Copyright (c) 2023 Chitrakara Hegde, Dr. Chandni Pathak
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis, Characterization and Eco-friendly Applications of Biodegradable Polycaprolactone-Tapioca Starch Polymeric Composite Membrane
Corresponding Author(s) : Chitrakara Hegde
Asian Journal of Chemistry,
Vol. 36 No. 1 (2024): Vol 36 Issue 1, 2024
Abstract
In the pursuit of sustainable materials, this study on the synthesis and multifaceted characterization of a novel biodegradable polymeric composite membrane. The polymeric composite composed of polycaprolactone (PCL) and tapioca starch (TS) was meticulously prepared and it’s properties were systematically investigated. FTIR was employed to elucidate the structure of the composite, while SEM facilitated the morphological examination. The biodegradability of the material was rigorously assessed through a burial method and a comparative analysis was also conducted against a commercially available facemask. The antimicrobial efficacy and the material’s suitability for water purification were also evaluated. The versatile application potential of the polymeric composite was further demonstrated through packaging tests utilizing tomatoes. The comprehensive investigated presented in this study demonstrates the advantageous sustain-ability of the PCL-TS polymer composite, hence highlighting its potential for many environmental friendly applications.
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K. Amulya, R. Katakojwala, S. Ramakrishna and S.V. Mohan, Composites Part C: Open Access, 4, 100111 (2021); https://doi.org/10.1016/j.jcomc.2021.100111
S.A. Miller, ACS Macro Lett., 2, 550 (2013); https://doi.org/10.1021/mz400207g
T.A. Hottle, M.M. Bilec and A.E. Landis, Polym. Degrad. Stab., 98, 1898 (2013); https://doi.org/10.1016/j.polymdegradstab.2013.06.016.
S.A.A Ghavimi, M. H. Ebrahimzadeh, M. Solati-Hashjin, and N.A.A. Osman, J. Biomed. Mater. Res. A, 103, 2482 (2015); https://doi.org/10.1002/jbm.a.35371
P. Matzinos, V. Tserki, A. Kontoyiannis and C. Panayiotou, Polym. Degrad. Stab., 77, 17 (2002); https://doi.org/10.1016/S0141-3910(02)00072-1
A.L. Sisson, D. Ekinci and A. Lendlein, Polymer, 54, 4333 (2013); https://doi.org/10.1016/j.polymer.2013.04.045
R.M. Mohamed and K.A. Yusoh, Adv. Mater. Res., 1134, 249 (2015); https://doi.org/10.4028/www.scientific.net/AMR.1134.249
M. Bartnikowski, T.R. Dargaville, S. Ivanovski and D.W. Hutmacher, Prog. Polym. Sci., 96, 1 (2019); https://doi.org/10.1016/j.progpolymsci.2019.05.004
Y. Fan, X. Miao, C. Hou, J. Wang, J. Lin and F. Bian, Polymer, 270, 125778 (2023); https://doi.org/10.1016/j.polymer.2023.125778
W. Qing, Z. Liu, S. Yang, L. Tan, Y. Yang, D. Zhang and J. Li, RSC Adv., 5, 55619 (2015); https://doi.org/10.1039/C5RA08723F.
S. Flores, L. Famá, A.M. Rojas, S. Goyanes and L. Gerschenson, Food Res. Int., 40, 257 (2007); https://doi.org/10.1016/j.foodres.2006.02.004
E. Hernandez-García, M. Vargas, C. Gonzalez-Martínez and A. Chiralt, Foods, 10, 1256 (2021); https://doi.org/10.3390/foods10061256
C. Hegde, A.M. Isloor, M. Padaki, P. Wanichapichart and Y. Liangdeng, Desalination, 265, 153 (2011); https://doi.org/10.1016/j.desal.2010.07.046
F.M. Nor, H.Y. Lee, J.Y. Lim and D. Kurniawan, E-Polymers, 16, 217 (2016); https://doi.org/10.1515/epoly-2015-0261
C. Hegde, S. Rao and J. D’Souza, Desalination Water Treat., 57, 3827 (2016); https://doi.org/10.1080/19443994.2014.988652
H. Li, Biomaterials, 25, 5473 (2004); https://doi.org/10.1016/j.biomaterials.2003.12.052
G.K. Arbade, J. Srivastava, V. Tripathi, N. Lenka and T.U. Patro, J. Biomater. Sci. Polym. Ed., 31, 1648 (2020); https://doi.org/10.1080/09205063.2020.1769799.
S.A. Varghese, H. Pulikkalparambil, S.M. Rangappa, S. Siengchin and J. Parameswaranpillai, Food Packag. Shelf Life, 25, 100538 (2020); https://doi.org/10.1016/j.fpsl.2020.100538
O.S. Odusanya, U.S. Ishiaku, B.M.N. Azemi, B.D.M. Manan and H.W. Kammer, Polym. Eng. Sci., 40, 1298 (2000); https://doi.org/10.1002/pen.11258
M. Qasim, D.D. Duong, J.Y. Lee and N.Y. Lee, J. Appl. Polym. Sci., 137, 49207 (2020); https://doi.org/10.1002/app.49207
M. Nevoralová, M. Koutný, A. Ujcic, Z. Starý, J. Šerá, H. Vlková, M. Šlouf, I. Fortelný and Z. Kruliš, Front. Mater., 7, 141 (2020); https://doi.org/10.3389/fmats.2020.00141
J. Pinheiro, C. Alegria, M. Abreu, E.M. Gonçalves and C.L.M. Silva, J. Food Eng., 114, 338 (2013); https://doi.org/10.1016/j.jfoodeng.2012.08.024