This work is licensed under a Creative Commons Attribution 4.0 International License.
Photocatalytic Degradation of Crystal Violet Dye in Aqueous Solution using ZnFe2O4-Cellulose Nanocomposite Catalyst
Corresponding Author(s) : Richa Tomar
Asian Journal of Chemistry,
Vol. 35 No. 6 (2023): Vol 35 Issue 6, 2023
Abstract
The major issue in the modern area is the wastewater discharge, particularly the organic pigments from several industries, which creates various pernicious health hazards. As a result, synthesized zinc ferrites and cellulose nanocomposites are effective photocatalysts used for the detoxification of crystal violet dyes. The crystallite-size of synthesized zinc ferrite nanoparticle was confirmed from XRD by using Scherrer equation to be 25.5 nm. The elemental composition of the zinc ferrite-cellulose nanocomposite was clearly shown by the EDS spectrum. Based on the FESEM micrographs, the zinc ferrite-cellulose nanocomposite morphology revealed a smooth surface with microspheres measuring 500 nm in size. The ZnFe2O4-cellulose nanocomposite demonstrated 92% photocatalytic efficiency for the removal of crystal violet dye at pH 6 after 160 min of sunlight irradiation with a catalyst dosage of 50 mg and an initial dye concentration of 10 ppm. The pseudo-second-order kinetic model was found to be consistent for the photocatalytic process. Finally, the newly developed photocatalyst (ZnFe2O4-cellulose nanocomposites) should be considered better for dye decontamination in wastewater.
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M.M.A. El-Hady and S.E. Saeed, Polymers, 12, 2451 (2020); https://doi.org/10.3390/polym12112451
P.L. Homagai, R. Poudel, S. Poudel and A. Bhattarai, Heliyon, 8, e09261 (2022); https://doi.org/10.1016/j.heliyon.2022.e09261
S.B. Somvanshi, S.A. Jadhav, M.V. Khedkar, P.B. Kharat, S.D. More and K.M. Jadhav, Ceram. Int., 46, 13170 (2020); https://doi.org/10.1016/j.ceramint.2020.02.091
E. Nakkeeran, S.J. Varjani, V. Dixit and A. Kalaiselvi, Indian J. Exp. Biol., 56, 498 (2018).
M. Chandrika, A.V. Ravindra, S.Y. Wang and S. Ju, J. Mater. Sci., 57, 2610 (2022); https://doi.org/10.1007/s10853-021-06701-8
M. Sriramulu, D. Shukla and S. Sumathi, Mater. Res. Express, 5, 115404 (2018); https://doi.org/10.1088/2053-1591/aadd88
B. Albiss and M. Abu-dalo, Sustainability, 13, 4729 (2021); https://doi.org/10.3390/su13094729
S. Mazhar, U.Y. Qazi, N. Nadeem, M. Zahid, A. Jalil, F. Khan, I. Ul-Hasan and I. Shahid, Environ. Sci. Pollut. Res. Int., 29, 9203 (2022); https://doi.org/10.1007/s11356-021-16181-7
S. Rachna, N.B. Singh and A. Agarwal, Mater. Today Proc., 5, 9148 (2018); https://doi.org/10.1016/j.matpr.2017.10.035
M. Gayathri, D.R. Kumar, E. Satheeshkumar, D. Manoj, A. Kumaresan, A. Arun, N. Jayaprakash and E. Sundaravadivel, J. Mater. Sci. Mater. Electron., 33, 10965 (2022); https://doi.org/10.1007/s10854-022-08076-1
T. Anjitha, T. Anilkumar, G. Mathew and M.T. Ramesan, Polym. Compos., 40, 2802 (2019); https://doi.org/10.1002/pc.25088
S. Fakhari, M. Jamzad and H. Kabiri Fard, Green Chem. Lett. Rev., 12, 19 (2019); https://doi.org/10.1080/17518253.2018.1547925
T. Appidi, D.B. Pemmaraju, R.A. Khan, S.B. Alvi, R. Srivastava, M. Pal, N. Khan and A.K. Rengan, Nanoscale, 12, 2028 (2020); https://doi.org/10.1039/C9NR05211A
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R. Tholkappiyan and K. Vishista, Int. J. Chemtech Res., 6, 2834 (2014).
R.M. Borade, S.B. Somvanshi, S.B. Kale, R.P. Pawar and K.M. Jadhav, Mater. Res. Express, 7, 016116 (2020); https://doi.org/10.1088/2053-1591/ab6c9c
J. Jiang, L. Ai and L.C. Li, J. Mater. Sci., 44, 1024 (2009); https://doi.org/10.1007/s10853-008-3225-6
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J. Lin, Z. Luo, J. Liu and P. Li, Mater. Sci. Semicond. Process., 87, 24 (2018); https://doi.org/10.1016/j.mssp.2018.07.003
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A. Nawaz, A. Khan, N. Ali, N. Ali and M. Bilal, Environ. Technol. Innov., 20, 101079 (2020); https://doi.org/10.1016/j.eti.2020.101079
M. Ait Haki, A. Imgharn, N. Aarab, A. Hsini, A. Essekri, M. Laabd, H. El Jazouli, M. Elamine, R. Lakhmiri and A. Albourine, Water Sci. Technol., 85, 433 (2022); https://doi.org/10.2166/wst.2021.451
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M. Alshabanat, G. Alsenani and R. Almufarij, J. Chem., 2013, 1 (2013); https://doi.org/10.1155/2013/210239
S.H. Ghoran, M.F. Dashti, A. Maroofi, M. Shafiee, A. Zare-Hoseinabadi, F. Behzad, M. Mehrabi, A. Jangjou and K. Jamali, Nanomedicine Res. J., 5, 20 (2020); https://doi.org/10.22034/NMRJ.2020.01.003
Y.S. Ho and G. McKay, Chem. Eng. J., 70, 115 (1998); http://dx.doi.org/10.1016/S0923-0467(98)00076-1
S. Banerjee and Y.C. Sharma, J. Environ. Manage., 233, 151 (2019); https://doi.org/10.1016/j.jenvman.2018.11.107
K. Rachna, A. Agarwal and N.B. Singh, Environ. Nanotechnol. Monit. Manag., 9, 154 (2018); https://doi.org/10.1016/j.enmm.2018.03.001
M. Essandoh, R.A. Garcia, V.L. Palochik, M.R. Gayle and C. Liang, Sep. Purif. Technol., 255, 117701 (2021); https://doi.org/10.1016/j.seppur.2020.117701
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B.T. Gemici, H.U. Ozel and H.B. Ozel, Sep. Sci. Technol., 55, 406 (2020); https://doi.org/10.1080/01496395.2019.1577268
S. Mohanty, S. Moulick and S.K. Maji, J. Water Proc. Eng., 37, 101428 (2020); https://doi.org/10.1016/j.jwpe.2020.101428
S. Maleki, F. Falaki and M. Karimi, J. Nanostruct. Chem., 9, 129 (2019); https://doi.org/10.1007/s40097-019-0303-z