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Vol. 36 No. 5 (2024): Vol 36 Issue 5, 2024

Copyright (c) 2024 Suresh F. Madar, Avinash C. Mendhe, Ahmedraza Mavazzan, Praveen K. Bayannavar, Babasaheb R. Sankapal, Ravindra R. Kamble, Vishwa B. Nadoni, Mussuvir Pasha

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Novel Phenothiazine and Coumarin based Sensitizers: Design, Synthesis and Photoelectrochemical Application by Anchoring on CdS Nanowires

https://doi.org/10.14233/ajchem.2024.31400
Suresh F. Madar
Department of Studies in Chemistry, Karnatak University Dharwad-580003, India
https://orcid.org/0000-0002-4497-2296
Avinash C. Mendhe
Department of Physics, Visvesvaraya National Institute of Technology, Nagpur-440010, India
https://orcid.org/0000-0003-4513-1066
Ahmedraza Mavazzan
Department of Studies in Chemistry, Karnatak University Dharwad-580003, India
https://orcid.org/0000-0002-3457-2424
Praveen K. Bayannavar
Department of Studies in Chemistry, Karnatak University Dharwad-580003, India
https://orcid.org/0000-0001-5330-4719
Babasaheb R. Sankapal
Department of Physics, Visvesvaraya National Institute of Technology, Nagpur-440010, India
https://orcid.org/0000-0002-7464-9633
Vishwa B. Nadoni
Department of Studies in Chemistry, Karnatak University Dharwad-580003, India
https://orcid.org/0000-0002-1465-1125
Ravindra R. Kamble
Department of Studies in Chemistry, Karnatak University Dharwad-580003, India
https://orcid.org/0000-0002-0384-655X
Mussuvir Pasha
Department of Chemistry, Karnatak Science College, Dharwad-580003, India
https://orcid.org/0000-0002-9092-886X

Corresponding Author(s) : Ravindra R. Kamble

ravichem@kud.ac.in

Asian Journal of Chemistry, Vol. 36 No. 5 (2024): Vol 36 Issue 5, 2024

Abstract

Novel metal-free organic dyes (E)-2-cyano-3-(10-(prop-2-yn-1-yl)-10H-phenothiazin-3-yl)acrylic acid (PPC) and (E)-2-cyano-3-(10-((1-((7-methyl-2-oxo-2H-chromen-4-yl)methyl)-1H-1,2,3-triazol-4-yl)methyl)-4a,10a-dihydro-10H-phenothiazin-3-yl)acrylic acid (PCTC) was synthesized and then anchored to 1D cadmium sulfide nanowires (1D CdS NWs) for application in photoelectrochemical dye-sensitized solar cell (DSSC). The 1D CdS nanowires were interconnected into a nanonetwork using solution chemistry in a straightforward and efficient manner. The UV-visible spectroscopy, cyclic voltammetry and density functional theory (DFT) were effectively employed to analyze the characteristics of PPC and PCTC. The sensitizer-anchored CdS nanowires have a broader range of light absorption in the UV-visible spectrum compared to bare CdS nanowires. The complete device has the assembly FTO, compact CdS, CdS nanowires, synthesized dye and counter electrode. In photovoltaic assessment, the PCTC and PPC devices yield 3.19 and 3.04 times, respectively, more efficiency than naked CdS nanowires under conventional sunshine illumination (100 mW/cm2, AM 1.5G). The obtained results provide strong evidence supporting the presence of rising external quantum efficiency (EQE) and show a high level of consistency with the optical tests.

Keywords

Dye-sensitized solar cells CdS nanowires CdS compact Cyanoacetic acid Sensitizers
Madar, S. F., Mendhe, A. C., Mavazzan, A., Bayannavar, P. K., Sankapal, B. R., Nadoni, V. B., … Pasha, M. (2024). Novel Phenothiazine and Coumarin based Sensitizers: Design, Synthesis and Photoelectrochemical Application by Anchoring on CdS Nanowires. Asian Journal of Chemistry, 36(5), 1142–1150. https://doi.org/10.14233/ajchem.2024.31400
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