Copyright (c) 2024 Ravichandran R
This work is licensed under a Creative Commons Attribution 4.0 International License.
Preparation, Characterization and Conductivity of SiO2 doped rGO-WO3 Composite for Battery Application
Corresponding Author(s) : S. Darlin Quine
Asian Journal of Chemistry,
Vol. 36 No. 11 (2024): Vol 36 Issue 11, 2024
Abstract
High-performance solid polymer electrolytes are regarded as one of the most promising materials to be used in the development of lithium ion batteries with improved extended life, increased recyclability and increased safety for electric vehicles and energy storage. In this work, a microwave-assisted hydrothermal technique was used to produce SiO2-doped rGO-WO3 composite, which possesses outstanding supercapacitor capabilities. This method is simple, low-cost method without using any other capping and reducing agents. The obtained SiO2 doped rGO-WO3 composite structural, morphology and components have been examined by XRD, FT-IR, FE-SEM, TEM, EDX, UV-visible techniques. It was found that the SiO2 doped rGO-WO3 composite well crystalline and the size range is about 20-30 nm. The SEM morphology results showed that the nanoparticles were stabilized by rGO, having cavity like structure and randomly distributed on the rGO-WO3 matrix. The solid state electrolyte revealed superior lithium ion transference number and cyclic stability. The SiO2 doped rGO-WO3 composite shows improved ionic conductivity of 2.74 × 10-5 S cm-1 at room temperature.
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J. Duan, X. Tang, H. Dai, Y. Yang, W. Wu, X. Wei and Y. Huang, Energ. Rev., 3, 1 (2020); https://doi.org/10.1007/s41918-019-00060-4
Y. Liang, C.-Z. Zhao, H. Yuan, Y. Chen, W. Zhang, J.-Q. Huang, D. Yu, Y. Liu, M.-M. Titirici, Y.-L. Chueh, H. Yu and Q. Zhang, InfoMat, 1, 6 (2019); https://doi.org/10.1002/inf2.12000
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L. Mu, Q. Yuan, C. Tian, C. Wei, K. Zhang, J. Liu, P. Pianetta, M.M. Doeff, Y. Liu and F. Lin, Nat. Commun., 9, 2810 (2018); https://doi.org/10.1038/s41467-018-05172-x
Q. Wang, Z. Cui, Q. Zhou, X. Shangguan, X. Du, S. Dong, L. Qiao, S. Huang, X. Liu, K. Tang, X. Zhou and G. Cui, Energy Storage Mater., 25, 756 (2020); https://doi.org/10.1016/j.ensm.2019.09.010
B. Li, Y. Liu, X. Zhang, P. He and H. Zhou, Green Energy Environ., 4, 3 (2019); https://doi.org/10.1016/j.gee.2018.08.002
S.S. Chi, Y.C. Liu, N. Zhao, X. Guo, C.-W. Nan and L.Z. Fan, Energy Storage Mater., 17, 309 (2019); https://doi.org/10.1016/j.ensm.2018.07.004
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R.S. Vemuri, M.H. Engelhard and C.V. Ramana, ACS Appl. Mater. Interfaces, 4, 1371 (2012); https://doi.org/10.1021/am2016409
S. Vijayakumar and S. Vadivel, Opt. Laser Technol., 118, 44 (2019); https://doi.org/10.1016/j.optlastec.2019.04.040
X. Zhang, X. Lu, Y. Shen, J. Han, L. Yuan, L. Gong, Z. Xu, X. Bai, M. Wei, Y. Tong, Y. Gao, J. Chen, J. Zhou and Z.L. Wang, Chem. Commun., 47, 5804 (2011); https://doi.org/10.1039/c1cc10389j
W.P. Jakubik, Thin Solid Films, 517, 6188 (2009); https://doi.org/10.1016/j.tsf.2009.04.008
M.V. Arularasu, M. Sendhil, T.V. Rajendran, G. Mani, A.M. Aljuwayid and M.A. Habila, Inorg. Chem. Commun., 139, 109332 (2022); https://doi.org/10.1016/j.inoche.2022.109332
M.V. Arularau, BioNanoSci., 14, 2170 (2024); https://doi.org/10.1007/s12668-024-01541-7
X. Chen, Y. Xie, Y. Ling, J. Zhao, Y. Xu, Y. Tong, S. Li and Y. Wang, Mater. Des., 192, 108760 (2020); https://doi.org/10.1016/j.matdes.2020.108760
W. Li, Y. Pang, J. Liu, G. Liu, Y. Wang and Y. Xia, RSC Adv., 7, 23494 (2017); https://doi.org/10.1039/C7RA02603J
M.V. Arularasu, SN Appl. Sci., 1, 393 (2019); https://doi.org/10.1007/s42452-019-0424-5
S. Kalaiarasi and M. Jose, J. Nanostruct., 7, 47 (2017); https://doi.org/10.1007/s40097-016-0213-2