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Vol. 36 No. 10 (2024): Vol 36 Issue 10, 2024

Copyright (c) 2024 Dr. Manohar Patil, Nanasaheb Huse, Narendra Patil, Vishnu Adole, Annapurna Jha

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Enhanced Catalytic Activity for Production of Biodiesel from Aloe vera Oil and the Removal of Methyl Violet Dye using Polyaniline-Fe3O4 Magnetic Nanocomposite

https://doi.org/10.14233/ajchem.2024.31954
Narendra Mahadu Patil
Department of Chemistry, Nandurbar Taluka Vidhayak Samiti’s, G.T. Patil Arts, Commerce and Science College, Nandurbar-425412, India
https://orcid.org/0009-0008-2583-4729
Annapurna Jha
Department of Chemistry, Jamshedpur Women’s University, Jamshedpur-831004, India
https://orcid.org/0000-0002-5864-0401
Vishnu A. Adole
Department of Chemistry, MGV’s Loknete Vyankatrao Hiray Arts, Science and Commerce College, Panchavati, Nashik-422003, India
https://orcid.org/0000-0001-7691-7884
Nanasaheb P. Huse
Advanced Nanomaterials and Interfaces Laboratory, Department of Physics, Nandurbar Taluka Vidhayak Samiti’s G.T. Patil Arts, Commerce and Science College, Nandurbar-425412, India
https://orcid.org/0000-0003-0719-885X
Manohar R. Patil
Department of Chemistry, Nandurbar Taluka Vidhayak Samiti’s, G.T. Patil Arts, Commerce and Science College, Nandurbar-425412, India
https://orcid.org/0000-0002-2459-6350

Corresponding Author(s) : Manohar R. Patil

profmanoharpatil@gmail.com

Asian Journal of Chemistry, Vol. 36 No. 10 (2024): Vol 36 Issue 10, 2024

Abstract

The aim of this work was to use a unique technique to maximize the efficiency and cost-effectiveness of biodiesel synthesis utilizing Aloe vera oil. Moreover, in order to facilitate the magnetic separation from the resultant mixture, lipase was immobilized on a magnetic nanocomposite consisting of polyaniline (PANI) and Fe3O4. Utilizing XRD, SEM, TGA and FTIR spectroscopy, the nanocomposite was thoroughly characterized. The results indicated that the immobilized lipase exhibited enhanced thermal stability and a modified optimum pH compared to its free form. Using immobilized lipase also significantly improved the biodiesel conversion yield from 27% with free enzyme to 60%. Remarkably, after five cycles of reutilization in the production of biodiesel, the immobilized lipase retained 90% activity. The catalytic effectiveness of lipase during biodiesel synthesis was significantly enhanced and its resistance to heat and pH fluctuations was strengthened by this novel immobilization approach. Beyond its potential usage in biodiesel production, the PANI-Fe3O4 magnetic nanocomposite also demonstrated photocatalytic removal and degradation of methyl violet dye from aqueous solution.

Keywords

PANI–Fe3O4 magnetic nanocomposites Lipase Immobilization Biodiesel Methyl violet dye
Patil, N. M., Jha, A., Adole, V. A., Huse, N. P., & Patil, M. R. (2024). Enhanced Catalytic Activity for Production of Biodiesel from Aloe vera Oil and the Removal of Methyl Violet Dye using Polyaniline-Fe3O4 Magnetic Nanocomposite. Asian Journal of Chemistry, 36(10), 2253–2259. https://doi.org/10.14233/ajchem.2024.31954
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