Copyright (c) 2024 SIVAKALA S SIVAKALA S, Paulcy Rani P.R. Paulcy Rani P.R., Asha S Kumar Asha S Kumar, Reshmi Jaya Raveendran
This work is licensed under a Creative Commons Attribution 4.0 International License.
Water Dispersible Poly(3,4-ethylenedioxythiophene) Nanogold Composites through Soft Template Route for Electrochemical Sensing of Ascorbic Acid
Corresponding Author(s) : S. Sivakala
Asian Journal of Chemistry,
Vol. 36 No. 10 (2024): Vol 36 Issue 10, 2024
Abstract
This study presented the development of a water dispersible poly(3,4-ethylene dioxythiophene) (PEDOT) nanogold nanocomposite with a renewable resource-derived amphiphilic dopant, 3-pentadecylphenol-4-sulphonic acid (3-PDPSA). The amphiphilic dopant so designed is found to form stable emulsion with ethylenedioxythiopene (EDOT) with a wide composition range in water. The lyotropic behaviour of the PDPSA is found to be of complex nature at higher concentration higher than the micellar region. 3-PDPSA have built-in head-to-tail geometry effectively penetrates into PEDOT-Au chains to form highly organized nanowires. PEDOT-Au nanotubes are freely dispersible in water for various applications. PEDOT-Au is found to be an effective electrode modifier and acts as an electrochemical sensor for determining the concentration of ascorbic acid.
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References
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B. Belaabed, J.L. Wojkiewicz, S. Lamouri, N. El Kamchi and T. Lasri, J. Alloys Compd., 527, 137 (2012); https://doi.org/10.1016/j.jallcom.2012.02.179
P. Calvo-Marzal, S.S. Rosatto, P.A. Granjeiro, H. Aoyama and L.T. Kubota, Anal. Chim. Acta, 441, 207 (2001); https://doi.org/10.1016/S0003-2670(01)01120-5
R.S. Nicholson and I. Shain, Anal. Chem., 37, 190 (1965); https://doi.org/10.1021/ac60221a003
X. Zhang, Z. Liu, J. Zhang and C. Robinson, Chem. Commun., 16, 1852 (2004); https://doi.org/10.1039/b405255b
G.B. Street, S.E. Lindsey, A.I. Nazzal and K.J. Wynne, Mol. Crys. Liq. Cryst., 118, 137 (1985); https://doi.org/10.1080/00268948508076201
Y. Lu, Y. Mei, M. Schrinner, M. Ballauff, M.W. Möller and J. Breu, J. Phys. Chem. C, 111, 7676 (2007); https://doi.org/10.1021/jp070973m
E. Song and J.W. Choi, Nanomaterials, 3, 498 (2013); https://doi.org/10.3390/nano3030498
M. Zaarour, M. El Roz, B. Dong, R. Retoux, R. Aad, J. Cardin, C. Dufour, F. Gourbilleau, J.-P. Gilson and S. Mintova, Langmuir, 30, 6250 (2014); https://doi.org/10.1021/la5006743
Q. Guo, R. Ghadiri, T. Weigel, A. Aumann, E. Gurevich, C. Esen, O. Medenbach, W. Cheng, B. Chichkov and A. Ostendorf, Polymers, 6, 2037 (2014); https://doi.org/10.3390/polym6072037
S. Wang, Y. Kang, I. Wang, H. Zhang, Y. Wang and Y. Wang, Sens. Actuators B Chem., 182, 467 (2013); https://doi.org/10.1016/j.snb.2013.03.042
M. El Rhazi, S. Majid, M. Elbasri, F.E. Salih, L. Oularbi and K. Lafdi, Int. Nano Lett., 8, 79 (2018); https://doi.org/10.1007/s40089-018-0238-2
P.K. Khanna, N. Singh, S. Charan, A.K. Viswanath, Mater. Chem. Phys., 92, 214 (2005); https://doi.org/10.1016/j.matchemphys.2005.01.011
Y.O. Kang, S.H. Choi, A. Gopalan, K.P. Lee, H.D. Kang HD and Y.S. Song, J. Non-Cryst. Solids, 352, 463 (2006); https://doi.org/10.1016/j.jnoncrysol.2006.01.043
M.R. Karim, K.T. Lim, C.J. Lee, M.T.I. Bhuiyan, H.J. Kim, L.S. Park and M.S. Lee, J. Polym. Sci.: Part A Polym. Chem., 45, 5741 (2007); https://doi.org/10.1002/pola.22323
J.M. Du, Z.M. Liu, B.X. Han, Z.H. Li, J.L. Zhang and Y. Huang, Micropor. Macropor. Mater., 84, 254 (2005); https://doi.org/10.1016/j.micromeso.2005.05.036
S.K. Pillalamarri, F D. Blum, A.T. Tokuhiro, J.G. Story and M.F. Bertino, Chem. Mater., 17, 5941 (2005); https://doi.org/10.1021/cm0488478
H.H. Zhou, X.H. Ning, S.L. Li, J.H. Chen and Y.F. Kuang, Thin Solid Films, 510, 164 (2006); https://doi.org/10.1016/j.tsf.2005.12.310
M. Dosedel, E. Jirkovský, K. Macáková, L.K. Krcmová, L. Javorská, J. Pourová, L. Mercolini, F. Remião, L. Nováková and P. Mladenka, Nutrients, 13, 615 (2021); https://doi.org/10.3390/nu13020615
A. Husain, S. Parveen, M. Umar, H.P. Jethani, Abubakar and S. Kaushal, J. Pharm. Med. Chem., 6, 69 (2020); https://doi.org/10.21088/jpmc.2395.6615.6220.7
R.J. Tseng, J. Huang, J. Ouyang, R.B. Kaner and Y. Yang, Nano Lett., 5, 1077 (2005); https://doi.org/10.1021/nl050587l