central University of Punjab, Bathinda-151401, India
https://orcid.org/0000-0002-6186-0456
Umesh Chand
Department of Microbiology, School of Basic Sciences, Central University of Punjab, Bathinda-151401, India
https://orcid.org/0000-0002-9268-4088
Sunita Singh
Department of Chemistry, Navyug Kanya Mahavidyalaya (Affliated to Lucknow, University), Lucknow-226004, India
https://orcid.org/0000-0002-8655-0649

Corresponding Author(s) : Chandan Maurya

cmaurya647@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 5 (2024): Vol 36 Issue 5, 2024

Abstract

Three novel organotellurium decorated 10-membered tetraazamacrocyclic complexes of Co(II) were synthesized using template condensation of 1,1-diiodo-1-telluracyclopentane, 1,1-diodo-2-methyl-1-telluracyclopentane and 1,1-diiodo-1,1-diethyltellurium(IV) with 1,2-diaminopropane and cobalt dichloride hexahydrate in dry methanol in 2:2:1 molar ratio. The characterization of the synthesized cobalt(II) complexes was carried out using elemental analysis, spectroscopic studies (IR, proton NMR & proton decoupled carbon NMR) and molar conductance measurements. The results of these studies suggested that the complexes may be formulated as [CoLCl2] where L = {C4H8Te-(NHCH2CH(CH3)NH)}2, {C4H7(CH3)Te(NHCH2CH(CH3)NH)}2 and {(C2H5)2Te(NHCH2CH(CH3)NH)}2. The synthesized complexes were also screened for antimicrobial activity using broth microdilution and agar disc diffusion methods.

Keywords

Organotellurium Macrocyclic complexes Spectroscopic studies Antimicrobial activity
Maurya, C., Bajpai, S., Kushwaha, P. K., Chand, U., & Singh, S. (2024). Synthesis, Characterization and in vitro Antimicrobial Activity of Organotellurium Decorated 10-Membered Tetraazamacrocyclic Complexes of Cobalt(II). Asian Journal of Chemistry, 36(5), 1056–1060. https://doi.org/10.14233/ajchem.2024.31358
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