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Vol. 36 No. 2 (2024): Vol 36 Issue 2, 2024

Copyright (c) 2024 Zubair Hasan

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Metal Organic Framework Derived Cu-Carbon Composite for the Effective Reduction of p-Nitrophenol

https://doi.org/10.14233/ajchem.2024.31153
Zubair Hasan
Department of Mathematical and Physical Sciences, East West University, Dhaka, Bangladesh
https://orcid.org/0000-0002-1241-7642
Md. Shariful Islam
Department of Pharmacy, East West University, Dhaka, Dhaka, Bangladesh
https://orcid.org/0000-0001-9644-7357
Mahmud Hassan
Department of Mathematical and Physical Sciences, East West University, Dhaka, Bangladesh
https://orcid.org/0000-0002-5937-2605
Md. Nazmul Abedin Khan
Department of Mathematical and Physical Sciences, East West University, Dhaka, Bangladesh
https://orcid.org/0000-0002-6337-6705
Mohammad Mahbubur Rahman
Fiber & Polymer Research Division, BCSIR Laboratories, Dhaka, Bangladesh
https://orcid.org/0000-0002-1729-7213
Mohammad Farhadur Rahman
https://orcid.org/0009-0000-1879-5022
https://orcid.org/0009-0000-1879-5022

Corresponding Author(s) : Zubair Hasan

zhasan@ewubd.edu

Asian Journal of Chemistry, Vol. 36 No. 2 (2024): Vol 36 Issue 2, 2024

Abstract

A Cu-carbon composite (Cu-C) was prepared via single-step carbonization of a metal-organic framework (MOF) composed of Cu2+ and 1,4-benzene dicarboxylate (BDC) and applied as a catalyst to degrade p-nitrophenol. The composite was characterized by X-ray powder diffraction (XRD), scanning electron microscope (SEM)/energy-dispersive X-ray (EDS), Fourier-transform infrared (FTIR) and X-ray photoelectron (XPS) spectroscopies. The characterization affirmed the preservation of MOF-originated CuO and metallic Cu in the carbon network. In presence of NaBH4, the Cu-C composite resulted in a complete reduction of p-nitrophenol within a few min and exhibited much higher removal rate than commercial CuO. The role of NaBH4 concentration in p-nitrophenol reduction was highlighted in the context of relevant catalytic mechanisms. The composite displayed good reusability during four consecutive cycles of p-nitrophenol reduction with only a small loss of its reactivity, signifying its potential as an alternative to noble-metal catalysts.

Keywords

Metal-organic framework p-Nitrophenol Reduction Metallic copper
Hasan, Z., Islam, M. S., Hassan, M., Khan, M. N. A., Rahman, M. M., & Rahman, M. F. (2024). Metal Organic Framework Derived Cu-Carbon Composite for the Effective Reduction of p-Nitrophenol. Asian Journal of Chemistry, 36(2), 481–488. https://doi.org/10.14233/ajchem.2024.31153
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