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Vol. 31 No. 8 (2019): Vol 31 Issue 8

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Synthesis, Spectral, Structural and Thermal Characterization of Inorganic Crystal: Phenyl Trimethylammonium Tetrachlorocobaltate

https://doi.org/10.14233/ajchem.2019.21929
V. Mohanraj
P.G. & Research Department of Chemistry, Government Arts College (Autonomous), Coimbatore-641018, India; P.G. & Research Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science (Autonomous), Coimbatore-641020, India
R. Pavithra
P.G. & Research Department of Chemistry, Government Arts College (Autonomous), Coimbatore-641018, India
M. Thenmozhi
Centre for Nanotechnology and Advanced Biomaterials (CeNTAB), School of Chemical and Biotechnology, SASTRA University, Thanjavur- 613401, India
R. Umarani
P.G. & Research Department of Chemistry, Government Arts College (Autonomous), Coimbatore-641018, India

Corresponding Author(s) : R. Umarani

grunesh@gmail.com

Asian Journal of Chemistry, Vol. 31 No. 8 (2019): Vol 31 Issue 8

Abstract

Phenyl trimethylammonium tetrachlorocobaltate, crystals were grown by slow evaporation technique. The crystal was bright, transparent. The three dimensional structure of the phenyl trimethylammonium tetrachlorocobaltate was obtained from single crystal X-ray diffraction studies. The molecule belongs to monoclinic crystal system with C2/c space group. The presence of functional groups and modes of vibrations were identified by FT-IR spectroscopy. 1H NMR spectroscopy was also used to characterise the compound and the thermal stability of the crystal was established by TGA/DT analysis. This work undergoes phase transition which makes the study interesting.

Keywords

Phenyl trimethylammonium tetrachlorocobaltate Crystal growth Alkyl halometallates Thermal stability
Mohanraj, V., Pavithra, R., Thenmozhi, M., & Umarani, R. (2019). Synthesis, Spectral, Structural and Thermal Characterization of Inorganic Crystal: Phenyl Trimethylammonium Tetrachlorocobaltate. Asian Journal of Chemistry, 31(8), 1779–1784. https://doi.org/10.14233/ajchem.2019.21929
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