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Vol. 35 No. 8 (2023): Vol 35 Issue 8, 2023

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Efficient Transfer Hydrogenation of 4-Nitrophenol using Ammonia Borane over Metal-Organic Framework Derived Bimetallic Nanoparticles

https://doi.org/10.14233/ajchem.2023.28033
Akkenapally Swamy
Department of Chemistry, Andhra University, Visakhapatnam-530003, India
https://orcid.org/0009-0006-1996-5621
Valle Krishnaveni
Department of Chemistry, Andhra University, Visakhapatnam-530003, India
https://orcid.org/0000-0002-7802-4243
Siripurapu Mounika
https://orcid.org/0000-0003-1437-4575
https://orcid.org/0000-0003-1437-4575
Keloth Basavaiah
Department of Chemistry, Andhra University, Visakhapatnam-530003, India
https://orcid.org/0000-0002-6227-4424

Corresponding Author(s) : Akkenapally Swamy

akkenapallyswamy@gmail.com

Asian Journal of Chemistry, Vol. 35 No. 8 (2023): Vol 35 Issue 8, 2023

Abstract

Metal-organic frameworks (MOFs) are crystalline porous materials composed of metal ions and organic linkers connected through covalent bonds. To synthesize bimetallic nanoparticles ammonia borane was used as a reducing agent was used on metal ions contained in MOF-74(Cu, Ni). Monometallic Cu and Ni nanoparticles were also synthesized from their corresponding MOF-74 materials. The nanoparticles generated through this methodology were effectively stabilized by the linker of MOF. These nanoparticles were then employed for the transfer hydrogenation of 4-nitrophenol to 4-aminophenol. Among the 5 different catalysts tested, CuxNi1-x exhibited exceptional catalytic activity towards 4-nitrophenol reduction within 2 min, indicating a synergistic effect between copper and nickel in the bimetallic catalyst. Additionally, these catalysts demonstrated good stability and recyclability up to 5 cycles.

Keywords

4-Nitrophenol Metal nanoparticles Metal-organic frameworks Ammonia borane Transfer hydrogenation
Swamy, A., Krishnaveni, V., Mounika, S., & Basavaiah, K. (2023). Efficient Transfer Hydrogenation of 4-Nitrophenol using Ammonia Borane over Metal-Organic Framework Derived Bimetallic Nanoparticles. Asian Journal of Chemistry, 35(8), 1907–1915. https://doi.org/10.14233/ajchem.2023.28033
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