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Solubility of Hydrogen, Carbon Monoxide and 1-Decene in Water, Toluene and Water-N-methyl-2-pyrrolidone Biphasic Solvent Mixtures
Corresponding Author(s) : N.S. Pagar
Asian Journal of Chemistry,
Vol. 36 No. 5 (2024): Vol 36 Issue 5, 2024
Abstract
The solubility of carbon monoxide and hydrogen has been determined experimentally as a function of their pressure in toluene, water and water-N-methyl-2-pyrrolidone (70:30 v/v) mixtures in the 383-403 K temperature range. The value of Henry’s constant for hydrogen and carbon monoxide was determined in all three solvent systems. Pressure had a linear influence on all systems, as predicted by Henry’s law. Through experimentation, the solubility of 1-decene in the organic and aqueous phase was established. The experimental data for the liquid-liquid equilibrium of 1-decene in a toluene and water-N-methyl-2-pyrrolidone mixture has been evaluated in the temperature range of 383-403 K. Temperature has a negligible effect on 1-decene solubility in the aqueous phase, but a significant effect in water-N-methyl-2-pyrrolidone (70:30 v/v) combination. The study of the solubility of hydrogen and carbon monoxide in organic and water-N-methyl-2-pyrrolidone mixture can be used for the kinetic study.
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- R. Battino and H.L. Clever, Chem. Rev., 66, 395 (1966); https://doi.org/10.1021/cr60242a003
- E. Wilhelm, Pure Appl. Chem., 57, 303 (1985); https://doi.org/10.1351/pac198557020303
- P.G.T. Fogg, Monatsh. Chem., 134, 619 (2003); https://doi.org/10.1007/s00706-002-0580-x
- B. Cornils and W.A. Hermann, Aqueous-Phase Organometallic Catalysis, Concepts and Application, Wiley VCH Verlag GmbH: Weinheim (1998).
- Purwanto, R.M. Deshpande, R.V. Chaudhari and H. Delmas, J. Chem. Eng. Data, 41, 1414 (1996); https://doi.org/10.1021/je960024e
- Z. Lei, C. Dai and B. Chen, Chem. Rev., 114, 1289 (2014); https://doi.org/10.1021/cr300497a
- U.J. Jáuregui-Haza, E.J. Pardillo-Fontdevila, A.M. Wilhelm and H. Delmas, Lat. Am. Appl. Res., 34, 71 (2004); https://www.researchgate.net/publication/270753376
- M.S. Shaharun, H. Mukhtar and B.K. Dutta, Chem. Eng. Sci., 63, 3024 (2008); https://doi.org/10.1016/j.ces.2008.02.035
- F. Wu, Q. Zhao, L. Tao, D. Danaci, P. Xiao, F.A. Hasan and P.A. Webley, J. Chem. Eng. Data, 64, 5609 (2019); https://doi.org/10.1021/acs.jced.9b00676
- I. Hablot, J. Jenck, G. Casamatta and H. Delmas, Chem. Eng. Sci., 47, 2689 (1992); https://doi.org/10.1016/0009-2509(92)87114-6
- C.L. Young, IUPAC Solubility Series, Vol. 5/6 Hydrogen and Deuterium, Pergamon Press: Oxford, U.K. (1981).
- R.W. Cargill, IUPAC Solubility Series Vol. 43 Carbon Monoxide, Pergamon Press: Oxford, U.K. (1990).
- W.F. Linke and A. Siedell, Solubilities of Inorganic and Metal Organic Compounds, Van Nostrand: Princeton, NJ (1958).
- R.W. Cargill, J. Chem. Soc., Faraday Trans. I, 74, 1444 (1978); https://doi.org/10.1039/f19787401444
- N.S. Pagar and R.M. Deshpande, Asian J. Chem., 32, 2061 (2020); https://doi.org/10.14233/ajchem.2020.22735
- N.S. Pagar and R.M. Deshpande, Int. J. Chem. Kinet., 53, 333 (2021); https://doi.org/10.1002/kin.21446
References
R. Battino and H.L. Clever, Chem. Rev., 66, 395 (1966); https://doi.org/10.1021/cr60242a003
E. Wilhelm, Pure Appl. Chem., 57, 303 (1985); https://doi.org/10.1351/pac198557020303
P.G.T. Fogg, Monatsh. Chem., 134, 619 (2003); https://doi.org/10.1007/s00706-002-0580-x
B. Cornils and W.A. Hermann, Aqueous-Phase Organometallic Catalysis, Concepts and Application, Wiley VCH Verlag GmbH: Weinheim (1998).
Purwanto, R.M. Deshpande, R.V. Chaudhari and H. Delmas, J. Chem. Eng. Data, 41, 1414 (1996); https://doi.org/10.1021/je960024e
Z. Lei, C. Dai and B. Chen, Chem. Rev., 114, 1289 (2014); https://doi.org/10.1021/cr300497a
U.J. Jáuregui-Haza, E.J. Pardillo-Fontdevila, A.M. Wilhelm and H. Delmas, Lat. Am. Appl. Res., 34, 71 (2004); https://www.researchgate.net/publication/270753376
M.S. Shaharun, H. Mukhtar and B.K. Dutta, Chem. Eng. Sci., 63, 3024 (2008); https://doi.org/10.1016/j.ces.2008.02.035
F. Wu, Q. Zhao, L. Tao, D. Danaci, P. Xiao, F.A. Hasan and P.A. Webley, J. Chem. Eng. Data, 64, 5609 (2019); https://doi.org/10.1021/acs.jced.9b00676
I. Hablot, J. Jenck, G. Casamatta and H. Delmas, Chem. Eng. Sci., 47, 2689 (1992); https://doi.org/10.1016/0009-2509(92)87114-6
C.L. Young, IUPAC Solubility Series, Vol. 5/6 Hydrogen and Deuterium, Pergamon Press: Oxford, U.K. (1981).
R.W. Cargill, IUPAC Solubility Series Vol. 43 Carbon Monoxide, Pergamon Press: Oxford, U.K. (1990).
W.F. Linke and A. Siedell, Solubilities of Inorganic and Metal Organic Compounds, Van Nostrand: Princeton, NJ (1958).
R.W. Cargill, J. Chem. Soc., Faraday Trans. I, 74, 1444 (1978); https://doi.org/10.1039/f19787401444
N.S. Pagar and R.M. Deshpande, Asian J. Chem., 32, 2061 (2020); https://doi.org/10.14233/ajchem.2020.22735
N.S. Pagar and R.M. Deshpande, Int. J. Chem. Kinet., 53, 333 (2021); https://doi.org/10.1002/kin.21446