Issue

Vol. 36 No. 10 (2024): Vol 36 Issue 10, 2024

Copyright (c) 2024 OVIYA K. J., SIVAGURUNATHAN P

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Structural, Magnetic and Electrochemical Properties of Nickel Manganese Ferrite (NixMn1-xFe2O4) Nanoparticles Prepared via Coprecipitation Method

https://doi.org/10.14233/ajchem.2024.32404
K.J. Oviya
Department of Physics, Annamalai University, Annamalai Nagar-608002, India
P. Sivagurunathan
Department of Physics, Annamalai University, Annamalai Nagar-608002, India

Corresponding Author(s) : P. Sivagurunathan

sivagurunathanp2012@yahoo.com

Asian Journal of Chemistry, Vol. 36 No. 10 (2024): Vol 36 Issue 10, 2024

Abstract

In current work, the co-precipitation approach was effectively used to synthesize NixMn1-xFe2O4 nanoparticles. Thermal stability of the nickel manganese ferrite nanoparticle was observed at temperatures above 390 ºC by TG/DTA analysis. XRD investigation revealed the cubic structure of the synthesized NixMn1-xFe2O4 nanoparticles. The average crystallite size of synthesized nanoparticles determined via Scherrer’s equation, increases linearly with calcination temperature and nickel concentration. The FTIR spectra showed the existence of stretching vibrations of metal oxide, which are ascribed to the formation of nickel manganese ferrite nanoparticles. The surface morphology of NixMn1-xFe2O4 nanoparticles, as observed using FESEM, exhibited a spherical shape. The EDX spectrum indicates the occurrence of Ni, Fe, Mn and O in the synthesized nickel manganese ferrite nanoparticles. The average size of the crystallites, as determined by XRD, closely matches the analysis conducted using HRTEM. The magnetic properties of NixMn1-xFe2O4 nanoparticles were analyzed using VSM. Nickel manganese ferrite nanoparticles exhibit increasing saturation magnetization and coercivity values as nickel concentration increases, indicating soft ferrimagnetic properties and making it appropriate for high-density recording devices. The cyclic voltammetry investigation of Ni0.7Mn0.3Fe2O4 sample, calcinated at 600 ºC, reveals a significant specific capacitance of 590 F g–1 at a scan rate of 2 mV s–1, suggesting its potential use in supercapacitors.

Keywords

Nickel manganese ferrite Structural Magnetic property Electrochemical property
Oviya, K., & Sivagurunathan, P. (2024). Structural, Magnetic and Electrochemical Properties of Nickel Manganese Ferrite (NixMn1-xFe2O4) Nanoparticles Prepared via Coprecipitation Method. Asian Journal of Chemistry, 36(10), 2375–2384. https://doi.org/10.14233/ajchem.2024.32404
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. A. Hussain, T. Abbas and S.B. Niazi, Ceram. Int., 39, 1221 (2013); https://doi.org/10.1016/j.ceramint.2012.07.049
  2. S. Gaffar, A. Kumar and U. Riaz, J. Electroceram., 51, 246 (2023); https://doi.org/10.1007/s10832-023-00333-x
  3. L. Shao, A. Sun, Y. Zhang, L. Yu, N. Suo and Z. Zuo, J. Mater. Sci. Mater. Electron., 32, 20474 (2021); https://doi.org/10.1007/s10854-021-06557-3
  4. S. Nazir, S. Sami, S. Haider, M. Shahid, M. Sher, M.F. Warsi, Q. Nadeem and M.A. Khan, Ceram. Int., 42, 13459 (2016); https://doi.org/10.1016/j.ceramint.2016.05.133
  5. G.M. Al-Senani, F.F. Al-Fawzan, R.S. Almufarij, O.H. Abd-Elkader and N.M. Deraz, Crystals, 12, 1542 (2022); https://doi.org/10.3390/cryst12111542
  6. T.F. Marinca, I. Chicinas, O. Isnard and B.V. Neamtu, Ceram. Int., 42, 4754 (2016); https://doi.org/10.1016/j.ceramint.2015.11.155
  7. B.I. Kharisov, H.V. Rasika Dias and O.V. Kharissova, Arabian J. Chem., 12, 1234 (2019); https://doi.org/10.1016/j.arabjc.2014.10.049
  8. S. Ramesh, B. Dhanalakshmi, B. Chandra Sekhar, P.S.V. Subba Rao and B. Parvatheeswara Rao, Appl. Phys., 122, 1 (2016); https://doi.org/10.1007/s00339-016-0517-6
  9. B.V. Tirupanyam, C. Srinivas, S.S. Meena, S.M. Yusuf, A. Satish Kumar, D.L. Sastry and V. Seshubai, J. Magn. Magn. Mater., 392, 101 (2015); https://doi.org/10.1016/j.jmmm.2015.05.010
  10. Z. Jabeen, A. Dawood, M. Alomar, S.N. Khan, I. Ali, M. Asif, W. Abbas, M.S. Irshad and M. Ahmad, Surf. Interfaces, 402, 103130 (2023); https://doi.org/10.1016/j.surfin.2023.103130
  11. B. Aslibeiki, P. Kameli, M.H. Ehsani, H. Salamati, E. Agostinelli, G. Muscas, V. Foglietti, S. Casciardi and D. Peddis, J. Magn. Magn. Mater., 399, 236 (2016); https://doi.org/10.1016/j.jmmm.2015.09.081
  12. A. Hajalilou, M. Hashim, R. Ebrahimi-Kahrizsangi and H.M. Kamari, J. Alloys Compd., 633, 306 (2015); https://doi.org/10.1016/j.jallcom.2015.02.061
  13. M.M. Hessien, Z.I. Zaki and A.Q. Mohsen, Adv. Mater. Phys. Chem., 3, 1 (2013); https://doi.org/10.4236/ampc.2013.31A001
  14. D. Deivatamil, J.A.M. Mark, T. Raghavan and J.P. Jesuraj, Inorg. Chem. Commun., 123, 108355 (2021); https://doi.org/10.1016/j.inoche.2020.108355
  15. R.S. Pandav, R.P. Patil, S.S. Chavan, I.S. Mulla and P.P. Hankare, J. Magn. Magn. Mater., 417, 407 (2016); https://doi.org/10.1016/j.jmmm.2016.04.090
  16. H. Yang, L. Zhao, X. Yang, L. Shen, L. Yu, W. Sun, Y. Yan, W. Wang and S. Feng, J. Magn. Magn. Mater., 271, 230 (2004); https://doi.org/10.1016/j.jmmm.2003.09.030
  17. E.R. Kumar, P.S.P. Reddy, G.S. Devi and S. Sathiyaraj, J. Magn. Magn. Mater., 398, 281 (2016); https://doi.org/10.1016/j.jmmm.2015.09.018
  18. G. Mathubala, A. Manikandan, S.A. Antony and P. Ramar, J. Mol. Struct., 1113, 79 (2016); https://doi.org/10.1016/j.molstruc.2016.02.032
  19. W. Pan, X. Zhang, Q.-F. Liu and J. Wang, Soft Nanosci. Lett., 7, 17 (2017); https://doi.org/10.4236/snl.2017.72002
  20. M. Kurian and C. Kunjachan, Int. Nano Lett., 4, 73 (2014); https://doi.org/10.1007/s40089-014-0122-7
  21. C. Barathiraja, A. Manikandan, A.M. Uduman Mohideen, S. Jayasree and S.A. Antony, J. Supercond. Nov. Magn., 29, 477 (2016); https://doi.org/10.1007/s10948-015-3312-2
  22. N. Nazari, M.M. Golzan and K. Mabhouti, Sci. Rep., 14, 6407 (2024); https://doi.org/10.1038/s41598-024-57045-7
  23. Y. Köseoglu, Ceram. Int., 39, 4221 (2013); https://doi.org/10.1016/j.ceramint.2012.11.004
  24. N. Channa, M. Khalid, A.D. Chandio, G. Mustafa, M.S. Akhtar, J.K. Khan, J. Ahmad and K.A. Kalhoro, J. Mater. Sci. Mater. Electron., 31, 1661 (2020); https://doi.org/10.1007/s10854-019-02684-0
  25. S.K. Jesudoss, J.J. Vijaya, L.J. Kennedy, P.I. Rajan, H.A. Al-Lohedan, R.J. Ramalingam, K. Kaviyarasu and M. Bououdina, J. Photochem. Photobiol. B, 165, 121 (2016); https://doi.org/10.1016/j.jphotobiol.2016.10.004
  26. R. Kesavamoorthi and C.R. Raja, J. Supercond. Nov. Magn., 29, 2729 (2016); https://doi.org/10.1007/s10948-016-3792-8
  27. S. Mirzaee, Y. Azizian-Kalandaragh and P. Rahimzadeh, Solid State Sci., 99, 106052 (2020); https://doi.org/10.1016/j.solidstatesciences.2019.106052
  28. J. Suresh, B. Trinadh, B.V. Babu, P.V.S.S.S.N. Reddy, B.S. Mohan, A.R. Krishna and K. Samatha, Physica B, 620, 413264 (2021); https://doi.org/10.1016/j.physb.2021.413264
  29. E.R. Kumar, A.S. Kamzin and T. Prakash, J. Magn. Magn. Mater., 378, 389 (2015); https://doi.org/10.1016/j.jmmm.2014.11.019
  30. S. Yuvaraj, N. Manikandan and G. Vinitha, Ceram. Int., 44, 22592 (2018); https://doi.org/10.1016/j.ceramint.2018.09.033
  31. T. Dippong, E.A. Levei, I.G. Deac, I. Petean and O. Cadar, Int. J. Mol. Sci., 23, 3097 (2022); https://doi.org/10.3390/ijms23063097
  32. A.I. Saputra, Herdiman, E. Suharyadi, T. Kato and S. Iwata, IOP Conf. Ser. Mater. Sci. Eng., 546, 042041 (2019); https://doi.org/10.1088/1757-899X/546/4/042041
  33. G. Asghar, E. Tariq, S.N. Khisro, G.H. Tariq, M.S. Awan, M.A.R. Khan, Y. Iqbal, K. Safeen and M. Anis-ur-Rehman, Kuwait J. Sci., 50, 518 (2023); https://doi.org/10.1016/j.kjs.2023.05.001
  34. K.P. Chae, W.O. Choi, J.G. Lee, B.S. Kang and S.H. Choi, J. Magn., 18, 21 (2013); https://doi.org/10.4283/JMAG.2013.18.1.021
  35. I. Chicinas, T.F. Marinca, B.V. Neamþu, F. Popa, O. Isnard and V. Pop, IEEE Trans. Magn., 50, 1 (2014); https://doi.org/10.1109/TMAG.2013.2285246
  36. K. Sasikumar, R. Bharathikannan, G. Sujithkumar, G.J. Arputhavalli, S. Raja, M. Vidhya, R. Marnadu and R. Suresh, J. Supercond. Nov. Magn., 34, 2189 (2021); https://doi.org/10.1007/s10948-021-05948-1
  37. Aakash, R. Choubey, D. Das and S. Mukherjee, J. Alloys Compd., 668, 33 (2016); https://doi.org/10.1016/j.jallcom.2016.01.198
  38. L. Zhao, H. Yang, L. Yu, Y. Cui, X. Zhao and S. Feng, J. Magn. Magn. Mater., 305, 91 (2006); https://doi.org/10.1016/j.jmmm.2005.11.043
  39. T.T.H. Hoang, S. Le The, S. Maenosono, T.N. Van, H.G. Do Thi, S.-E. Chun, T.T. Viet and N.T. Van, J. Appl. Electrochem., 53, 2109 (2023); https://doi.org/10.1007/s10800-023-01907-x
  40. P. Sivagurunathan and S.R. Gibin, J. Mater. Sci. Mater. Electron., 27, 2601 (2016); https://doi.org/10.1007/s10854-015-4065-1
  41. M.K. Zate, S.M.F. Shaikh, V.V. Jadhav, K.K. Tehare, S.S. Kolekar, R.S. Mane, M. Naushad, B.N. Pawar and K.N. Hui, J. Anal. Appl. Pyrolysis, 116, 177 (2015); https://doi.org/10.1016/j.jaap.2015.09.012
  42. S. Sharifi, A. Yazdani and K. Rahimi, Sci. Rep., 10, 10916 (2020); https://doi.org/10.1038/s41598-020-67802-z
  43. P. Bhojane, A. Sharma, M. Pusty, Y. Kumar, S. Sen and P. Shirage, J. Nanosci. Nanotechnol., 17, 1387 (2017); https://doi.org/10.1166/jnn.2017.12666
  44. S.B. Sreeja Lekshmi, S.R. Gibin, V.K. Premkumar and C. Rajeevgandhi, Neuroquantology, 20, 936 (2022); https://doi.org/10.48047/NQ.2022.20.1.NQ22377
Read More
Author biographies is not available.
Statistic
Read Counter : 0 Download : 0