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Vol. 36 No. 12 (2024): Vol 36 Issue 12, 2024

Copyright (c) 2024 JAYASREE KOMARA, Jaya Prasanthi Karumuri, Ravikanth Tandra, Santhosh Thota

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Amorphous Zirconium-Zinc Bimetallic Metal Organic Framework based Fluorescent Sensor for Sensing of Ceftriaxone, Metronidazole and Ornidazole Antibiotics

https://doi.org/10.14233/ajchem.2024.32759
Jayasree Komara
Department of Chemistry, AU College of Science and Technology, Andhra University, Visakhapatnam-530003, India
https://orcid.org/0009-0003-3510-9604
Jaya Prasanthi Karumuri
Department of Chemistry, AU College of Science and Technology, Andhra University, Visakhapatnam-530003, India
https://orcid.org/0009-0000-3308-3429
Ravikanth Tandra
Department of Chemistry, AU College of Science and Technology, Andhra University, Visakhapatnam-530003, India
https://orcid.org/0009-0003-9975-8929
Santhosh Thota
Department of Chemistry, AU College of Science and Technology, Andhra University, Visakhapatnam-530003, India
https://orcid.org/0009-0001-0621-6780

Corresponding Author(s) : Jaya Prasanthi Karumuri

dr.kjprasanthi@andhrauniversity.edu.in

Asian Journal of Chemistry, Vol. 36 No. 12 (2024): Vol 36 Issue 12, 2024

Abstract

It is essential to have both sensitive and selective antibiotic sensor, as the overuse of antibiotics has escalated in the last few years, endangering both human health and the environment. This work produced a hydrostable amorphous bimetallic metal organic framework (Zr-Zn-EDTA), which is employed as a fluorescence sensor using a solvothermal approach. Zr-Zn-EDTA bimetallic metal organic framework effectively quenches ceftriaxone, metronidazole and ornidazole among the five antibiotics, with low detection limits (LOD) 4.9 × 10–7 M for ceftriaxone, 5.4 × 10–7 M for metronidazole and 6.05 × 10–7 M for ornidazole, respectively. Moreover, Zr-Zn-EDTA exhibits good selectivity and recyclability for the detection of antibiotics including metronidazole, ornidazole and ceftriaxone. Specifically, a comprehensive analysis of the quenching mechanism has been shown, which might offer a clear comprehension for the identification of the ensuing antibiotics.

Keywords

Zirconium Zinc Ethylene diaminetetraacetate Sensor Metal organic framework Bimetallic MOFs Antibiotics
Komara, J., Karumuri, J. P., Tandra, R., & Thota, S. (2024). Amorphous Zirconium-Zinc Bimetallic Metal Organic Framework based Fluorescent Sensor for Sensing of Ceftriaxone, Metronidazole and Ornidazole Antibiotics. Asian Journal of Chemistry, 36(12), 2939–2945. https://doi.org/10.14233/ajchem.2024.32759
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