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Vol. 35 No. 9 (2023): Vol 35 Issue 9, 2023

Copyright (c) 2023 U. M. MANDLE, S. B. Rathod, N. S. KOLATE, P. A. NANAWARE, V. S. RANE, P. A. AMBLE, K. S. LOHAR, B. L. Shinde

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An Efficient One-Pot Synthesis of Octahydroquinazolinone Derivatives Using Magnetic Cobalt Ferrite Catalyst

https://doi.org/10.14233/ajchem.2023.28109
U. M. MANDLE
Department of Chemistry, Sangmeshwar College, Solapur, 413001, (MS), India
https://orcid.org/0000-0002-7308-7720
S. B. Rathod
Department of Chemistry, Waghire College of Arts, Commerce and Science, Saswad, Pune, 412301, (MS), India
https://orcid.org/0000-0003-3517-015X
N. S. KOLATE
Department of Chemistry, Waghire College of Arts, Commerce and Science, Saswad, Pune, 412301, (MS), India
P. A. NANAWARE
Department of Chemistry, Waghire College of Arts, Commerce and Science, Saswad, Pune, 412301, (MS), India
V. S. RANE
Department of Chemistry, Waghire College of Arts, Commerce and Science, Saswad, Pune, 412301, (MS), India
P. A. AMBLE
Department of Chemistry, Waghire College of Arts, Commerce and Science, Saswad, Pune, 412301, (MS), India
K. S. LOHAR
Department of Chemistry, Shrikrishna Mahavidyalaya, Gunjoti, Osmanabad, 413606, (MS), India
https://orcid.org/0000-0003-1933-2542
B. L. Shinde
Department of Chemistry, Waghire College of Arts, Commerce and Science, Saswad, Pune, 412301, (MS), India
https://orcid.org/0000-0001-6568-5977

Corresponding Author(s) : B. L. Shinde

shindebl1981@gmail.com

Asian Journal of Chemistry, Vol. 35 No. 9 (2023): Vol 35 Issue 9, 2023

Abstract

In this work, octahydroquinazolinone derivatives were synthesized using magnetic cobalt ferrite nanoparticles using oxalate precursor method. The XRD pattern and IR spectrum confirmed the formation of single segment cubic spinel cobalt ferrite. The average size of the crystallites was determined to be 26.599 nm, while the lattice constant was found to be 8.365 Å. A fine spherical CoFe2O4 particles with some quantity of aggregation may be observed within the SEM and TEM images. Nano spinel cobalt ferrite nanoparticles is a easily synthesized, non-toxic, less expensive, effortlessly magnetically recoverable and green catalyst for the synthesis of octahydroquinazolinone derivatives through the condensation of aromatic aldehydes with urea or thiourea and dimedone. The advantages of this technique are quick reaction time, ease of product isolation and high yields.

Keywords

Octahydroquinazolinone; Cobalt ferrite Magnetic Aromatic aldehyde
MANDLE, U. M., Rathod, S. B., KOLATE, N. S. ., NANAWARE, P. A., RANE, V. S., AMBLE, P. A. ., … Shinde, B. L. (2023). An Efficient One-Pot Synthesis of Octahydroquinazolinone Derivatives Using Magnetic Cobalt Ferrite Catalyst. Asian Journal of Chemistry, 35(9), 2181–2188. https://doi.org/10.14233/ajchem.2023.28109
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