Copyright (c) 2026 Mahima Chaudhary

This work is licensed under a Creative Commons Attribution 4.0 International License.
Bismuth and Antimony-based Nanoparticles: New Avenues for Sustainable Catalysis and Environmental Remediation
Corresponding Author(s) : Mahima Chaudhary
Asian Journal of Chemistry,
Vol. 38 No. 7 (2026): Vol. 38, No 7 (2026)
Abstract
Nanostructured bismuth- and antimony-containing photocatalysts have become increasingly popular in photocatalytic applications because of their strong visible-light response and adjustable band-gap energies. Compared with conventional photocatalysts such as TiO2 and ZnO, Bi-based and Sb-based photocatalysts exhibit broader visible-light absorption and more favourable electronic structures. Their photocatalytic performance can be readily tailored through various engineering strategies, including defect engineering, elemental doping, morphology control and heterojunction construction. This review article summarizes some of the successful uses of Bi- and Sb-based nanostructured semiconductor photocatalysts for the degradation of organic dyes, pharmaceuticals, pesticides and heavy metals from aqueous solutions. Specific examples are provided to demonstrate the influence of morphology variation, oxygen vacancies and the construction of Z-scheme or S-scheme heterojunctions on the enhanced photocatalytic activity of Bi- and Sb-based nanomaterials. Recent developments in synthesis strategies and heterostructure design are also discussed in relation to improved catalytic activity and stability. Current challenges, including photocorrosion, catalyst deactivation, scalability, recyclability, and the potential ecotoxicity of Sb-containing materials, are highlighted, together with future perspectives for the development of sustainable and efficient photocatalytic systems.
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