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Vol. 35 No. 9 (2023): Vol 35 Issue 9, 2023

Copyright (c) 2023 RAVIRAJ M. KULKARNI

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Thermally Activated Natural Clay for the Removal of Pharmaceutical Drug Levofloxacin

https://doi.org/10.14233/ajchem.2023.28124
RAVIRAJ M. KULKARNI
Department of Chemistry, KLS Gogte Institute of Technology (Autonomous) affiliated to Visvesvaraya Technological University, Udyambag, Belagavi-590008, India Centre for Nanoscience and Nanotechnology, KLS Gogte Institute of Technology (Autonomous) affiliated to Visvesvaraya Technological
https://orcid.org/0000-0001-6894-6888
SHILPA YAKKERIMATH
Department of Chemistry, KLS Gogte Institute of Technology (Autonomous) affiliated to Visvesvaraya Technological University, Udyambag, Belagavi-590008, India Centre for Nanoscience and Nanotechnology, KLS Gogte Institute of Technology (Autonomous) affiliated to Visvesvaraya Technological
https://orcid.org/0009-0000-7481-9287
SANJAYKUMAR V. DIVEKAR
Department of Chemistry, KLS Gogte Institute of Technology (Autonomous) affiliated to Visvesvaraya Technological University, Udyambag, Belagavi-590008, India
VAIBHAV R. CHATE
Centre for Nanoscience and Nanotechnology, KLS Gogte Institute of Technology (Autonomous) affiliated to Visvesvaraya Technological University, Udyambag, Belagavi-590008, India Department of Civil Engineering, KLS Gogte Institute of Technology (Autonomous) affiliated to Visvesvaraya Technological University, Udyambag, Belagavi-590008, India
https://orcid.org/0000-0002-8562-6250
BEKAL PURANDARA
Department of Civil Engineering, KLS Gogte Institute of Technology (Autonomous) affiliated to Visvesvaraya Technological University, Udyambag, Belagavi-590008, India
https://orcid.org/0000-0001-6863-2248

Corresponding Author(s) : RAVIRAJ M. KULKARNI

ravirajmk@git.edu

Asian Journal of Chemistry, Vol. 35 No. 9 (2023): Vol 35 Issue 9, 2023

Abstract

The adsorption behaviour of natural clay (NC) and thermal activated clay (TAC) mineral of the Panchanganga river flood zone sediment
for levofloxacin (a class of fluoroquinolone antibacterial drug) has been studied. The isotherm and kinetic studies were performed using the batch technique. The results showed that TAC has 72.6% removal efficiency comparatively higher than NC, which is 62.8% at  120 min, pH = 7, dosage 0.40 g/L and Initial concentration of 18.69 mg/L. The kinetic and isotherm results indicate the adsorption of levofloxacin on NC and TAC follows Freundlich isotherm suggesting multilayer sorption and chemisorption as a rate-limiting step  during the process. A plausible mechanism is proposed for the interaction of NC and TAC with levofloxacin from the results of the  adsorption study. The negative free energy change and positive enthalpy change indicated that the adsorption process is spontaneous  and endothermic. 

Keywords

Levofloxacin Adsorption Panchganga river thermal activated clay Natural Clay
KULKARNI, R. M., YAKKERIMATH, S., V. DIVEKAR, S., CHATE, V. R., & PURANDARA, B. (2023). Thermally Activated Natural Clay for the Removal of Pharmaceutical Drug Levofloxacin. Asian Journal of Chemistry, 35(9), 2161–2170. https://doi.org/10.14233/ajchem.2023.28124
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