Copyright (c) 2023 Nagaveni V. B. , Dr. ARUNA G.L., Dr. Mahadevan K.M.
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis, Characterization, Photoluminescence Emission and Antibacterial Properties of Some Schiff Base Derivatives of Substituted Salicylaldehyde
Corresponding Author(s) : Dr. ARUNA G.L.
Asian Journal of Chemistry,
Vol. 35 No. 9 (2023): Vol 35 Issue 9, 2023
Abstract
Schiff bases such as 4-{[(2-hydroxyphenyl) methylidene]amino} benzoic acid analogues (SB1-SB3) have been produced by the condensation of mole equivalent of 4-amino benzoic acid and various substituted salicylaldehyde. It has given good yield. The synthesized compounds (SB1-SB3) were analyzed by FT-IR, 1H-NMR and Mass spectroscopy techniques. Light emitting properties of the compounds have been studied by photoluminescence (PL) and diffuse reflectance (DR) spectra. Photoluminescence spectra of the compounds SB1-SB3 revealed that these molecules emit light from bright yellow to orange red color following exposure to UV light. From diffuse reflectance spectra, the measured optical band energy for SB1-SB3 was found to be 2.14eV, 2.06eV and 2.26eV respectively. The 3D surface view of scanning electron microscope (SEM) of SB1-SB3 have also been studied. This study revealed that Schiff base derivatives of 4-amino benzoic acid analogue molecules become promising material for light emitting devices. Antibacterial study of these compounds by Kirby-Bauer diffusion method revealed the antibacterial activity . This showed these compounds can be used as antibacterial compounds.
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- K. Shivakumar, S. Shashidhar, P. Vithal Reddy and M.B. Halli, J. Coord. Chem., 61, 2274 (2008); https://doi.org/10.1080/00958970801905239
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- M. Mustapha, B.R. Thorat, S. Sawant, R.G. Atram and R. Yamgar, J. Chem. Pharm. Res., 3, 1045 (2011).
- N. Al-Najjar, Iraqi J. Sci., 50, 271 (2009).
- A.R. Haque and M.A. Salam, Cogent Chem., 1, 1045212 (2015); https://doi.org/10.1080/23312009.2015.1045212
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References
K. Shivakumar, S. Shashidhar, P. Vithal Reddy and M.B. Halli, J. Coord. Chem., 61, 2274 (2008); https://doi.org/10.1080/00958970801905239
C.H. Chen and C.W. Tang, Appl. Phys. Lett., 79, 3711 (2001); https://doi.org/10.1063/1.1420583
M.S. More, P.G. Joshi, Y.K. Mishra and P.K. Khanna, Mater. Today Chem., 14, 100195 (2019); https://doi.org/10.1016/j.mtchem.2019.100195
N. Novoa, C. Manzur, T. Roisnel, S. Kahlal, J.-Y. Saillard, D. Carrillo and J.-R. Hamon, Molecules, 26, 5316 (2021); https://doi.org/10.3390/molecules26175316
S.M. Gomha, H.A. Ahmed, M. Shaban, T.Z. Abolibda, M.S. Khushaim and K.A. Alharbi, Materials, 14, 3718 (2021); https://doi.org/10.3390/ma14133718
Z.H. Chohan, A. Munawar and C.T. Supuran, Met. Based Drugs, 8, 137 (2001); https://doi.org/10.1155/MBD.2001.137
B. Hemmateenejad, M. Yazdani and H. Sharghi, Spectrochim. Acta A Mol. Biomol. Spectrosc., 91, 198 (2012); https://doi.org/10.1016/j.saa.2012.01.023
S. Kagatikar and D. Sunil, J. Electron. Mater., 50, 6708 (2021); https://doi.org/10.1007/s11664-021-09197-9
J. Zhang, L. Xu and W.-Ye. Wong, Coord. Chem. Rev., 355, 180 (2018); https://doi.org/10.1016/j.ccr.2017.08.007
M. Mustapha, B.R. Thorat, S. Sawant, R.G. Atram and R. Yamgar, J. Chem. Pharm. Res., 3, 1045 (2011).
N. Al-Najjar, Iraqi J. Sci., 50, 271 (2009).
A.R. Haque and M.A. Salam, Cogent Chem., 1, 1045212 (2015); https://doi.org/10.1080/23312009.2015.1045212
R.C. Maurya, P. Patel and S. Rajput, Synth. React. Inorg. Met.-Org. Chem., 33, 817 (2003); https://doi.org/10.1081/SIM-120021648
V. Nishal, D. Singh, R.K. Saini, V. Tanwar, S. Kadyan, R. Srivastava and P.S. Kadyan, Cogent Chem., 1, 1079291 (2015); https://doi.org/10.1080/23312009.2015.1079291
M. Srinivas, G.R. Vijayakumar, K.M. Mahadevan, H. Nagabhushana and H.S. Bhojya Naik, J. Sci. Adv. Mater. Dev., 2, 156 (2017); https://doi.org/10.1016/j.jsamd.2017.02.008
B.X. Yang, C. Yao and G. Zhou, Platin. Met. Rev., 57, 2 (2013); https://doi.org/10.1595/147106713X659019
B. Becerir, Fibers Polym., 6, 224 (2005); https://doi.org/10.1007/BF02875646