Copyright (c) 2026 Jinali B. Shah, Prof. K. Santhosh Kumar, Dr. Pujan B. Vaishnav

This work is licensed under a Creative Commons Attribution 4.0 International License.
Micronutrient-Fortified Guar Gum-Borax Hydrogels for Controlled Release and Improved Growth of Green Gram (Vigna radiata)
Corresponding Author(s) : Jinali B. Shah
Asian Journal of Chemistry,
Vol. 38 No. 7 (2026): Vol. 38, No 7 (2026)
Abstract
Micronutrient deficiencies and water scarcity are major constraints to crop productivity, especially in conditions of excessive cultivation and low fertilizer use efficiency. To overcome this, the designing of smart materials such as hydrogels by simple and scalable synthesis method is essential. In this study, we propose the development of fortified guar gum-borax (GGB) hydrogels as polysaccharide-derived matrices for controlled micronutrient delivery. Different loading strategies were investigated to incorporate essential micronutrients, including Zn, Fe, Mn, Cu and B, into the hydrogel matrix. Among the approaches evaluated, the post-gelation loading method proved to be the most effective for achieving efficient nutrient encapsulation and retention. Comprehensive physico-chemical characterization confirmed the successful incorporation of the micronutrients within the hydrogel network. Furthermore, soil incubation and aqueous release studies demonstrated a sustained and controlled release behaviour confirmed prolonged micronutrient availability and enhanced nutrient delivery potential. Pot trials on green gram (Vigna radiata) revealed that fortified hydrogel treatments showed faster germination and better or comparable vegetative growth when compared with treatments of conventional micronutrient fertilisation. Post-harvest soil analysis indicated that fortified-GGB hydrogels-maintained soil pH and electrical conductivity within a comparable range while supporting post-harvest micronutrient availability.
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L.V.P. Minello, S.G. Kuntzler, E. Berghahn, L.T. Dorneles, F.K. Ricachenevsky and R.A. Sperotto, J. Nanobiotechnology, 23, 669 (2025); https://doi.org/10.1186/s12951-025-03746-8
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N.H. Thang, T.B. Chien and D.X. Cuong, Gels, 9, 523 (2023); https://doi.org/10.3390/gels9070523
R. Ene (Vatcu), A.-T. Iacob, I. Fulga, M.L. Di Gioia, I. Dragostin, A. Fulga, S.K. Samal and O.-M. Dragostin, Polymers, 18, 709 (2026); https://doi.org/10.3390/polym18060709
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M.S. Haydar, D. Ghosh and S. Roy, Plant Nano Biol., 7, 100058 (2024); https://doi.org/10.1016/j.plana.2024.100058
M.M. Bhuyan and J.H. Jeong, Gels, 11, 896 (2025); https://doi.org/10.3390/gels11110896
A. Berradi, F. Aziz, M.E. Achaby, N. Ouazzani and L. Mandi, Polymers, 15, 2908 (2023); https://doi.org/10.3390/polym15132908
N. Thombare, U. Jha, S. Mishra and M.Z. Siddiqui, Carbohydr. Polym., 168, 274 (2017); https://doi.org/10.1016/j.carbpol.2017.03.086
N. Manousi, E. Isaakidou and G.A. Zachariadis, Appl. Sci., 12, 534 (2022); https://doi.org/10.3390/app12020534
M. Senila, Molecules, 29, 3169 (2024); https://doi.org/10.3390/molecules29133169
N. Thombare, U. Jha, S. Mishra and M.Z. Siddiqui, Int. J. Biol. Macromol., 88, 361 (2016); https://doi.org/10.1016/j.ijbiomac.2016.04.001
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A. Kaur, D. Singh and D. Sud, J. Polym. Res., 27, 297 (2020); https://doi.org/10.1007/s10965-020-02271-6
S. Van Vlierberghe, P. Dubruel and E. Schacht, Biomacromolecules, 12, 1387 (2011); https://doi.org/10.1021/bm200083n
K. Ali, Z. Asad, G.H.D. Agbna, A. Saud, A. Khan and S.J. Zaidi, Agronomy, 14, 2815 (2024); https://doi.org/10.3390/agronomy14122815
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