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Vol. 36 No. 10 (2024): Vol 36 Issue 10, 2024

Copyright (c) 2024 Rituparna Biswas, Dr. Pranabes Bhattacharyya

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Magnetostructural Studies of Dinuclear Ni(II) Complexes with Tridentate NNO Chelator Schiff Base Ligands Originating from N-Substituted Diammines and Salicyldehyde or its Analogues: A Review

https://doi.org/10.14233/ajchem.2024.32291
Rituparna Biswas
Department of Chemistry, Bidhannagar College, EB-2, Salt Lake, Kolkata-700064, India
https://orcid.org/0009-0008-0815-5206
Pranabes Bhattacharyya
Department of Chemistry, Dr. A.P.J. Abdul Kalam Government College, New Town, Kolkata-700156, India
https://orcid.org/0009-0004-0401-4976

Corresponding Author(s) : Rituparna Biswas

rituparna2040@yahoo.co.in

Asian Journal of Chemistry, Vol. 36 No. 10 (2024): Vol 36 Issue 10, 2024

Abstract

Considering its significant single-ion zero-field splitting and distinctive spin magnetic moment, nickel(II) complex is frequently utilized as a paramagnetic center in the synthesis of magnetic complexes. In this review, the magnetostructural features of dinuclear nickel(II) complexes of tridentate Schiff base ligands with NNO chelator resulting from several N-substituted diamines and salicyldehyde or its analogus aldehydes is discussed. A perfect combination of a tridentate Schiff base together with bridging coligands produces a large number of complexes with fascinating magnetic properties. The structural diversity of the Ni(II) complexes with NNO blocking Schiff bases are mostly directed by both the coordination number of the metal ions and different bridging modes of the co-ligands like azide, nitrate, thiocyanate, carboxylates, etc. The relationship between magnetic exchange interaction (i.e. ferromagnetic or antiferromagnetic) with bonding parameters such as Ni···Ni separation, Ni–O–Ni angles have also been analyzed. This review is focused on the structural aspects as well as the magnetic characterization of nickel(II) dimmers of tridentate Schiff bases having NNO donor sets to establish a magnetostructural correlation.

Keywords

Nickel(II) complexes Schiff bases Tridentate NNO donor Magnetic characterization Magnetostructural correlation
Biswas, R., & Bhattacharyya, P. (2024). Magnetostructural Studies of Dinuclear Ni(II) Complexes with Tridentate NNO Chelator Schiff Base Ligands Originating from N-Substituted Diammines and Salicyldehyde or its Analogues: A Review. Asian Journal of Chemistry, 36(10), 2231–2245. https://doi.org/10.14233/ajchem.2024.32291
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