Issue

Vol. 36 No. 1 (2024): Vol 36 Issue 1, 2024

Copyright (c) 2023 punitha T

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Multifunctional Properties of Biphasic DyFeO3 Perovskite/Dy3Fe5O12 Garnet Rare Earth Orthoferrite

https://doi.org/10.14233/ajchem.2024.30718
T. Punitha
PG & Research Department of Physics, Government Arts College (Men), Nandanam, Chennai-600035, India
https://orcid.org/0009-0002-5210-0719
P. Balamurugan
PG & Research Department of Physics, Government Arts College (Men), Nandanam, Chennai-600035, India
https://orcid.org/0000-0002-5129-6898
G. Sathish Kumar
Department of Physics, Sri Sai Ram Engineering College, Chennai-600044, India
https://orcid.org/0000-0001-9954-3184

Corresponding Author(s) : T. Punitha

punithaecs@princescience.in

Asian Journal of Chemistry, Vol. 36 No. 1 (2024): Vol 36 Issue 1, 2024

Abstract

Rare-earth orthoferrites are a group of compounds which exhibit improved magnetic, optical, and electrical characteristics throughout a wide range of temperatures. In present work, dysprosium based orthoferrite compound containing double phase of DyFeO3 perovskite/ Dy3Fe5O12 garnet was synthesized via co-precipitation technique. A mixed phase of orthoferrite, DyFeO3 perovskite and  Dy3Fe5O12 garnet has been obtained. The X-ray diffraction (XRD) was carried out to explore the structural arrangements of atoms in  the prepared material and clearly demonstrated the presence of both cubic phase of Dy3Fe5O12 (bcc) and orthorhombic phase of  DyFeO3 in the powder sample. The nanoparticles surface morphological behaviour is explored with field emission scanning electron  microscope (FE-SEM), which shows nearly spherical shape particles with little agglomeration. Using the UV-visible absorbance, band  gap of the prepared sample was evaluated as 2.06 eV from Tauc plot. The magnetization behaviour was observed using a vibrating  sample magnetometer (VSM), which revealed the Langevin component (ferromagnetic) at low field and as linear component  (antiferromagnetic) at high field. The electric polarization (P-E loop) studies also revealed the typical induced ferroelectric behaviour. 

Keywords

Co-precipitation Rare-earth orthoferrites Nanocomposite Magnetic property Electric polarization
Punitha, T., Balamurugan, P., & Kumar, G. S. (2023). Multifunctional Properties of Biphasic DyFeO3 Perovskite/Dy3Fe5O12 Garnet Rare Earth Orthoferrite. Asian Journal of Chemistry, 36(1), 135–140. https://doi.org/10.14233/ajchem.2024.30718
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. D. Carranza-Celis, A. Cardona-Rodríguez, J. Narváez, O. MoscosoLondono, D. Muraca, M. Knobel, N. Ornelas-Soto, A. Reiber and J.G. Ramírez, Sci. Rep., 9, 3182 (2019); https://doi.org/10.1038/s41598-019-39517-3
  2. M. Nakhaei and D. Sanavi Khoshnoud, Physica B, 612, 412899 (2021); https://doi.org/10.1016/j.physb.2021.412899
  3. P.K. Gupta, S. Ghosh, A. Pal, S. Roy, A.G. Joshi, A.K. Ghosh and S. Chatterjee, SN Appl. Sci., 1, 1607 (2019); https://doi.org/10.1007/s42452-019-1640-8
  4. S. Hanif, M. Hassan, S. Riaz, S. Atiq, S.S. Hussain, S. Naseem and G. Murtaza, Results Phys., 7, 3190 (2017); https://doi.org/10.1016/j.rinp.2017.08.061
  5. C. Prakash, A.K. Yadav and A. Dixit, Phys. Chem. Chem. Phys., 25, 19868 (2023); https://doi.org/10.1039/D3CP02235H
  6. C.M. Raghavan, J.W. Kim and S.S. Kim, Ceram. Int., 39, 3563 (2013); https://doi.org/10.1016/j.ceramint.2012.10.182
  7. N.S. Kumar, R.P. Suvarna, K.C. Babu Naidu, P.P. Mohapatra and P. Dobbidi, Inorg. Chem. Commun., 149, 110408 (2023); https://doi.org/10.1016/j.inoche.2023.110408
  8. N. Suresh Kumar and K. Chandra Babu Naidu, J. Materiomics, 7, 940 (2021); https://doi.org/10.1016/j.jmat.2021.04.002
  9. S. Sahoo, P.K. Mahapatra, R.N.P. Choudhary, M.L. Nandagoswami and A. Kumar, Mater. Res. Express, 3, 065017 (2016); https://doi.org/10.1088/2053-1591/3/6/065017
  10. Y. Tokunaga, S. Iguchi, T. Arima and Y. Tokura, Phys. Rev. Lett., 101, 097205 (2008); https://doi.org/10.1103/PhysRevLett.101.097205
  11. G. Deng, Y. Chen, M. Tao, C. Wu, X. Shen, H. Yang and M. Liu, Electrochim. Acta, 55, 1120 (2010); https://doi.org/10.1016/j.electacta.2009.09.078
  12. A.T.S. Sudandararaj, G. Sathish Kumar, M. Dhivya, R.D. Eithiraj and I.B. Shameem Banu, J. Alloys Compd., 783, 393 (2019); https://doi.org/10.1016/j.jallcom.2018.11.205
  13. S. Mathur, H. Shen, A. Leleckaite, A. Beganskiene and A. Kareiva, Mater. Res. Bull., 40, 439 (2005); https://doi.org/10.1016/j.materresbull.2004.12.002
  14. Z.Y. Zhao, X. Zhao, H.D. Zhou, F.B. Zhang, Q.J. Li, C. Fan, X.F. Sun and X.G. Li, Phys. Rev. B Condens. Matter Mater. Phys., 89, 224405 (2014); https://doi.org/10.1103/PhysRevB.89.224405
  15. F.K. Chiang, M.W. Chu, F.C. Chou, H.T. Jeng, H.S. Sheu, F.R. Chen and C.H. Chen, Phys. Rev. B Condens. Matter Mater. Phys., 83, 245105 (2011); https://doi.org/10.1103/PhysRevB.83.245105
  16. A. Stroppa, M. Marsman, G. Kresse and S. Picozzi, New J. Phys., 12, 093026 (2010); https://doi.org/10.1088/1367-2630/12/9/093026
  17. B.M. Wanklyn, D. Midgley and B.K. Tanner, J. Cryst. Growth, 29, 281 (1975); https://doi.org/10.1016/0022-0248(75)90172-4
  18. S.S.K. Reddy, N. Raju, C.G. Reddy, P.Y. Reddy, K.R. Reddy and V.R. Reddy, J. Magn. Magn. Mater., 396, 214 (2015); https://doi.org/10.1016/j.jmmm.2015.08.038
  19. S.J. Luo, S.Z. Li, N. Zhang, T. Wei, X.W. Dong, K.F. Wang and J.-M. Liu, Thin Solid Films, 519, 240 (2010); https://doi.org/10.1016/j.tsf.2010.08.002
  20. G. Rekha, R. Tholkappiyan, K. Vishista and F. Hamed, Appl. Surf. Sci., 385, 171 (2016); https://doi.org/10.1016/j.apsusc.2016.05.092
  21. M. Guillot, C.N. Chinnasamy, J.M. Greneche and V.G. Harris, J. Appl. Phys., 111, 07A5171 (2012); https://doi.org/10.1063/1.3679020
  22. A. Salehabadi, M. Salavati-Niasari, T. Gholami and A. Khoobi, Int. J. Hydrogen Energy, 43, 9713 (2018); https://doi.org/10.1016/j.ijhydene.2018.04.018
  23. V. Anbarasu, M. Dhilip, K. Saravana Kumar and K. Sivakumar, J. Mater. Sci. Mater. Electron., 28, 8976 (2017); https://doi.org/10.1007/s10854-017-6628-9
  24. M. Ristic, S. Popovic, I. Czako-Nagy and S. Music, Mater. Lett., 27, 337 (1996); https://doi.org/10.1016/0167-577X(96)00020-1
  25. N. Adhlakha, K.L. Yadav and R. Singh, Sci. Adv. Mater., 5, 947 (2013); https://doi.org/10.1166/sam.2013.1543
  26. G. Madhu, K. Maniammal and V. Biju, Phys. Chem. Chem. Phys., 18, 12135 (2016); https://doi.org/10.1039/C5CP03710G
  27. S. Ghosh, K. Das, K. Chakrabarti and S.K. De, Dalton Trans., 42, 3434 (2013); https://doi.org/10.1039/C2DT31764H
  28. B. Panigrahy, M. Aslam, D.S. Misra, M. Ghosh and D. Bahadur, Adv. Funct. Mater., 20, 1161 (2010); https://doi.org/10.1002/adfm.200902018
  29. V. Anbarasu, A. Manigandan, T. Karthik and K. Sivakumar, J. Mater. Sci. Mater. Electron., 23, 1201 (2012); https://doi.org/10.1007/s10854-011-0573-9
  30. Y. Hamasaki, S. Yasui, T. Katayama, T. Kiguchi, S. Sawai and M. Itoh, Appl. Phys. Lett., 119, 182904 (2021); https://doi.org/10.1063/5.0063021
Read More
Author biographies is not available.
Download
AJC-36-1-18
Statistic
Read Counter : 0 Download : 0