Copyright (c) 2024 MD NURUL ISLAM SIDDIQUE
This work is licensed under a Creative Commons Attribution 4.0 International License.
Production of Methane and Hydrogen from Mild-Strength Industrial Wastewater
Corresponding Author(s) : Md. Nurul Islam Siddique
Asian Journal of Chemistry,
Vol. 36 No. 4 (2024): Vol 36 Issue 4, 2024
Abstract
Over the past two decades, fossil fuel reserves have sharply shrunk, which has resulted in a global fall in energy sources. Alternative carbon-neutral renewable energy sources have caught the interest of experts due to the erratic nature of energy prices and their severe ecological effects. The treatment plant’s mild-strength effluent from an equalization tank at an industrial factory was used in this study to generate hydrogen and methane. This mild-strength effluent had a chemical oxygen demand (COD) content of 2.8 ± 1.0 g COD/L. A double stage anaerobic digestion system’s hydrogen-generating digester was run at a hydraulic retention time of 8 h while the methane-generating digester was run at a hydraulic retention time of 24 h. The highest methane production rate (MPR), methane yield (MY), methane content and COD elimination were, in order, 71 ± 30 mL/L-d, 57 ± 10 mL/g COD, 90 ± 1% and 77%, respectively. In this experiment, energy efficiency was assessed using the following criteria: Maximum heating was at a value of 2.1 × 108 kcal/y. Utilizing energy-equivalent coal, natural gas, or fuel reduced annual carbon emissions by 8.7 × 104 kg CO2/y, 5.1 × 104 kg CO2/y and 7.1 × 104 kg CO2/y, respectively.
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- J. Malinauskaite, H. Jouhara, D. Czajczyñska, P. Stanchev, E. Katsou, P. Rostkowski, R.J. Thorne, J. Colón, S. Ponsá, F. Al-Mansour, L. Anguilano, R. Krzyzynska, I.C. López, A.Vlasopoulos and N. Spencer, Energy, 141, 2013 (2017); https://doi.org/10.1016/j.energy.2017.11.128
- M.N.I. Siddique and Z.A. Wahid, J. Clean. Prod., 194, 359 (2018); https://doi.org/10.1016/j.jclepro.2018.05.155
- M.N.I. Siddique, M.S. Abdul Munaim and A.W. Zularisam, J. Clean. Prod., 106, 380 (2015); https://doi.org/10.1016/j.jclepro.2014.08.003
- B.K. Zaied, M. Nasrullah, M.N.I. Siddique, A.W. Zularisam, L. Singh and S. Krishnan, Sci. Total Environ., 706, 136095 (2020); https://doi.org/10.1016/j.scitotenv.2019.136095
- B.K. Zaied, M. Nasrullah, M.N. Islam Siddique, A.W. Zularisam, L. Singh and S. Krishnan, J. Environ. Chem. Eng., 8, 103551 (2020); https://doi.org/10.1016/j.jece.2019.103551
- F.M. Liew, M.E. Martin, R.C. Tappel, B.D. Heijstra, C. Mihalcea and M. Köpke, Front. Microbiol., 7, 694 (2016); https://doi.org/10.3389/fmicb.2016.00694
- T. Nevzorova and V. Kutcherov, Energy Strategy Rev., 26, 100414 (2019); https://doi.org/10.1016/j.esr.2019.100414
- M.N. Islam Siddique, Z.B. Khalid and M.Z.B. Ibrahim, J. Environ. Chem. Eng., 8, 103569 (2020); https://doi.org/10.1016/j.jece.2019.103569
- M.A. Dareioti, A.I. Vavouraki, K. Tsigkou and M. Kornaros, Energies, 14, 5423 (2021); https://doi.org/10.3390/en14175423
- A. Schievano, A. Tenca, S. Lonati, E. Manzini and F. Adani, Appl. Energy, 124, 335 (2014); https://doi.org/10.1016/j.apenergy.2014.03.024
- M.N.I. Siddique, M.S.A. Munaim and A.W. Zularisam, J. Taiwan Inst. Chem. Eng., 58, 451 (2016); https://doi.org/10.1016/j.jtice.2015.06.038
- T.J. Tse, D.J. Wiens and M.J.T. Reaney, Fermentation, 7, 268 (2021); https://doi.org/10.3390/fermentation7040268
- N.A. Mohidem, M. Mohamad, M.U. Rashid, M.N. Norizan, F. Hamzah and H.N. Mat, J. Compos. Sci., 7, 488 (2023); https://doi.org/10.3390/jcs7120488
- M.N.I. Siddique and Z.B.A. Wahid, Water Environ. Res., 90, 835 (2018); https://doi.org/10.2175/106143017X15131012153031
- N.I. Siddique and Z.A. Wahid, J. Environ. Sci. Technol., 5, 155 (2012); https://doi.org/10.3923/jest.2012.155.167
- B.K. Zaied, M.N.I. Siddique, A.W. Zularisam, M.F. Ahmad and Y.M. Salih, Asian J. Chem., 31, 2413 (2019); https://doi.org/10.14233/ajchem.2019.22196
- M.N.I. Siddique, M.S.A. Munaim and Z.B.A. Wahid, J. Clean. Prod., 145, 303 (2017); https://doi.org/10.1016/j.jclepro.2017.01.061
- Z.B. Khalid, M.N.I. Siddique, A. Nayeem, T.M. Adyel, S.B. Ismail and M.Z. Ibrahim, J. Environ. Chem. Eng., 9, 105489 (2021); https://doi.org/10.1016/j.jece.2021.105489
- S. Krishnan, L. Singh, P. Mishra, M. Nasrullah, M. Sakinah, S. Thakur, N.I. Siddique and Z.A. Wahid, Environ. Technol. Innov., 8, 360 (2017); https://doi.org/10.1016/j.eti.2017.08.005
- Z.B. Khalid, M.N.I. Siddique, M. Nasrullah, L. Singh, Z.B.A. Wahid and M.F. Ahmad, Environ. Technol. Innov., 16, 100446 (2019); https://doi.org/10.1016/j.eti.2019.100446
- M.N.I. Siddique, M. Sakinah Abd Munaim and A.W. Zularisam, J. Ind. Eng. Chem., 20, 331 (2014); https://doi.org/10.1016/j.jiec.2013.03.030
- P.N.Y. Yek, C. Li, W. Peng, C.S. Wong, R.K. Liew, W.A. Wan Mahari, C. Sonne and S.S. Lam, Chem. Eng. J., 425, 131886 (2021); https://doi.org/10.1016/j.cej.2021.131886
- Q. Yang, S. Ravnskov, J.W.M. Pullens and M.N. Andersen, Sci. Total Environ., 816, 151649 (2022); https://doi.org/10.1016/j.scitotenv.2021.151649
- Z. Shi, M. Usman, J. He, H. Chen, S. Zhang and G. Luo, Water Res., 205, 117679 (2021); https://doi.org/10.1016/j.watres.2021.117679
- Y. Li, X. Chen, L. Liu, P. Liu, Z. Zhou, Y. Huhetaoli, Y. Wu and T. Lei, J. Anal. Appl. Pyrolysis, 162, 105449 (2022); https://doi.org/10.1016/j.jaap.2022.105449
- A. Pant and J.P.N. Rai, Environ. Challenges, 5, 100262 (2021); https://doi.org/10.1016/j.envc.2021.100262
- G. Kaur, D. Johnravindar and J.W.C. Wong, Bioresour. Technol., 308, 123250 (2020); https://doi.org/10.1016/j.biortech.2020.123250
- D. Johnravindar, J.W.C. Wong, D. Chakraborty, G. Bodedla and G. Kaur, J. Environ. Manage., 290, 112457 (2021); https://doi.org/10.1016/j.jenvman.2021.112457
- Z. Yang, Z. Wang, G. Liang, X. Zhang and X. Xie, Chem. Eng. J., 426, 131777 (2021); https://doi.org/10.1016/j.cej.2021.131777
- F. Zheng, J. Fang, F. Guo, X. Yang, T. Liu, M. Chen, M. Nie and Y.C. Chen, Eng. J. (N.Y.), 432, 134377 (2022); https://doi.org/10.1016/j.cej.2021.134377
References
J. Malinauskaite, H. Jouhara, D. Czajczyñska, P. Stanchev, E. Katsou, P. Rostkowski, R.J. Thorne, J. Colón, S. Ponsá, F. Al-Mansour, L. Anguilano, R. Krzyzynska, I.C. López, A.Vlasopoulos and N. Spencer, Energy, 141, 2013 (2017); https://doi.org/10.1016/j.energy.2017.11.128
M.N.I. Siddique and Z.A. Wahid, J. Clean. Prod., 194, 359 (2018); https://doi.org/10.1016/j.jclepro.2018.05.155
M.N.I. Siddique, M.S. Abdul Munaim and A.W. Zularisam, J. Clean. Prod., 106, 380 (2015); https://doi.org/10.1016/j.jclepro.2014.08.003
B.K. Zaied, M. Nasrullah, M.N.I. Siddique, A.W. Zularisam, L. Singh and S. Krishnan, Sci. Total Environ., 706, 136095 (2020); https://doi.org/10.1016/j.scitotenv.2019.136095
B.K. Zaied, M. Nasrullah, M.N. Islam Siddique, A.W. Zularisam, L. Singh and S. Krishnan, J. Environ. Chem. Eng., 8, 103551 (2020); https://doi.org/10.1016/j.jece.2019.103551
F.M. Liew, M.E. Martin, R.C. Tappel, B.D. Heijstra, C. Mihalcea and M. Köpke, Front. Microbiol., 7, 694 (2016); https://doi.org/10.3389/fmicb.2016.00694
T. Nevzorova and V. Kutcherov, Energy Strategy Rev., 26, 100414 (2019); https://doi.org/10.1016/j.esr.2019.100414
M.N. Islam Siddique, Z.B. Khalid and M.Z.B. Ibrahim, J. Environ. Chem. Eng., 8, 103569 (2020); https://doi.org/10.1016/j.jece.2019.103569
M.A. Dareioti, A.I. Vavouraki, K. Tsigkou and M. Kornaros, Energies, 14, 5423 (2021); https://doi.org/10.3390/en14175423
A. Schievano, A. Tenca, S. Lonati, E. Manzini and F. Adani, Appl. Energy, 124, 335 (2014); https://doi.org/10.1016/j.apenergy.2014.03.024
M.N.I. Siddique, M.S.A. Munaim and A.W. Zularisam, J. Taiwan Inst. Chem. Eng., 58, 451 (2016); https://doi.org/10.1016/j.jtice.2015.06.038
T.J. Tse, D.J. Wiens and M.J.T. Reaney, Fermentation, 7, 268 (2021); https://doi.org/10.3390/fermentation7040268
N.A. Mohidem, M. Mohamad, M.U. Rashid, M.N. Norizan, F. Hamzah and H.N. Mat, J. Compos. Sci., 7, 488 (2023); https://doi.org/10.3390/jcs7120488
M.N.I. Siddique and Z.B.A. Wahid, Water Environ. Res., 90, 835 (2018); https://doi.org/10.2175/106143017X15131012153031
N.I. Siddique and Z.A. Wahid, J. Environ. Sci. Technol., 5, 155 (2012); https://doi.org/10.3923/jest.2012.155.167
B.K. Zaied, M.N.I. Siddique, A.W. Zularisam, M.F. Ahmad and Y.M. Salih, Asian J. Chem., 31, 2413 (2019); https://doi.org/10.14233/ajchem.2019.22196
M.N.I. Siddique, M.S.A. Munaim and Z.B.A. Wahid, J. Clean. Prod., 145, 303 (2017); https://doi.org/10.1016/j.jclepro.2017.01.061
Z.B. Khalid, M.N.I. Siddique, A. Nayeem, T.M. Adyel, S.B. Ismail and M.Z. Ibrahim, J. Environ. Chem. Eng., 9, 105489 (2021); https://doi.org/10.1016/j.jece.2021.105489
S. Krishnan, L. Singh, P. Mishra, M. Nasrullah, M. Sakinah, S. Thakur, N.I. Siddique and Z.A. Wahid, Environ. Technol. Innov., 8, 360 (2017); https://doi.org/10.1016/j.eti.2017.08.005
Z.B. Khalid, M.N.I. Siddique, M. Nasrullah, L. Singh, Z.B.A. Wahid and M.F. Ahmad, Environ. Technol. Innov., 16, 100446 (2019); https://doi.org/10.1016/j.eti.2019.100446
M.N.I. Siddique, M. Sakinah Abd Munaim and A.W. Zularisam, J. Ind. Eng. Chem., 20, 331 (2014); https://doi.org/10.1016/j.jiec.2013.03.030
P.N.Y. Yek, C. Li, W. Peng, C.S. Wong, R.K. Liew, W.A. Wan Mahari, C. Sonne and S.S. Lam, Chem. Eng. J., 425, 131886 (2021); https://doi.org/10.1016/j.cej.2021.131886
Q. Yang, S. Ravnskov, J.W.M. Pullens and M.N. Andersen, Sci. Total Environ., 816, 151649 (2022); https://doi.org/10.1016/j.scitotenv.2021.151649
Z. Shi, M. Usman, J. He, H. Chen, S. Zhang and G. Luo, Water Res., 205, 117679 (2021); https://doi.org/10.1016/j.watres.2021.117679
Y. Li, X. Chen, L. Liu, P. Liu, Z. Zhou, Y. Huhetaoli, Y. Wu and T. Lei, J. Anal. Appl. Pyrolysis, 162, 105449 (2022); https://doi.org/10.1016/j.jaap.2022.105449
A. Pant and J.P.N. Rai, Environ. Challenges, 5, 100262 (2021); https://doi.org/10.1016/j.envc.2021.100262
G. Kaur, D. Johnravindar and J.W.C. Wong, Bioresour. Technol., 308, 123250 (2020); https://doi.org/10.1016/j.biortech.2020.123250
D. Johnravindar, J.W.C. Wong, D. Chakraborty, G. Bodedla and G. Kaur, J. Environ. Manage., 290, 112457 (2021); https://doi.org/10.1016/j.jenvman.2021.112457
Z. Yang, Z. Wang, G. Liang, X. Zhang and X. Xie, Chem. Eng. J., 426, 131777 (2021); https://doi.org/10.1016/j.cej.2021.131777
F. Zheng, J. Fang, F. Guo, X. Yang, T. Liu, M. Chen, M. Nie and Y.C. Chen, Eng. J. (N.Y.), 432, 134377 (2022); https://doi.org/10.1016/j.cej.2021.134377