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Vol. 36 No. 5 (2024): Vol 36 Issue 5, 2024

Copyright (c) 2024 Bidyut Akhuli

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Metal-Ligand Coordination Driven Di/Tri-nuclear Helicate and Mesocate: A Brief Review

https://doi.org/10.14233/ajchem.2024.31331
Bidyut Akhuli
Department of Chemistry, Chunaram Gobinda Memorial Government College (Formerly Government General Degree College, Manbazar-II), Purulia-723131, India
https://orcid.org/0009-0001-3795-2668

Corresponding Author(s) : Bidyut Akhuli

akhuli.bidyut2009@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 5 (2024): Vol 36 Issue 5, 2024

Abstract

Helicity is a geometric motif that can be observed in nature as well as artificial structures. In synthetic supramolecular architectures, helicity can be incorporated by conformational restrictions of macromolecules, inter- or intra- molecular hydrogen bonds or coordination to metal ions. In present brief review, the discussions will be restricted on the metal-ligand coordination driven self-assembled di/tri-nuclear helical structures. Furthermore, the chirality of the helical structures is enlightened, which arises due to preferential orientation of the ligand strands around the metal centers that comprise the formation of two type helicates, one is homo-chiral helicate and the other is hetero-chiral helicate or mesocate.

Keywords

Self-assembly Helicate Mesocate Homo-chiral Hetero-chiral
Akhuli, B. (2024). Metal-Ligand Coordination Driven Di/Tri-nuclear Helicate and Mesocate: A Brief Review. Asian Journal of Chemistry, 36(5), 1009–1016. https://doi.org/10.14233/ajchem.2024.31331
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